Cu 2 (BDC) 2 (BPY)–MOF: an efficient and reusable heterogeneous catalyst for the aerobic Chan–Lam coupling prepared via ball-milling strategy
Nanoporous Cu 2 (BDC) 2 (BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the sy...
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| Veröffentlicht in: | RSC advances 2017, Vol.7 (73), p.46022-46027 |
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| container_title | RSC advances |
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| creator | Khosravi, Armaqan Mokhtari, Javad Naimi-Jamal, Mohammad Reza Tahmasebi, Sharareh Panahi, Leila |
| description | Nanoporous Cu
2
(BDC)
2
(BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal–organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu
2
(BDC)
2
(BPY) were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) surface area analysis. |
| doi_str_mv | 10.1039/C7RA09772G |
| format | Article |
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2
(BDC)
2
(BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal–organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu
2
(BDC)
2
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2
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2
(BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal–organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu
2
(BDC)
2
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2
(BDC)
2
(BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal–organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu
2
(BDC)
2
(BPY) were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) surface area analysis.</abstract><doi>10.1039/C7RA09772G</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-8512-9513</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2017, Vol.7 (73), p.46022-46027 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C7RA09772G |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| title | Cu 2 (BDC) 2 (BPY)–MOF: an efficient and reusable heterogeneous catalyst for the aerobic Chan–Lam coupling prepared via ball-milling strategy |
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