Synthesis and spectroscopic characterization of alkali-metal intercalated ZrSe 2
We report on the synthesis and spectroscopic characterization of alkali metal intercalated ZrSe single crystals. ZrSe is produced by chemical vapour transport and then Li is intercalated. Intercalation is performed from the liquid phase (via butyllithium) and from the vapour phase. Raman spectroscop...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018-02, Vol.47 (9), p.2986-2991 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 47 |
| creator | Nikonov, Konstantin Ehlen, Niels Senkovskiy, Boris Saigal, Nihit Fedorov, Alexander Nefedov, Alexei Wöll, Christof Di Santo, Giovanni Petaccia, Luca Grüneis, Alexander |
| description | We report on the synthesis and spectroscopic characterization of alkali metal intercalated ZrSe
single crystals. ZrSe
is produced by chemical vapour transport and then Li is intercalated. Intercalation is performed from the liquid phase (via butyllithium) and from the vapour phase. Raman spectroscopy of intercalated ZrSe
reveals phonon energy shifts of the Raman active A
and E
phonon modes, the disappearance of two-phonon modes and new low wavenumber Raman modes. Angle-resolved photoemission spectroscopy is used to perform a mapping of the Fermi surface revealing an electron concentration of 4.7 × 10
cm
. We also perform vapour phase intercalation of K and Cs into ZrSe
and observe similar changes in the Raman modes as for the Li case. |
| doi_str_mv | 10.1039/c7dt03756b |
| format | Article |
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single crystals. ZrSe
is produced by chemical vapour transport and then Li is intercalated. Intercalation is performed from the liquid phase (via butyllithium) and from the vapour phase. Raman spectroscopy of intercalated ZrSe
reveals phonon energy shifts of the Raman active A
and E
phonon modes, the disappearance of two-phonon modes and new low wavenumber Raman modes. Angle-resolved photoemission spectroscopy is used to perform a mapping of the Fermi surface revealing an electron concentration of 4.7 × 10
cm
. We also perform vapour phase intercalation of K and Cs into ZrSe
and observe similar changes in the Raman modes as for the Li case.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt03756b</identifier><identifier>PMID: 29215105</identifier><language>eng</language><publisher>England</publisher><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2018-02, Vol.47 (9), p.2986-2991</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c995-fd533fe340cf8e5ef59b18a8f6c546811fd42aa064e19487fc7a0067eb0787b33</citedby><cites>FETCH-LOGICAL-c995-fd533fe340cf8e5ef59b18a8f6c546811fd42aa064e19487fc7a0067eb0787b33</cites><orcidid>0000-0003-1443-6780 ; 0000-0003-2771-6386 ; 0000-0003-2448-6060 ; 0000-0001-8698-1468 ; 0000-0003-1078-3304</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29215105$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nikonov, Konstantin</creatorcontrib><creatorcontrib>Ehlen, Niels</creatorcontrib><creatorcontrib>Senkovskiy, Boris</creatorcontrib><creatorcontrib>Saigal, Nihit</creatorcontrib><creatorcontrib>Fedorov, Alexander</creatorcontrib><creatorcontrib>Nefedov, Alexei</creatorcontrib><creatorcontrib>Wöll, Christof</creatorcontrib><creatorcontrib>Di Santo, Giovanni</creatorcontrib><creatorcontrib>Petaccia, Luca</creatorcontrib><creatorcontrib>Grüneis, Alexander</creatorcontrib><title>Synthesis and spectroscopic characterization of alkali-metal intercalated ZrSe 2</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>We report on the synthesis and spectroscopic characterization of alkali metal intercalated ZrSe
single crystals. ZrSe
is produced by chemical vapour transport and then Li is intercalated. Intercalation is performed from the liquid phase (via butyllithium) and from the vapour phase. Raman spectroscopy of intercalated ZrSe
reveals phonon energy shifts of the Raman active A
and E
phonon modes, the disappearance of two-phonon modes and new low wavenumber Raman modes. Angle-resolved photoemission spectroscopy is used to perform a mapping of the Fermi surface revealing an electron concentration of 4.7 × 10
cm
. We also perform vapour phase intercalation of K and Cs into ZrSe
