The Suzuki-Miyaura reaction as a tool for modification of phenoxyl-nitroxyl radicals of the 4 H -imidazole N -oxide series

2-(3,5-Di- -butyl-4-hydroxyphenyl)-5-(4-iodophenyl)-4,4-dimethyl-4 -imidazole 3-oxide reacts with phenylboronic acid and its substituted derivatives in a cross-coupling reaction of the Suzuki-Miyaura type to form 5-biphenyl derivatives of 4 -imidazole- -oxide. Interaction of the same compound with B (pin) in the presence of PdCl (PPh ) proceeds through the formation of intermediate 1,3,2-dioxoborolane and leads to the product of homocoupling: biphenyl-bis(imidazole). Oxidation of the resultant imidazoles with lead dioxide quantitatively yields stable conjugated phenoxyl-nitroxyl mono- and diradicals, which are of interest as electroactive paramagnetic materials. The crystal structure of the monoradical, 2,6-di- -butyl-4-[1-oxido-4-(biphenyl-4-yl)-5,5-dimethyl-1 -imidazole-2(5 )-ylidene]cyclohex-2,5-dienone, its magnetic susceptibility, EPR spectra of the obtained hybrid radicals in solution, and cyclic voltammetry characteristics of 4 -imidazoles were studied.