MIL-100Cr with open Cr sites for a record N 2 O capture
Nitrous oxide (N2O) is considered as the third most important greenhouse gas after carbon dioxide and methane and needs to be removed from air. Herein, we reported the metal-organic framework MIL-100Cr with open Cr sites for record N2O capture capacities of 5.78 mmol g-1 at 298 K and 8.25 mmol g-1 a...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-12, Vol.54 (100), p.14061-14064 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 54 |
| creator | Yang, Jiangfeng Du, Bingjie Liu, Jiaqi Krishna, Rajamani Zhang, Feifei Zhou, Wei Wang, Yong Li, Jinping Chen, Banglin |
| description | Nitrous oxide (N2O) is considered as the third most important greenhouse gas after carbon dioxide and methane and needs to be removed from air. Herein, we reported the metal-organic framework MIL-100Cr with open Cr sites for record N2O capture capacities of 5.78 mmol g-1 at 298 K and 8.25 mmol g-1 at 273 K, respectively. DFT calculations showed that the static binding energy of N2O on the open-Cr site is notably higher than that of N2, 72.5 kJ mol-1vs. 51.6 kJ mol-1, which enforces MIL-100Cr to exhibit extremely high N2O/N2 ideal adsorbed solution theory (IAST) gas separation selectivity up to 1000. |
| doi_str_mv | 10.1039/c8cc07679k |
| format | Article |
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Herein, we reported the metal-organic framework MIL-100Cr with open Cr sites for record N2O capture capacities of 5.78 mmol g-1 at 298 K and 8.25 mmol g-1 at 273 K, respectively. 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Herein, we reported the metal-organic framework MIL-100Cr with open Cr sites for record N2O capture capacities of 5.78 mmol g-1 at 298 K and 8.25 mmol g-1 at 273 K, respectively. DFT calculations showed that the static binding energy of N2O on the open-Cr site is notably higher than that of N2, 72.5 kJ mol-1vs. 51.6 kJ mol-1, which enforces MIL-100Cr to exhibit extremely high N2O/N2 ideal adsorbed solution theory (IAST) gas separation selectivity up to 1000.</abstract><cop>England</cop><pmid>30451265</pmid><doi>10.1039/c8cc07679k</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-4784-8530</orcidid><orcidid>https://orcid.org/0000-0003-0135-2203</orcidid><orcidid>https://orcid.org/0000-0002-5461-3617</orcidid><orcidid>https://orcid.org/0000-0002-2628-0376</orcidid><orcidid>https://orcid.org/0000-0001-8707-8115</orcidid></addata></record> |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | MIL-100Cr with open Cr sites for a record N 2 O capture |
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