Conformation of bis-nitroxide polarizing agents by multi-frequency EPR spectroscopy

The chemical structure of polarizing agents critically determines the efficiency of dynamic nuclear polarization (DNP). For cross-effect DNP, biradicals are the polarizing agents of choice and the interaction and relative orientation of the two unpaired electrons should be optimal. Both parameters a...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2018-10, Vol.2 (39), p.2556-25517
Hauptverfasser:	Soetbeer, Janne, Gast, Peter, Walish, Joseph J, Zhao, Yanchuan, George, Christy, Yang, Chen, Swager, Timothy M, Griffin, Robert G, Mathies, Guinevere
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography Electrons Molecular structure NMR spectroscopy Organic chemistry Polarization Spectrum analysis
Online-Zugang:	Volltext
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