Metallosupramolecular 3D assembly of dimetallic Zn 4 [RuL 2 ] 2 and trimetallic Fe 2 Zn 2 [RuL 2 ] 2
A novel metallo-organic ligand [RuL ] with four uncomplexed coordination sites was created, and upon treatment with Zn generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assemb...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2017-10, Vol.53 (80), p.11087-11090 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 53 |
| creator | Chen, Mingzhao Wang, Jun Chakraborty, Sourav Liu, Die Jiang, Zhilong Liu, Qianqian Yan, Jun Zhong, Hong Newkome, George R Wang, Pingshan |
| description | A novel metallo-organic ligand [RuL
] with four uncomplexed coordination sites was created, and upon treatment with Zn
generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru
, two Fe
, and two Zn
ions precisely located in the different edges. This strategy opens the door to novel designer 3D polymetallic constructs capable of diverse applications. |
| doi_str_mv | 10.1039/c7cc05577c |
| format | Article |
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] with four uncomplexed coordination sites was created, and upon treatment with Zn
generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru
, two Fe
, and two Zn
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] with four uncomplexed coordination sites was created, and upon treatment with Zn
generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru
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] with four uncomplexed coordination sites was created, and upon treatment with Zn
generated a dimetallic 3D metallosupramolecule in nearly quantitative yield. This self-assembly process gave stable intermediates, opening the pathway to the first 3D metallo-assembly possessing two Ru
, two Fe
, and two Zn
ions precisely located in the different edges. This strategy opens the door to novel designer 3D polymetallic constructs capable of diverse applications.</abstract><cop>England</cop><pmid>28951894</pmid><doi>10.1039/c7cc05577c</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-5564-3087</orcidid><orcidid>https://orcid.org/0000-0001-6019-5071</orcidid><orcidid>https://orcid.org/0000-0002-1988-7604</orcidid></addata></record> |
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2017-10, Vol.53 (80), p.11087-11090 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C7CC05577C |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Metallosupramolecular 3D assembly of dimetallic Zn 4 [RuL 2 ] 2 and trimetallic Fe 2 Zn 2 [RuL 2 ] 2 |
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