First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquids. An electrochemical and chemical study on the role of temperature
Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120 °C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was confirmed by the formation of a PhCHO–NHC adduct...
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| Veröffentlicht in: | New journal of chemistry 2017, Vol.41 (16), p.7840-7843 |
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| container_end_page | 7843 |
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| container_issue | 16 |
| container_start_page | 7840 |
| container_title | New journal of chemistry |
| container_volume | 41 |
| creator | Chiarotto, I. Feroci, M. Inesi, A. |
| description | Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120 °C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was confirmed by the formation of a PhCHO–NHC adduct in the pure ionic liquid. The role of the temperature was considered. |
| doi_str_mv | 10.1039/C7NJ00779E |
| format | Article |
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| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2017, Vol.41 (16), p.7840-7843 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C7NJ00779E |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquids. An electrochemical and chemical study on the role of temperature |
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