Ten-fold boost of catalytic performance in thiol-yne click reaction enabled by a palladium diketonate complex with a hexafluoroacetylacetonate ligand

Palladium complexes with fluorinated acetylacetonate chelating ligands were studied as catalysts for alkyne hydrothiolation. A ten-fold increase in the catalytic efficiency was achieved by using 0.1 mol% of Pd(hfpd) 2 complex (hfpd = hexafluoroacetylacetonate) with a variety of thiol-yne coupling pa...

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Veröffentlicht in:	Catalysis science & technology 2018, Vol.8 (12), p.373-38
Hauptverfasser:	Eremin, Dmitry B, Boiko, Daniil A, Borkovskaya, Eugenia V, Khrustalev, Victor N, Chernyshev, Victor M, Ananikov, Valentine P
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene Alkynes Catalysis Catalysts Chelation Chemical reactions Coordination compounds Fluorination Ligands Palladium
Online-Zugang:	Volltext
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