A novel hydroxyl-containing polyimide as a colorimetric and ratiometric chemosensor for the reversible detection of fluoride ions
A novel hydroxyl-containing polyimide ( PI-OH ) has been successfully synthesized and subsequently used as a new colorimetric and ratiometric chemosensor for the detection of F − with high selectivity and a fast response time. The ratiometric absorbance changes of the chemosensor PI-OH in DMSO solut...
Gespeichert in:
Veröffentlicht in: | Polymer chemistry 2019-03, Vol.1 (11), p.1399-146 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 146 |
---|---|
container_issue | 11 |
container_start_page | 1399 |
container_title | Polymer chemistry |
container_volume | 1 |
creator | Wu, Yancheng Shi, Chuqi Chen, Zhigeng Zhou, Yubin Liu, Shumei Zhao, Jianqing |
description | A novel hydroxyl-containing polyimide (
PI-OH
) has been successfully synthesized and subsequently used as a new colorimetric and ratiometric chemosensor for the detection of F
−
with high selectivity and a fast response time. The ratiometric absorbance changes of the chemosensor
PI-OH
in DMSO solution show a linear response to F
−
in the concentration range of 0-0.50 mM with a detection limit of 1.79 μM, which provides a quantitative method for F
−
detection.
1
H NMR titration and DFT calculation studies confirm the F
−
sensing mechanism involves H-bond interactions and subsequent deprotonation in the chemosensor. Moreover, the chemosensor
PI-OH
in DMSO solution can be reversed many times and applied to the visual detection of F
−
. Finally,
PI-OH
film has been fabricated for real-time visualization of F
−
with high selectivity and sensitivity. The F
−
bonded to the
PI-OH
film can be easily removed by immersing it in acidic solution to recover the sensing ability to F
−
. X-ray photoelectron spectroscopy and energy dispersive spectroscopy analysis indicate that hydroxyl groups in the
PI-OH
film can bond to F
−
and the bonded F
−
can be removed quantitatively. This work provides not only a novel PI film-based sensor device for the visual and reversible detection of F
−
with high-efficiency, but also a promising F
−
extractor.
A novel hydroxyl-containing polyimide film has been designed and fabricated as a chemosensor for the real-time visualization of F
−
with high selectivity and sensitivity. |
doi_str_mv | 10.1039/c8py01697f |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C8PY01697F</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2190183714</sourcerecordid><originalsourceid>FETCH-LOGICAL-c281t-564fbfb641bdc7bb45b0c717e76c63a2315eb0938956368bf67f8a3800e3e6ca3</originalsourceid><addsrcrecordid>eNpFkUFLAzEQhYMoWGov3oWAN2E12ewmm2MpVoWCHvTgaUmyE5uy3dRkW9yj_9xoSx0YZgY-3jBvELqk5JYSJu9MtRkI5VLYEzSiopSZlDw_PfZlcY4mMa5ICkaLnPER-p7izu-gxcuhCf5raDPju165znUfeOPbwa1dA1hFrLDxrQ9uDX1wBquuwUH1zh9ms4S1j9BFH7BN2S8BB9hBiE63gBvowSS6w95i226TUJJNc7xAZ1a1ESaHOkZv8_vX2WO2eH54mk0Xmckr2mclL6y2mhdUN0ZoXZSaGEEFCG44UzmjJWgiWSVLznilLRe2UqwiBBhwo9gYXe91N8F_biH29cpvQ5dW1jmVhFZM0CJRN3vKBB9jAFtv0skqDDUl9a_L9ax6ef9zeZ7gqz0cojly_19gP70cfEA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2190183714</pqid></control><display><type>article</type><title>A novel hydroxyl-containing polyimide as a colorimetric and ratiometric chemosensor for the reversible detection of fluoride ions</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Wu, Yancheng ; Shi, Chuqi ; Chen, Zhigeng ; Zhou, Yubin ; Liu, Shumei ; Zhao, Jianqing</creator><creatorcontrib>Wu, Yancheng ; Shi, Chuqi ; Chen, Zhigeng ; Zhou, Yubin ; Liu, Shumei ; Zhao, Jianqing</creatorcontrib><description>A novel hydroxyl-containing polyimide (
PI-OH
) has been successfully synthesized and subsequently used as a new colorimetric and ratiometric chemosensor for the detection of F
−
with high selectivity and a fast response time. The ratiometric absorbance changes of the chemosensor
PI-OH
in DMSO solution show a linear response to F
−
in the concentration range of 0-0.50 mM with a detection limit of 1.79 μM, which provides a quantitative method for F
−
detection.
1
H NMR titration and DFT calculation studies confirm the F
−
sensing mechanism involves H-bond interactions and subsequent deprotonation in the chemosensor. Moreover, the chemosensor
PI-OH
in DMSO solution can be reversed many times and applied to the visual detection of F
−
. Finally,
PI-OH
film has been fabricated for real-time visualization of F
−
with high selectivity and sensitivity. The F
−
bonded to the
PI-OH
film can be easily removed by immersing it in acidic solution to recover the sensing ability to F
−
. X-ray photoelectron spectroscopy and energy dispersive spectroscopy analysis indicate that hydroxyl groups in the
PI-OH
film can bond to F
−
and the bonded F
−
can be removed quantitatively. This work provides not only a novel PI film-based sensor device for the visual and reversible detection of F
−
with high-efficiency, but also a promising F
−
extractor.
