Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn() coordination polymer
1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal-organic framework (MOF) [Zn 2 (H 2 O) 2 (Amal) 2 (bpe)] to produce a 3D MOF with a new topology. 1,2-Bis(pyrid-4-yl)ethylene (red) and 2-allylmalonate (b...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-12, Vol.54 (98), p.13861-13864 |
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| container_issue | 98 |
| container_start_page | 13861 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 54 |
| creator | Volodin, Alexander D Korlyukov, Alexander A Zorina-Tikhonova, Ekaterina N Chistyakov, Aleksandr S Sidorov, Aleksei A Eremenko, Igor L Vologzhanina, Anna V |
| description | 1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal-organic framework (MOF) [Zn
2
(H
2
O)
2
(Amal)
2
(bpe)] to produce a 3D MOF with a new topology.
1,2-Bis(pyrid-4-yl)ethylene (red) and 2-allylmalonate (blue) undergo a photoinitiated [2+2] crossed cycloaddition reaction in a 3D coordination polymer, accompanied with significant atomic movement and crystal decomposition. |
| doi_str_mv | 10.1039/c8cc07734g |
| format | Article |
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2
(H
2
O)
2
(Amal)
2
(bpe)] to produce a 3D MOF with a new topology.
1,2-Bis(pyrid-4-yl)ethylene (red) and 2-allylmalonate (blue) undergo a photoinitiated [2+2] crossed cycloaddition reaction in a 3D coordination polymer, accompanied with significant atomic movement and crystal decomposition.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc07734g</identifier><identifier>PMID: 30474654</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Alkenes ; Coordination polymers ; Crystallography ; Cycloaddition ; Metal-organic frameworks ; NMR ; Nuclear magnetic resonance ; Stereoselectivity ; X-ray diffraction</subject><ispartof>Chemical communications (Cambridge, England), 2018-12, Vol.54 (98), p.13861-13864</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-1dd0f7a6571c5d51ce6b67fcf7b132db728a5356f937743c3f909369edd050c63</citedby><cites>FETCH-LOGICAL-c337t-1dd0f7a6571c5d51ce6b67fcf7b132db728a5356f937743c3f909369edd050c63</cites><orcidid>0000-0002-5600-9886 ; 0000-0002-6456-9584 ; 0000-0002-3522-9193 ; 0000-0001-6861-1404 ; 0000-0002-6228-303X ; 0000-0002-4284-8451</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30474654$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Volodin, Alexander D</creatorcontrib><creatorcontrib>Korlyukov, Alexander A</creatorcontrib><creatorcontrib>Zorina-Tikhonova, Ekaterina N</creatorcontrib><creatorcontrib>Chistyakov, Aleksandr S</creatorcontrib><creatorcontrib>Sidorov, Aleksei A</creatorcontrib><creatorcontrib>Eremenko, Igor L</creatorcontrib><creatorcontrib>Vologzhanina, Anna V</creatorcontrib><title>Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn() coordination polymer</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal-organic framework (MOF) [Zn
2
(H
2
O)
2
(Amal)
2
(bpe)] to produce a 3D MOF with a new topology.
