A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers
Solid-state electrolytes have emerged as a promising alternative to existing liquid electrolytes for next-generation flexible Li metal batteries with enhanced safety and stability. Nevertheless, the brittleness and inferior room temperature conductivity are major obstacles for practical applications...
Gespeichert in:
| Veröffentlicht in: | RSC advances 2019-01, Vol.9 (8), p.4157-4161 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4161 |
|---|---|
| container_issue | 8 |
| container_start_page | 4157 |
| container_title | RSC advances |
| container_volume | 9 |
| creator | He, Kun Xie, Pu Zu, Chengkui Wang, Yanhang Li, Baoying Han, Bin Rong, Min Zhi Zhang, Ming Qiu |
| description | Solid-state electrolytes have emerged as a promising alternative to existing liquid electrolytes for next-generation flexible Li metal batteries with enhanced safety and stability. Nevertheless, the brittleness and inferior room temperature conductivity are major obstacles for practical applications. Herein, for the first time, we have fabricated a flexible lithium ion conductive glass-ceramic fiber by using a melt-spun homogeneous NASICON-type structured Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) glass melt and annealed at 825 °C. The annealed samples exhibited a higher lithium ion conductivity than the air-quenched sample due to the presence of a well-crystallized crystal grain in the annealed sample. Meanwhile, the ionic conductivity has shown an inverse relationship with the diameter of annealed LAGP glass-ceramic fibers. The results revealed that the annealed glass-ceramic fiber, with a diameter of 10 μm, resulted in lithium ion conductivity of 8.8 × 10
3
S cm
−1
at room temperature.
A flexible lithium ion conductive Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
glass-ceramic fiber was prepared by melt-spun method. |
| doi_str_mv | 10.1039/c8ra08401g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C8RA08401G</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2183062406</sourcerecordid><originalsourceid>FETCH-LOGICAL-c520t-b84b206923ecf5ea9b897157e7193622f60d15b059aa51d245307235bc62d553</originalsourceid><addsrcrecordid>eNp9kcFrFDEUxoMottRevCsRLyKMviSTzOQiLItWoSBI7zGTebObkpmsyUyx_vVm3bpWD75LXvh-fHyPj5CnDN4wEPqta5OFtga2eUBOOdSq4qD0w3v7CTnP-RrKKMm4Yo_JiZCSA9PNKfm6ooN1PiC1U0-zs8F25bNL0WHOdI40307zFrP_gXQI-N3v5eDnrV9G6uNEXZz6xc3-Bukm2Jwrh8mO3tHBd5jyE_JosCHj-d17Rq4-vL9af6wuP198Wq8uK1eizFXX1t0-LBfoBolWd61umGywYVoozgcFPZMdSG2tZD2vpYCGC9k5xXspxRl5d7DdLd2IvcNpTjaYXfKjTbcmWm_-Via_NZt4YzQoqNumGLy6M0jx24J5NqPPDkOwE8YlG64Ug5Y3ui7oy3_Q67ikqVxnOGsFKF6DKtTrA-VSzDnhcAzDwOyrM-v2y-pXdRcFfn4__hH9XVQBXhyAlN1R_dO92fVDYZ79jxE_AcrIqSk</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2183062406</pqid></control><display><type>article</type><title>A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers</title><source>DOAJ Directory of Open Access Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central Open Access</source><source>PubMed Central</source><creator>He, Kun ; Xie, Pu ; Zu, Chengkui ; Wang, Yanhang ; Li, Baoying ; Han, Bin ; Rong, Min Zhi ; Zhang, Ming Qiu</creator><creatorcontrib>He, Kun ; Xie, Pu ; Zu, Chengkui ; Wang, Yanhang ; Li, Baoying ; Han, Bin ; Rong, Min Zhi ; Zhang, Ming Qiu</creatorcontrib><description>Solid-state electrolytes have emerged as a promising alternative to existing liquid electrolytes for next-generation flexible Li metal batteries with enhanced safety and stability. Nevertheless, the brittleness and inferior room temperature conductivity are major obstacles for practical applications. Herein, for the first time, we have fabricated a flexible lithium ion conductive glass-ceramic fiber by using a melt-spun homogeneous NASICON-type structured Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) glass melt and annealed at 825 °C. The annealed samples exhibited a higher lithium ion conductivity than the air-quenched sample due to the presence of a well-crystallized crystal grain in the annealed sample. Meanwhile, the ionic conductivity has shown an inverse relationship with the diameter of annealed LAGP glass-ceramic fibers. The results revealed that the annealed glass-ceramic fiber, with a diameter of 10 μm, resulted in lithium ion conductivity of 8.8 × 10
3
S cm
−1
at room temperature.