A novel hydroxyl-containing polyimide film has been designed and fabricated as a chemosensor for the real-time visualization of F
−
with high selectivity and sensitivity.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/c8py01697f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical sensors ; Chemical synthesis ; Chemoreceptors ; Colorimetry ; Hydroxyl groups ; Infrared spectroscopy ; Mathematical analysis ; NMR ; Nuclear magnetic resonance ; Photoelectrons ; Polymer chemistry ; Response time ; Selectivity ; Spectrum analysis ; Time dependence ; Titration</subject><ispartof>Polymer chemistry, 2019-03, Vol.1 (11), p.1399-146</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-564fbfb641bdc7bb45b0c717e76c63a2315eb0938956368bf67f8a3800e3e6ca3</citedby><cites>FETCH-LOGICAL-c281t-564fbfb641bdc7bb45b0c717e76c63a2315eb0938956368bf67f8a3800e3e6ca3</cites><orcidid>0000-0002-3211-1691 ; 0000-0002-9085-483X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wu, Yancheng</creatorcontrib><creatorcontrib>Shi, Chuqi</creatorcontrib><creatorcontrib>Chen, Zhigeng</creatorcontrib><creatorcontrib>Zhou, Yubin</creatorcontrib><creatorcontrib>Liu, Shumei</creatorcontrib><creatorcontrib>Zhao, Jianqing</creatorcontrib><title>A novel hydroxyl-containing polyimide as a colorimetric and ratiometric chemosensor for the reversible detection of fluoride ions</title><title>Polymer chemistry</title><description>A novel hydroxyl-containing polyimide (
PI-OH
) has been successfully synthesized and subsequently used as a new colorimetric and ratiometric chemosensor for the detection of F
−
with high selectivity and a fast response time. The ratiometric absorbance changes of the chemosensor
PI-OH
in DMSO solution show a linear response to F
−
in the concentration range of 0-0.50 mM with a detection limit of 1.79 μM, which provides a quantitative method for F
−
detection.
1
H NMR titration and DFT calculation studies confirm the F
−
sensing mechanism involves H-bond interactions and subsequent deprotonation in the chemosensor. Moreover, the chemosensor
PI-OH
in DMSO solution can be reversed many times and applied to the visual detection of F
−
. Finally,
PI-OH
film has been fabricated for real-time visualization of F
−
with high selectivity and sensitivity. The F
−
bonded to the
PI-OH
film can be easily removed by immersing it in acidic solution to recover the sensing ability to F
−
. X-ray photoelectron spectroscopy and energy dispersive spectroscopy analysis indicate that hydroxyl groups in the
PI-OH
film can bond to F
−
and the bonded F
−
can be removed quantitatively. This work provides not only a novel PI film-based sensor device for the visual and reversible detection of F
−
with high-efficiency, but also a promising F
−
extractor.
A novel hydroxyl-containing polyimide film has been designed and fabricated as a chemosensor for the real-time visualization of F
−
with high selectivity and sensitivity.</description><subject>Chemical sensors</subject><subject>Chemical synthesis</subject><subject>Chemoreceptors</subject><subject>Colorimetry</subject><subject>Hydroxyl groups</subject><subject>Infrared spectroscopy</subject><subject>Mathematical analysis</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Photoelectrons</subject><subject>Polymer chemistry</subject><subject>Response time</subject><subject>Selectivity</subject><subject>Spectrum analysis</subject><subject>Time dependence</subject><subject>Titration</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkUFLAzEQhYMoWGov3oWAN2E12ewmm2MpVoWCHvTgaUmyE5uy3dRkW9yj_9xoSx0YZgY-3jBvELqk5JYSJu9MtRkI5VLYEzSiopSZlDw_PfZlcY4mMa5ICkaLnPER-p7izu-gxcuhCf5raDPju165znUfeOPbwa1dA1hFrLDxrQ9uDX1wBquuwUH1zh9ms4S1j9BFH7BN2S8BB9hBiE63gBvowSS6w95i226TUJJNc7xAZ1a1ESaHOkZv8_vX2WO2eH54mk0Xmckr2mclL6y2mhdUN0ZoXZSaGEEFCG44UzmjJWgiWSVLznilLRe2UqwiBBhwo9gYXe91N8F_biH29cpvQ5dW1jmVhFZM0CJRN3vKBB9jAFtv0skqDDUl9a_L9ax6ef9zeZ7gqz0cojly_19gP70cfEA</recordid><startdate>20190321</startdate><enddate>20190321</enddate><creator>Wu, Yancheng</creator><creator>Shi, Chuqi</creator><creator>Chen, Zhigeng</creator><creator>Zhou, Yubin</creator><creator>Liu, Shumei</creator><creator>Zhao, Jianqing</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-3211-1691</orcidid><orcidid>https://orcid.org/0000-0002-9085-483X</orcidid></search><sort><creationdate>20190321</creationdate><title>A novel hydroxyl-containing polyimide as a colorimetric and ratiometric chemosensor for the reversible detection of fluoride ions</title><author>Wu, Yancheng ; Shi, Chuqi ; Chen, Zhigeng ; Zhou, Yubin ; Liu, Shumei ; Zhao, Jianqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-564fbfb641bdc7bb45b0c717e76c63a2315eb0938956368bf67f8a3800e3e6ca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemical sensors</topic><topic>Chemical synthesis</topic><topic>Chemoreceptors</topic><topic>Colorimetry</topic><topic>Hydroxyl groups</topic><topic>Infrared spectroscopy</topic><topic>Mathematical analysis</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Photoelectrons</topic><topic>Polymer chemistry</topic><topic>Response time</topic><topic>Selectivity</topic><topic>Spectrum analysis</topic><topic>Time dependence</topic><topic>Titration</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Yancheng</creatorcontrib><creatorcontrib>Shi, Chuqi</creatorcontrib><creatorcontrib>Chen, Zhigeng</creatorcontrib><creatorcontrib>Zhou, Yubin</creatorcontrib><creatorcontrib>Liu, Shumei</creatorcontrib><creatorcontrib>Zhao, Jianqing</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Yancheng</au><au>Shi, Chuqi</au><au>Chen, Zhigeng</au><au>Zhou, Yubin</au><au>Liu, Shumei</au><au>Zhao, Jianqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel hydroxyl-containing polyimide as a colorimetric and ratiometric chemosensor for the reversible detection of fluoride ions</atitle><jtitle>Polymer chemistry</jtitle><date>2019-03-21</date><risdate>2019</risdate><volume>1</volume><issue>11</issue><spage>1399</spage><epage>146</epage><pages>1399-146</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>A novel hydroxyl-containing polyimide (
PI-OH
) has been successfully synthesized and subsequently used as a new colorimetric and ratiometric chemosensor for the detection of F
−
with high selectivity and a fast response time. The ratiometric absorbance changes of the chemosensor
PI-OH
in DMSO solution show a linear response to F
−
in the concentration range of 0-0.50 mM with a detection limit of 1.79 μM, which provides a quantitative method for F
−
detection.
1
H NMR titration and DFT calculation studies confirm the F
−
sensing mechanism involves H-bond interactions and subsequent deprotonation in the chemosensor. Moreover, the chemosensor
PI-OH
in DMSO solution can be reversed many times and applied to the visual detection of F
−
. Finally,
PI-OH
film has been fabricated for real-time visualization of F
−
with high selectivity and sensitivity. The F
−
bonded to the
PI-OH
film can be easily removed by immersing it in acidic solution to recover the sensing ability to F
−
. X-ray photoelectron spectroscopy and energy dispersive spectroscopy analysis indicate that hydroxyl groups in the
PI-OH
film can bond to F
−
and the bonded F
−
can be removed quantitatively. This work provides not only a novel PI film-based sensor device for the visual and reversible detection of F
−
with high-efficiency, but also a promising F
−
extractor.
A novel hydroxyl-containing polyimide film has been designed and fabricated as a chemosensor for the real-time visualization of F
−
with high selectivity and sensitivity.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8py01697f</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-3211-1691</orcidid><orcidid>https://orcid.org/0000-0002-9085-483X</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1759-9954 |
ispartof | Polymer chemistry, 2019-03, Vol.1 (11), p.1399-146 |
issn | 1759-9954 1759-9962 |
language | eng |
recordid | cdi_crossref_primary_10_1039_C8PY01697F |
source | Royal Society Of Chemistry Journals 2008- |
subjects | Chemical sensors Chemical synthesis Chemoreceptors Colorimetry Hydroxyl groups Infrared spectroscopy Mathematical analysis NMR Nuclear magnetic resonance Photoelectrons Polymer chemistry Response time Selectivity Spectrum analysis Time dependence Titration |
title | A novel hydroxyl-containing polyimide as a colorimetric and ratiometric chemosensor for the reversible detection of fluoride ions |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T07%3A23%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20novel%20hydroxyl-containing%20polyimide%20as%20a%20colorimetric%20and%20ratiometric%20chemosensor%20for%20the%20reversible%20detection%20of%20fluoride%20ions&rft.jtitle=Polymer%20chemistry&rft.au=Wu,%20Yancheng&rft.date=2019-03-21&rft.volume=1&rft.issue=11&rft.spage=1399&rft.epage=146&rft.pages=1399-146&rft.issn=1759-9954&rft.eissn=1759-9962&rft_id=info:doi/10.1039/c8py01697f&rft_dat=%3Cproquest_cross%3E2190183714%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2190183714&rft_id=info:pmid/&rfr_iscdi=true |