Electrochemical sulfonylation of thiols with sulfonyl hydrazides: a metal- and oxidant-free protocol for the synthesis of thiosulfonates

An efficient electrochemical transformation of structurally diverse sulfonyl hydrazides and thiols into thiosulfonates in the presence of ammonium iodide as redox catalyst and electrolyte in acetonitrile at ambient temperature is reported. Transition metal- and oxidant-free conditions are the striki...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.2 (19), p.4428-4432
Hauptverfasser:	Mo, Zu-Yu, Swaroop, Toreshettahally R, Tong, Wei, Zhang, Yu-Zhen, Tang, Hai-Tao, Pan, Ying-Ming, Sun, Hong-Bin, Chen, Zhen-Feng
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Ambient temperature Ammonium Apoptosis Cancer Cell adhesion & migration Cell cycle Cell migration Cytotoxicity Electrochemistry Electrolytic cells Green chemistry Hydrazides Iodides Metals Polymerization Thiols Toxicity Tubulin Tumor cell lines Tumor cells
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