The perfluorinated alcohols c-C 6 F 11 OH, c-C 6 F 10 -1,1-(OH) 2 and c-C 6 F 10 -1-(CF 3 )OH

The perfluorinated alcohols c-C 6 F 11 OH, c-C 6 F 10 -1,1-(OH) 2 and c-C 6 F 10 -1-(CF 3 )OH

The thermally unstable α-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone. c-C6F10(CF3)OH was obtained by protonation of its alkoxide [NMe4]+[C7F13O]-. Decafluorocyclohexane-1,1-diol (c-C6F10(OH)2) was prepared by acidic wor...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018-07, Vol.54 (67), p.9294-9297
Hauptverfasser: Schaab, Jonas, Schwab, Miriam, Kratzert, Daniel, Schwabedissen, Jan, Stammler, Hans-Georg, Mitzel, Norbert W, Krossing, Ingo
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container_end_page 9297
container_issue 67
container_start_page 9294
container_title Chemical communications (Cambridge, England)
container_volume 54
creator Schaab, Jonas
Schwab, Miriam
Kratzert, Daniel
Schwabedissen, Jan
Stammler, Hans-Georg
Mitzel, Norbert W
Krossing, Ingo
description The thermally unstable α-fluoroalcohol undecafluorocyclohexanol (c-C6F11OH) was prepared by addition of hydrogen fluoride to the corresponding ketone. c-C6F10(CF3)OH was obtained by protonation of its alkoxide [NMe4]+[C7F13O]-. Decafluorocyclohexane-1,1-diol (c-C6F10(OH)2) was prepared by acidic workup of the corresponding alkoxide [NMe4]+[C6F11O]- with sulfuric acid, which yielded (c-C6F10(OH)2) and fluorosulfonic acid. The structures of c-C6F10(CF3)OH·2H2O and of (c-C6F10(OH)2) were elucidated by single-crystal X-ray and gas-phase electron-diffraction studies.
doi_str_mv 10.1039/C8CC05148H
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title The perfluorinated alcohols c-C 6 F 11 OH, c-C 6 F 10 -1,1-(OH) 2 and c-C 6 F 10 -1-(CF 3 )OH
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