and observe similar changes in the Raman modes as for the Li case.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9kEtLw0AUhQdRbK1u_AEyayE6z0xmqfEJBYV25SbcTO7Q0TQJmXFRf73Valf3wP04HD5Czjm74kzaa2eaxKTReX1AplwZk1kh1eE-i3xCTmJ8Z0wIpsUxmQgruOZMT8nrYtOlFcYQKXQNjQO6NPbR9UNw1K1gBJdwDF-QQt_R3lNoP6AN2RoTtDR026eDFhI29G1cIBWn5MhDG_Hs787I8uF-WT5l85fH5_JmnjlrdeYbLaVHqZjzBWr02ta8gMLnTqu84Nw3SgCwXCG3qjDeGWAsN1gzU5hayhm53NW67do4oq-GMaxh3FScVT9WqtLcLX-t3G7hix08fNZrbPbovwb5DeNGXdI</recordid><startdate>20180227</startdate><enddate>20180227</enddate><creator>Nikonov, Konstantin</creator><creator>Ehlen, Niels</creator><creator>Senkovskiy, Boris</creator><creator>Saigal, Nihit</creator><creator>Fedorov, Alexander</creator><creator>Nefedov, Alexei</creator><creator>Wöll, Christof</creator><creator>Di Santo, Giovanni</creator><creator>Petaccia, Luca</creator><creator>Grüneis, Alexander</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1443-6780</orcidid><orcidid>https://orcid.org/0000-0003-2771-6386</orcidid><orcidid>https://orcid.org/0000-0003-2448-6060</orcidid><orcidid>https://orcid.org/0000-0001-8698-1468</orcidid><orcidid>https://orcid.org/0000-0003-1078-3304</orcidid></search><sort><creationdate>20180227</creationdate><title>Synthesis and spectroscopic characterization of alkali-metal intercalated ZrSe 2</title><author>Nikonov, Konstantin ; Ehlen, Niels ; Senkovskiy, Boris ; Saigal, Nihit ; Fedorov, Alexander ; Nefedov, Alexei ; Wöll, Christof ; Di Santo, Giovanni ; Petaccia, Luca ; Grüneis, Alexander</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c995-fd533fe340cf8e5ef59b18a8f6c546811fd42aa064e19487fc7a0067eb0787b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nikonov, Konstantin</creatorcontrib><creatorcontrib>Ehlen, Niels</creatorcontrib><creatorcontrib>Senkovskiy, Boris</creatorcontrib><creatorcontrib>Saigal, Nihit</creatorcontrib><creatorcontrib>Fedorov, Alexander</creatorcontrib><creatorcontrib>Nefedov, Alexei</creatorcontrib><creatorcontrib>Wöll, Christof</creatorcontrib><creatorcontrib>Di Santo, Giovanni</creatorcontrib><creatorcontrib>Petaccia, Luca</creatorcontrib><creatorcontrib>Grüneis, Alexander</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nikonov, Konstantin</au><au>Ehlen, Niels</au><au>Senkovskiy, Boris</au><au>Saigal, Nihit</au><au>Fedorov, Alexander</au><au>Nefedov, Alexei</au><au>Wöll, Christof</au><au>Di Santo, Giovanni</au><au>Petaccia, Luca</au><au>Grüneis, Alexander</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and spectroscopic characterization of alkali-metal intercalated ZrSe 2</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2018-02-27</date><risdate>2018</risdate><volume>47</volume><issue>9</issue><spage>2986</spage><epage>2991</epage><pages>2986-2991</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>We report on the synthesis and spectroscopic characterization of alkali metal intercalated ZrSe
single crystals. ZrSe
is produced by chemical vapour transport and then Li is intercalated. Intercalation is performed from the liquid phase (via butyllithium) and from the vapour phase. Raman spectroscopy of intercalated ZrSe
reveals phonon energy shifts of the Raman active A
and E
phonon modes, the disappearance of two-phonon modes and new low wavenumber Raman modes. Angle-resolved photoemission spectroscopy is used to perform a mapping of the Fermi surface revealing an electron concentration of 4.7 × 10
cm
. We also perform vapour phase intercalation of K and Cs into ZrSe
and observe similar changes in the Raman modes as for the Li case.</abstract><cop>England</cop><pmid>29215105</pmid><doi>10.1039/c7dt03756b</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-1443-6780</orcidid><orcidid>https://orcid.org/0000-0003-2771-6386</orcidid><orcidid>https://orcid.org/0000-0003-2448-6060</orcidid><orcidid>https://orcid.org/0000-0001-8698-1468</orcidid><orcidid>https://orcid.org/0000-0003-1078-3304</orcidid></addata></record> |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018-02, Vol.47 (9), p.2986-2991 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Synthesis and spectroscopic characterization of alkali-metal intercalated ZrSe 2 |
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