A flexible lithium ion conductive Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
glass-ceramic fiber was prepared by melt-spun method.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c8ra08401g</identifier><identifier>PMID: 35520197</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Annealing ; Batteries ; Ceramic fibers ; Chemical synthesis ; Chemistry ; Crystallization ; Electrolytes ; Glass ceramics ; Ion currents ; Ions ; Lithium ; Lithium ions ; Melt spinning ; Molten salt electrolytes ; Solid electrolytes ; Thermal conductivity</subject><ispartof>RSC advances, 2019-01, Vol.9 (8), p.4157-4161</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2019</rights><rights>This journal is © The Royal Society of Chemistry 2019 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c520t-b84b206923ecf5ea9b897157e7193622f60d15b059aa51d245307235bc62d553</citedby><cites>FETCH-LOGICAL-c520t-b84b206923ecf5ea9b897157e7193622f60d15b059aa51d245307235bc62d553</cites><orcidid>0000-0001-6521-5246 ; 0000-0002-4888-498X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060487/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060487/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,725,778,782,862,883,27907,27908,53774,53776</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35520197$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>He, Kun</creatorcontrib><creatorcontrib>Xie, Pu</creatorcontrib><creatorcontrib>Zu, Chengkui</creatorcontrib><creatorcontrib>Wang, Yanhang</creatorcontrib><creatorcontrib>Li, Baoying</creatorcontrib><creatorcontrib>Han, Bin</creatorcontrib><creatorcontrib>Rong, Min Zhi</creatorcontrib><creatorcontrib>Zhang, Ming Qiu</creatorcontrib><title>A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Solid-state electrolytes have emerged as a promising alternative to existing liquid electrolytes for next-generation flexible Li metal batteries with enhanced safety and stability. Nevertheless, the brittleness and inferior room temperature conductivity are major obstacles for practical applications. Herein, for the first time, we have fabricated a flexible lithium ion conductive glass-ceramic fiber by using a melt-spun homogeneous NASICON-type structured Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) glass melt and annealed at 825 °C. The annealed samples exhibited a higher lithium ion conductivity than the air-quenched sample due to the presence of a well-crystallized crystal grain in the annealed sample. Meanwhile, the ionic conductivity has shown an inverse relationship with the diameter of annealed LAGP glass-ceramic fibers. The results revealed that the annealed glass-ceramic fiber, with a diameter of 10 μm, resulted in lithium ion conductivity of 8.8 × 10
3
S cm
−1
at room temperature.
A flexible lithium ion conductive Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
glass-ceramic fiber was prepared by melt-spun method.</description><subject>Annealing</subject><subject>Batteries</subject><subject>Ceramic fibers</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Crystallization</subject><subject>Electrolytes</subject><subject>Glass ceramics</subject><subject>Ion currents</subject><subject>Ions</subject><subject>Lithium</subject><subject>Lithium ions</subject><subject>Melt spinning</subject><subject>Molten salt electrolytes</subject><subject>Solid electrolytes</subject><subject>Thermal conductivity</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kcFrFDEUxoMottRevCsRLyKMviSTzOQiLItWoSBI7zGTebObkpmsyUyx_vVm3bpWD75LXvh-fHyPj5CnDN4wEPqta5OFtga2eUBOOdSq4qD0w3v7CTnP-RrKKMm4Yo_JiZCSA9PNKfm6ooN1PiC1U0-zs8F25bNL0WHOdI40307zFrP_gXQI-N3v5eDnrV9G6uNEXZz6xc3-Bukm2Jwrh8mO3tHBd5jyE_JosCHj-d17Rq4-vL9af6wuP198Wq8uK1eizFXX1t0-LBfoBolWd61umGywYVoozgcFPZMdSG2tZD2vpYCGC9k5xXspxRl5d7DdLd2IvcNpTjaYXfKjTbcmWm_-Via_NZt4YzQoqNumGLy6M0jx24J5NqPPDkOwE8YlG64Ug5Y3ui7oy3_Q67ikqVxnOGsFKF6DKtTrA-VSzDnhcAzDwOyrM-v2y-pXdRcFfn4__hH9XVQBXhyAlN1R_dO92fVDYZ79jxE_AcrIqSk</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>He, Kun</creator><creator>Xie, Pu</creator><creator>Zu, Chengkui</creator><creator>Wang, Yanhang</creator><creator>Li, Baoying</creator><creator>Han, Bin</creator><creator>Rong, Min Zhi</creator><creator>Zhang, Ming