1,2-Bis(pyrid-4-yl)ethylene (red) and 2-allylmalonate (blue) undergo a photoinitiated [2+2] crossed cycloaddition reaction in a 3D coordination polymer, accompanied with significant atomic movement and crystal decomposition.</description><subject>Alkenes</subject><subject>Coordination polymers</subject><subject>Crystallography</subject><subject>Cycloaddition</subject><subject>Metal-organic frameworks</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Stereoselectivity</subject><subject>X-ray diffraction</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0ctr3DAQB2ARWpI07aX3BEEvScGN5NHDPgbnCQu5tBB6MVpp1Ch4ra3kLex_X-1uHhBdRkifhuEnQr5y9oMzaM9tYy3TGsSfPXLIQYlKiubhw2Yv26qcywPyKecnVhaXzT45ACa0UFIcEn8ZTJ4wYcw4oJ3CP6Q5DsFVeTITUptizujo8jFO0a7tEI1zYQpxpNHTOKAPY6ZhpIbCJf09np5RG2NyYTRbtIzDeoHpM_nozZDxy3M9Ir-ur352t9Xs_uauu5hVFkBPFXeOeW2U1NxKJ7lFNVfaW6_nHGo313VjJEjlW9BagAXfshZUi-WdZFbBETnd9V2m-HeFeeoXIVscBjNiXOW-5tAwUQsNhX57R5_iKo1luqIkA1krKYv6vlPbIBL6fpnCwqR1z1m_Sb_vmq7bpn9T8Mlzy9V8ge6VvsRdwPEOpGxfb9--D_4DomuJYA</recordid><startdate>20181206</startdate><enddate>20181206</enddate><creator>Volodin, Alexander D</creator><creator>Korlyukov, Alexander A</creator><creator>Zorina-Tikhonova, Ekaterina N</creator><creator>Chistyakov, Aleksandr S</creator><creator>Sidorov, Aleksei A</creator><creator>Eremenko, Igor L</creator><creator>Vologzhanina, Anna V</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5600-9886</orcidid><orcidid>https://orcid.org/0000-0002-6456-9584</orcidid><orcidid>https://orcid.org/0000-0002-3522-9193</orcidid><orcidid>https://orcid.org/0000-0001-6861-1404</orcidid><orcidid>https://orcid.org/0000-0002-6228-303X</orcidid><orcidid>https://orcid.org/0000-0002-4284-8451</orcidid></search><sort><creationdate>20181206</creationdate><title>Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn() coordination polymer</title><author>Volodin, Alexander D ; Korlyukov, Alexander A ; Zorina-Tikhonova, Ekaterina N ; Chistyakov, Aleksandr S ; Sidorov, Aleksei A ; Eremenko, Igor L ; Vologzhanina, Anna V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-1dd0f7a6571c5d51ce6b67fcf7b132db728a5356f937743c3f909369edd050c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alkenes</topic><topic>Coordination polymers</topic><topic>Crystallography</topic><topic>Cycloaddition</topic><topic>Metal-organic frameworks</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Stereoselectivity</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Volodin, Alexander D</creatorcontrib><creatorcontrib>Korlyukov, Alexander A</creatorcontrib><creatorcontrib>Zorina-Tikhonova, Ekaterina N</creatorcontrib><creatorcontrib>Chistyakov, Aleksandr S</creatorcontrib><creatorcontrib>Sidorov, Aleksei A</creatorcontrib><creatorcontrib>Eremenko, Igor L</creatorcontrib><creatorcontrib>Vologzhanina, Anna V</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Volodin, Alexander D</au><au>Korlyukov, Alexander A</au><au>Zorina-Tikhonova, Ekaterina N</au><au>Chistyakov, Aleksandr S</au><au>Sidorov, Aleksei A</au><au>Eremenko, Igor L</au><au>Vologzhanina, Anna V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn() coordination polymer</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2018-12-06</date><risdate>2018</risdate><volume>54</volume><issue>98</issue><spage>13861</spage><epage>13864</epage><pages>13861-13864</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal-organic framework (MOF) [Zn
2
(H
2
O)
2
(Amal)
2
(bpe)] to produce a 3D MOF with a new topology.
1,2-Bis(pyrid-4-yl)ethylene (red) and 2-allylmalonate (blue) undergo a photoinitiated [2+2] crossed cycloaddition reaction in a 3D coordination polymer, accompanied with significant atomic movement and crystal decomposition.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30474654</pmid><doi>10.1039/c8cc07734g</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5600-9886</orcidid><orcidid>https://orcid.org/0000-0002-6456-9584</orcidid><orcidid>https://orcid.org/0000-0002-3522-9193</orcidid><orcidid>https://orcid.org/0000-0001-6861-1404</orcidid><orcidid>https://orcid.org/0000-0002-6228-303X</orcidid><orcidid>https://orcid.org/0000-0002-4284-8451</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018-12, Vol.54 (98), p.13861-13864 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8CC07734G |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Alkenes Coordination polymers Crystallography Cycloaddition Metal-organic frameworks NMR Nuclear magnetic resonance Stereoselectivity X-ray diffraction |
| title | Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn() coordination polymer |
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