Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells
Comprehensive studies were carried out to understand the origin of the current hysteresis effects in highly efficient C -CH NH PbI (MAPbI ) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-r...
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Veröffentlicht in: | Nanoscale 2017-11, Vol.9 (45), p.17802-17806 |
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container_title | Nanoscale |
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creator | Chen, Lung-Chien Lin, Yu-Shiang Tang, Po-Wen Tai, Chao-Yi Tseng, Zong-Liang Lin, Ja-Hon Chen, Sheng-Hui Kuo, Hao-Chung |
description | Comprehensive studies were carried out to understand the origin of the current hysteresis effects in highly efficient C
-CH
NH
PbI
(MAPbI
) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-resolved pump-probe technique. The power conversion efficiency (PCE) of C
-MAPbI
solar cells can be increased to 18.23% by eliminating the point (lattice) defects in the MAPbI
thin film which is fabricated by using the one-step spin-coating method with toluene washing treatment. The experimental results show that the point defects and surface defects of the MAPbI
thin films can be minimized by varying the dropping time of the washing solvent. The point defects (surface defects) can be reduced with an (a) increase (decrease) in the dropping time, resulting in an optimized dropping time for obtaining the defect-minimized MAPbI
thin film deposited on top of the C
thin film. Consequently, the formation of the defect-minimized MAPbI
thin film allows for high-efficiency MAPbI
solar cells. |
doi_str_mv | 10.1039/C7NR07001B |
format | Article |
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-CH
NH
PbI
(MAPbI
) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-resolved pump-probe technique. The power conversion efficiency (PCE) of C
-MAPbI
solar cells can be increased to 18.23% by eliminating the point (lattice) defects in the MAPbI
thin film which is fabricated by using the one-step spin-coating method with toluene washing treatment. The experimental results show that the point defects and surface defects of the MAPbI
thin films can be minimized by varying the dropping time of the washing solvent. The point defects (surface defects) can be reduced with an (a) increase (decrease) in the dropping time, resulting in an optimized dropping time for obtaining the defect-minimized MAPbI
thin film deposited on top of the C
thin film. Consequently, the formation of the defect-minimized MAPbI
thin film allows for high-efficiency MAPbI
solar cells.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/C7NR07001B</identifier><identifier>PMID: 29115332</identifier><language>eng</language><publisher>England</publisher><ispartof>Nanoscale, 2017-11, Vol.9 (45), p.17802-17806</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c992-5b34bd60f517a5537a0c16d02e83effdfbf5667bbd81664cc24f41a30a24e7723</citedby><cites>FETCH-LOGICAL-c992-5b34bd60f517a5537a0c16d02e83effdfbf5667bbd81664cc24f41a30a24e7723</cites><orcidid>0000-0001-5470-8491</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29115332$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Lung-Chien</creatorcontrib><creatorcontrib>Lin, Yu-Shiang</creatorcontrib><creatorcontrib>Tang, Po-Wen</creatorcontrib><creatorcontrib>Tai, Chao-Yi</creatorcontrib><creatorcontrib>Tseng, Zong-Liang</creatorcontrib><creatorcontrib>Lin, Ja-Hon</creatorcontrib><creatorcontrib>Chen, Sheng-Hui</creatorcontrib><creatorcontrib>Kuo, Hao-Chung</creatorcontrib><title>Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Comprehensive studies were carried out to understand the origin of the current hysteresis effects in highly efficient C
-CH
NH
PbI
(MAPbI
) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-resolved pump-probe technique. The power conversion efficiency (PCE) of C
-MAPbI
solar cells can be increased to 18.23% by eliminating the point (lattice) defects in the MAPbI
