A non-innocent pincer H 3 L ONS ligand and its corresponding octahedral low-spin Fe(iii) complex formation via ligand-centric homolytic S-S bond scission
In the presence of FeCl3 and Et3N, a ligand H4Ldtda(AP) underwent S-S bond cleavage and generated a pincer non-innocent H3LONS ligand, which formed a homoleptic, six-coordinate, low-spin Fe(iii) complex (1). The complex comprised two 2-iminobenzosemiquinone (1-) π-radicals and one thiyl π-radical.
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018-10, Vol.47 (38), p.13337-13341 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | In the presence of FeCl3 and Et3N, a ligand H4Ldtda(AP) underwent S-S bond cleavage and generated a pincer non-innocent H3LONS ligand, which formed a homoleptic, six-coordinate, low-spin Fe(iii) complex (1). The complex comprised two 2-iminobenzosemiquinone (1-) π-radicals and one thiyl π-radical. |
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| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/C8DT02763C |