Facile synthesis of novel hybrid POSS biomolecules via “Click” reactions

Facile synthesis of novel hybrid POSS biomolecules via “Click” reactions

A novel alkyne-terminated cubic-octameric POSS was synthesised in high yield (82–90%). The X-ray crystal structure revealed intra- and intermolecular hydrogen bonding between the amide groups of the arms. Hybrid biomaterials were synthesised in nearly quantitative yields via a click reaction with (i...

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Veröffentlicht in:RSC advances 2017, Vol.7 (59), p.37474-37477
Hauptverfasser: El Aziz, Youssef, Mehrban, Nazia, Taylor, Peter G., Birchall, Martin A., Bowen, James, Bassindale, Alan R., Pitak, Mateusz B., Coles, Simon J.
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container_end_page 37477
container_issue 59
container_start_page 37474
container_title RSC advances
container_volume 7
creator El Aziz, Youssef
Mehrban, Nazia
Taylor, Peter G.
Birchall, Martin A.
Bowen, James
Bassindale, Alan R.
Pitak, Mateusz B.
Coles, Simon J.
description A novel alkyne-terminated cubic-octameric POSS was synthesised in high yield (82–90%). The X-ray crystal structure revealed intra- and intermolecular hydrogen bonding between the amide groups of the arms. Hybrid biomaterials were synthesised in nearly quantitative yields via a click reaction with (i) azido- N -Fmoc-norleucine and (ii) 3′-azido-3′-deoxythymidine.
doi_str_mv 10.1039/C7RA07915J
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title Facile synthesis of novel hybrid POSS biomolecules via “Click” reactions
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