BINAP-copper supported by hydrotalcite as an efficient catalyst for the borrowing hydrogen reaction and dehydrogenation cyclization under water or solvent-free conditions
A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization. This BINAP-Cu complex supported by hydrotalcite is highly air-stable and can be recycled at least...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.2 (11), p.2571-2577 |
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| container_issue | 11 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Xu, Zhaojun Yu, Xiaoli Sang, Xinxin Wang, Dawei |
| description | A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization. This BINAP-Cu complex supported by hydrotalcite is highly air-stable and can be recycled at least five times under solvent-free conditions. Notably, 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives could be synthesized from alcohols in only one step with water as the solvent for the first time. This provided a much greener and efficient catalytic method towards the synthesis of functionalized amines, ketones and 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives with high yields under water or solvent-free conditions.
A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization. |
| doi_str_mv | 10.1039/c8gc00557e |
| format | Article |
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H
-benzo[
d
]imidazole derivatives could be synthesized from alcohols in only one step with water as the solvent for the first time. This provided a much greener and efficient catalytic method towards the synthesis of functionalized amines, ketones and 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives with high yields under water or solvent-free conditions.
A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/c8gc00557e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alcohols ; Amines ; Aromatic compounds ; Catalysis ; Catalysts ; Chemical synthesis ; Copper ; Dehydrogenation ; Derivatives ; Green chemistry ; Hydrogen storage ; Imidazole ; Ketones ; Solvents</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2018, Vol.2 (11), p.2571-2577</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-f834bc9d5f1c2a96f0bb9cdf2bb98f357238ab97647d98addc8936828d7370513</citedby><cites>FETCH-LOGICAL-c384t-f834bc9d5f1c2a96f0bb9cdf2bb98f357238ab97647d98addc8936828d7370513</cites><orcidid>0000-0002-2439-4302 ; 0000-0001-9327-7487</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Xu, Zhaojun</creatorcontrib><creatorcontrib>Yu, Xiaoli</creatorcontrib><creatorcontrib>Sang, Xinxin</creatorcontrib><creatorcontrib>Wang, Dawei</creatorcontrib><title>BINAP-copper supported by hydrotalcite as an efficient catalyst for the borrowing hydrogen reaction and dehydrogenation cyclization under water or solvent-free conditions</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization. This BINAP-Cu complex supported by hydrotalcite is highly air-stable and can be recycled at least five times under solvent-free conditions. Notably, 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives could be synthesized from alcohols in only one step with water as the solvent for the first time. This provided a much greener and efficient catalytic method towards the synthesis of functionalized amines, ketones and 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives with high yields under water or solvent-free conditions.
A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization.</description><subject>Alcohols</subject><subject>Amines</subject><subject>Aromatic compounds</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Copper</subject><subject>Dehydrogenation</subject><subject>Derivatives</subject><subject>Green chemistry</subject><subject>Hydrogen storage</subject><subject>Imidazole</subject><subject>Ketones</subject><subject>Solvents</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkU9LAzEQxRdRsFYv3oWAN2E1m-yf5FhLrYWiHvS8ZCdJu6Vu1iS1rB_JT2na1XrJDJPfm8fwougywbcJpvwO2AIwzrJCHUWDJM1pzEmBjw99Tk6jM-dWGCdJkaeD6Pt-9jR6icG0rbLIbdrWWK8kqjq07KQ1Xqyh9goJh0SDlNY11KrxCET46ZxH2ljklwpVxlqzrZtFr1uoBlklwNemCUqJpPqbi_0MOljXX32_aWQw3wof3rDOmfVn8Ii1VQqBaWS9o9x5dKLF2qmL3zqM3h4mr-PHeP48nY1H8xgoS4OK0bQCLjOdABE817iqOEhNQmGaZgWhTFQ8XF9IzoSUwDjNGWGyoAXOEjqMrvu9rTUfG-V8uTIb2wTLkuCUZ4xwkgbqpqfAGues0mVr63dhuzLB5S6Lcsym430WkwBf9bB1cOD-s6I_mOmK1w</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Xu, Zhaojun</creator><creator>Yu, Xiaoli</creator><creator>Sang, Xinxin</creator><creator>Wang, Dawei</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-2439-4302</orcidid><orcidid>https://orcid.org/0000-0001-9327-7487</orcidid></search><sort><creationdate>2018</creationdate><title>BINAP-copper supported by hydrotalcite as an efficient catalyst for the borrowing hydrogen reaction and dehydrogenation cyclization under water or solvent-free conditions</title><author>Xu, Zhaojun ; Yu, Xiaoli ; Sang, Xinxin ; Wang, Dawei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-f834bc9d5f1c2a96f0bb9cdf2bb98f357238ab97647d98addc8936828d7370513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alcohols</topic><topic>Amines</topic><topic>Aromatic compounds</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Copper</topic><topic>Dehydrogenation</topic><topic>Derivatives</topic><topic>Green chemistry</topic><topic>Hydrogen storage</topic><topic>Imidazole</topic><topic>Ketones</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Zhaojun</creatorcontrib><creatorcontrib>Yu, Xiaoli</creatorcontrib><creatorcontrib>Sang, Xinxin</creatorcontrib><creatorcontrib>Wang, Dawei</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Zhaojun</au><au>Yu, Xiaoli</au><au>Sang, Xinxin</au><au>Wang, Dawei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>BINAP-copper supported by hydrotalcite as an efficient catalyst for the borrowing hydrogen reaction and dehydrogenation cyclization under water or solvent-free conditions</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2018</date><risdate>2018</risdate><volume>2</volume><issue>11</issue><spage>2571</spage><epage>2577</epage><pages>2571-2577</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization. This BINAP-Cu complex supported by hydrotalcite is highly air-stable and can be recycled at least five times under solvent-free conditions. Notably, 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives could be synthesized from alcohols in only one step with water as the solvent for the first time. This provided a much greener and efficient catalytic method towards the synthesis of functionalized amines, ketones and 1-benzyl-2-aryl-1
H
-benzo[
d
]imidazole derivatives with high yields under water or solvent-free conditions.
A BINAP-Cu system supported by hydrotalcite has been developed and proved to be a highly efficient catalyst for the atom-efficient and green borrowing hydrogen reaction and dehydrogenative cyclization.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8gc00557e</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-2439-4302</orcidid><orcidid>https://orcid.org/0000-0001-9327-7487</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2018, Vol.2 (11), p.2571-2577 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8GC00557E |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alcohols Amines Aromatic compounds Catalysis Catalysts Chemical synthesis Copper Dehydrogenation Derivatives Green chemistry Hydrogen storage Imidazole Ketones Solvents |
| title | BINAP-copper supported by hydrotalcite as an efficient catalyst for the borrowing hydrogen reaction and dehydrogenation cyclization under water or solvent-free conditions |
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