Stabilization of Ni 2+ dimers in hexacyano Mo 6 cluster-based Prussian blue derivatives: experimental and theoretical investigations of magnetic properties

Herein, two new octahedral molybdenum cyanide cluster compounds, namely [{Ni(NH ) } {Ni (NH ) } ][Mo Br Q (CN) ] ·12H O, Q = S (1) and Se (2), have been synthesized as single crystals by slow diffusion of a solution of nickel chloride into aqueous ammonia solutions of a K Cs [Mo Br Q (CN) ] molybden...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (4), p.1122-1130
Hauptverfasser:	Daigre, Gilles, Costuas, Karine, Tarasenko, Maria S, Ledneva, Alexandra Yu, Naumov, Nikolay G, Lemoine, Pierric, Guizouarn, Thierry, Molard, Yann, Amela-Cortes, Maria, Audebrand, Nathalie, Cordier, Stéphane
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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