thin film which is fabricated by using the one-step spin-coating method with toluene washing treatment. The experimental results show that the point defects and surface defects of the MAPbI
thin films can be minimized by varying the dropping time of the washing solvent. The point defects (surface defects) can be reduced with an (a) increase (decrease) in the dropping time, resulting in an optimized dropping time for obtaining the defect-minimized MAPbI
thin film deposited on top of the C
thin film. Consequently, the formation of the defect-minimized MAPbI
thin film allows for high-efficiency MAPbI
solar cells.</description><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNpFkE1Lw0AQhhdRbK1e_AGyZyE6-5Hd5qhBbaFUkXoOm81sm5ImZTcR8u9NqdbLO3N43mF4CLll8MBAJI-pXn6CBmDPZ2TMQUIkhObnp13JEbkKYQugEqHEJRnxhLFYCD4m7qv25hursl5T23mPdUs3fWjRYygDRefQtoGWNfW47irjo7bfI02pAhqlMyro8hAf-XzIDQ69ZtvVti2bmoZm4KnFqgrX5MKZKuDN75yQ1evLKp1Fi_e3efq0iGyS8CjOhcwLBS5m2sSx0AYsUwVwnIrhk8LlLlZK53kxZUpJa7l0khkBhkvUmosJuT-etb4JwaPL9r7cGd9nDLKDq-zf1QDfHeF9l--wOKF_csQPl6hixQ</recordid><startdate>20171123</startdate><enddate>20171123</enddate><creator>Chen, Lung-Chien</creator><creator>Lin, Yu-Shiang</creator><creator>Tang, Po-Wen</creator><creator>Tai, Chao-Yi</creator><creator>Tseng, Zong-Liang</creator><creator>Lin, Ja-Hon</creator><creator>Chen, Sheng-Hui</creator><creator>Kuo, Hao-Chung</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-5470-8491</orcidid></search><sort><creationdate>20171123</creationdate><title>Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells</title><author>Chen, Lung-Chien ; Lin, Yu-Shiang ; Tang, Po-Wen ; Tai, Chao-Yi ; Tseng, Zong-Liang ; Lin, Ja-Hon ; Chen, Sheng-Hui ; Kuo, Hao-Chung</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c992-5b34bd60f517a5537a0c16d02e83effdfbf5667bbd81664cc24f41a30a24e7723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Lung-Chien</creatorcontrib><creatorcontrib>Lin, Yu-Shiang</creatorcontrib><creatorcontrib>Tang, Po-Wen</creatorcontrib><creatorcontrib>Tai, Chao-Yi</creatorcontrib><creatorcontrib>Tseng, Zong-Liang</creatorcontrib><creatorcontrib>Lin, Ja-Hon</creatorcontrib><creatorcontrib>Chen, Sheng-Hui</creatorcontrib><creatorcontrib>Kuo, Hao-Chung</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Lung-Chien</au><au>Lin, Yu-Shiang</au><au>Tang, Po-Wen</au><au>Tai, Chao-Yi</au><au>Tseng, Zong-Liang</au><au>Lin, Ja-Hon</au><au>Chen, Sheng-Hui</au><au>Kuo, Hao-Chung</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2017-11-23</date><risdate>2017</risdate><volume>9</volume><issue>45</issue><spage>17802</spage><epage>17806</epage><pages>17802-17806</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Comprehensive studies were carried out to understand the origin of the current hysteresis effects in highly efficient C
-CH
NH
PbI
(MAPbI
) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-resolved pump-probe technique. The power conversion efficiency (PCE) of C
-MAPbI
solar cells can be increased to 18.23% by eliminating the point (lattice) defects in the MAPbI
thin film which is fabricated by using the one-step spin-coating method with toluene washing treatment. The experimental results show that the point defects and surface defects of the MAPbI
thin films can be minimized by varying the dropping time of the washing solvent. The point defects (surface defects) can be reduced with an (a) increase (decrease) in the dropping time, resulting in an optimized dropping time for obtaining the defect-minimized MAPbI
thin film deposited on top of the C
thin film. Consequently, the formation of the defect-minimized MAPbI
thin film allows for high-efficiency MAPbI
solar cells.</abstract><cop>England</cop><pmid>29115332</pmid><doi>10.1039/C7NR07001B</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-5470-8491</orcidid></addata></record> |
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language | eng |
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source | Royal Society Of Chemistry Journals 2008- |
title | Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells |
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