Qiu</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-6521-5246</orcidid><orcidid>https://orcid.org/0000-0002-4888-498X</orcidid></search><sort><creationdate>20190101</creationdate><title>A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers</title><author>He, Kun ; Xie, Pu ; Zu, Chengkui ; Wang, Yanhang ; Li, Baoying ; Han, Bin ; Rong, Min Zhi ; Zhang, Ming Qiu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c520t-b84b206923ecf5ea9b897157e7193622f60d15b059aa51d245307235bc62d553</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Annealing</topic><topic>Batteries</topic><topic>Ceramic fibers</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Crystallization</topic><topic>Electrolytes</topic><topic>Glass ceramics</topic><topic>Ion currents</topic><topic>Ions</topic><topic>Lithium</topic><topic>Lithium ions</topic><topic>Melt spinning</topic><topic>Molten salt electrolytes</topic><topic>Solid electrolytes</topic><topic>Thermal conductivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>He, Kun</creatorcontrib><creatorcontrib>Xie, Pu</creatorcontrib><creatorcontrib>Zu, Chengkui</creatorcontrib><creatorcontrib>Wang, Yanhang</creatorcontrib><creatorcontrib>Li, Baoying</creatorcontrib><creatorcontrib>Han, Bin</creatorcontrib><creatorcontrib>Rong, Min Zhi</creatorcontrib><creatorcontrib>Zhang, Ming Qiu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>He, Kun</au><au>Xie, Pu</au><au>Zu, Chengkui</au><au>Wang, Yanhang</au><au>Li, Baoying</au><au>Han, Bin</au><au>Rong, Min Zhi</au><au>Zhang, Ming Qiu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2019-01-01</date><risdate>2019</risdate><volume>9</volume><issue>8</issue><spage>4157</spage><epage>4161</epage><pages>4157-4161</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Solid-state electrolytes have emerged as a promising alternative to existing liquid electrolytes for next-generation flexible Li metal batteries with enhanced safety and stability. Nevertheless, the brittleness and inferior room temperature conductivity are major obstacles for practical applications. Herein, for the first time, we have fabricated a flexible lithium ion conductive glass-ceramic fiber by using a melt-spun homogeneous NASICON-type structured Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
(LAGP) glass melt and annealed at 825 °C. The annealed samples exhibited a higher lithium ion conductivity than the air-quenched sample due to the presence of a well-crystallized crystal grain in the annealed sample. Meanwhile, the ionic conductivity has shown an inverse relationship with the diameter of annealed LAGP glass-ceramic fibers. The results revealed that the annealed glass-ceramic fiber, with a diameter of 10 μm, resulted in lithium ion conductivity of 8.8 × 10
3
S cm
−1
at room temperature.
A flexible lithium ion conductive Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
glass-ceramic fiber was prepared by melt-spun method.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35520197</pmid><doi>10.1039/c8ra08401g</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-6521-5246</orcidid><orcidid>https://orcid.org/0000-0002-4888-498X</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2019-01, Vol.9 (8), p.4157-4161 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8RA08401G |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| subjects | Annealing Batteries Ceramic fibers Chemical synthesis Chemistry Crystallization Electrolytes Glass ceramics Ion currents Ions Lithium Lithium ions Melt spinning Molten salt electrolytes Solid electrolytes Thermal conductivity |
| title | A facile and scalable process to synthesize flexible lithium ion conductive glass-ceramic fibers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T08%3A44%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20facile%20and%20scalable%20process%20to%20synthesize%20flexible%20lithium%20ion%20conductive%20glass-ceramic%20fibers&rft.jtitle=RSC%20advances&rft.au=He,%20Kun&rft.date=2019-01-01&rft.volume=9&rft.issue=8&rft.spage=4157&rft.epage=4161&rft.pages=4157-4161&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/c8ra08401g&rft_dat=%3Cproquest_cross%3E2183062406%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2183062406&rft_id=info:pmid/35520197&rfr_iscdi=true |