Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells

Comprehensive studies were carried out to understand the origin of the current hysteresis effects in highly efficient C -CH NH PbI (MAPbI ) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-r...

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Veröffentlicht in:Nanoscale 2017-11, Vol.9 (45), p.17802-17806
Hauptverfasser: Chen, Lung-Chien, Lin, Yu-Shiang, Tang, Po-Wen, Tai, Chao-Yi, Tseng, Zong-Liang, Lin, Ja-Hon, Chen, Sheng-Hui, Kuo, Hao-Chung
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container_end_page 17806
container_issue 45
container_start_page 17802
container_title Nanoscale
container_volume 9
creator Chen, Lung-Chien
Lin, Yu-Shiang
Tang, Po-Wen
Tai, Chao-Yi
Tseng, Zong-Liang
Lin, Ja-Hon
Chen, Sheng-Hui
Kuo, Hao-Chung
description Comprehensive studies were carried out to understand the origin of the current hysteresis effects in highly efficient C -CH NH PbI (MAPbI ) heterojunction solar cells, using atomic-force microscopy, transmittance spectra, photoluminescence spectra, X-ray diffraction patterns and a femtosecond time-resolved pump-probe technique. The power conversion efficiency (PCE) of C -MAPbI solar cells can be increased to 18.23% by eliminating the point (lattice) defects in the MAPbI thin film which is fabricated by using the one-step spin-coating method with toluene washing treatment. The experimental results show that the point defects and surface defects of the MAPbI thin films can be minimized by varying the dropping time of the washing solvent. The point defects (surface defects) can be reduced with an (a) increase (decrease) in the dropping time, resulting in an optimized dropping time for obtaining the defect-minimized MAPbI thin film deposited on top of the C thin film. Consequently, the formation of the defect-minimized MAPbI thin film allows for high-efficiency MAPbI solar cells.
doi_str_mv 10.1039/C7NR07001B
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title Unraveling current hysteresis effects in regular-type C 60 -CH 3 NH 3 PbI 3 heterojunction solar cells
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