A 1-D coordination polymer route to catalytically active Co@C nanoparticles
Pyrolysis of a 1-D polymeric cobalt( ii ) coordination complex ([Co(BDC)(Mim) 2 ] n , H 2 BDC = benzenedicarboxylic acid; Mim = N -methylimidazole) results in the formation of carbon embedded fcc cobalt nanoparticle composites, Co@C. The as-prepared Co@C shows an agglomerated secondary structure wit...
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (45), p.38533-3854 |
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| container_title | RSC advances |
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| creator | Pariyar, Anand Gopalakrishnan, Siddharth Stansbery, Joseph Patel, Rajankumar L Liang, Xinhua Gerasimchuk, Nikolay Choudhury, Amitava |
| description | Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C. The as-prepared Co@C shows an agglomerated secondary structure with a highly embedded carbon shell comprising of cobalt nanoparticles of 20100 nm. These Co@C particles show excellent catalytic activity in the reduction of nitrophenol to aminophenol, studied as a model reaction, and evolves as a promising candidate for the gas phase reduction process.
Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C. |
| doi_str_mv | 10.1039/c6ra04650a |
| format | Article |
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ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C. The as-prepared Co@C shows an agglomerated secondary structure with a highly embedded carbon shell comprising of cobalt nanoparticles of 20100 nm. These Co@C particles show excellent catalytic activity in the reduction of nitrophenol to aminophenol, studied as a model reaction, and evolves as a promising candidate for the gas phase reduction process.
Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra04650a</identifier><language>eng</language><ispartof>RSC advances, 2016-01, Vol.6 (45), p.38533-3854</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c289t-729ad0a97ed499278b04831db330628f0cccf75c3e4b09232d4d1433d0ed8fae3</citedby><cites>FETCH-LOGICAL-c289t-729ad0a97ed499278b04831db330628f0cccf75c3e4b09232d4d1433d0ed8fae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Pariyar, Anand</creatorcontrib><creatorcontrib>Gopalakrishnan, Siddharth</creatorcontrib><creatorcontrib>Stansbery, Joseph</creatorcontrib><creatorcontrib>Patel, Rajankumar L</creatorcontrib><creatorcontrib>Liang, Xinhua</creatorcontrib><creatorcontrib>Gerasimchuk, Nikolay</creatorcontrib><creatorcontrib>Choudhury, Amitava</creatorcontrib><title>A 1-D coordination polymer route to catalytically active Co@C nanoparticles</title><title>RSC advances</title><description>Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C. The as-prepared Co@C shows an agglomerated secondary structure with a highly embedded carbon shell comprising of cobalt nanoparticles of 20100 nm. These Co@C particles show excellent catalytic activity in the reduction of nitrophenol to aminophenol, studied as a model reaction, and evolves as a promising candidate for the gas phase reduction process.
Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLxDAUhYMoOIyzcS9kLVRvHk2bnaU-cUAQXZfbJIVKpylJFPrvrY6oZ3MP3I-z-Ag5ZXDBQOhLowKCVDngAVnxpWUclD7814_JJsY3WKJyxhVbkceKsuyaGu-D7UdMvR_p5Id55wIN_j05mjw1mHCYU29wGGaKJvUfjtb-qqYjjn7CsLwGF0_IUYdDdJufuyavtzcv9X22fbp7qKttZnipU1ZwjRZQF85KrXlRtiBLwWwrBChedmCM6YrcCCdb0FxwKy2TQlhwtuzQiTU53--a4GMMrmum0O8wzA2D5stEU6vn6ttEtcBnezhE88v9mRKfOglaWA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Pariyar, Anand</creator><creator>Gopalakrishnan, Siddharth</creator><creator>Stansbery, Joseph</creator><creator>Patel, Rajankumar L</creator><creator>Liang, Xinhua</creator><creator>Gerasimchuk, Nikolay</creator><creator>Choudhury, Amitava</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160101</creationdate><title>A 1-D coordination polymer route to catalytically active Co@C nanoparticles</title><author>Pariyar, Anand ; Gopalakrishnan, Siddharth ; Stansbery, Joseph ; Patel, Rajankumar L ; Liang, Xinhua ; Gerasimchuk, Nikolay ; Choudhury, Amitava</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c289t-729ad0a97ed499278b04831db330628f0cccf75c3e4b09232d4d1433d0ed8fae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pariyar, Anand</creatorcontrib><creatorcontrib>Gopalakrishnan, Siddharth</creatorcontrib><creatorcontrib>Stansbery, Joseph</creatorcontrib><creatorcontrib>Patel, Rajankumar L</creatorcontrib><creatorcontrib>Liang, Xinhua</creatorcontrib><creatorcontrib>Gerasimchuk, Nikolay</creatorcontrib><creatorcontrib>Choudhury, Amitava</creatorcontrib><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pariyar, Anand</au><au>Gopalakrishnan, Siddharth</au><au>Stansbery, Joseph</au><au>Patel, Rajankumar L</au><au>Liang, Xinhua</au><au>Gerasimchuk, Nikolay</au><au>Choudhury, Amitava</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 1-D coordination polymer route to catalytically active Co@C nanoparticles</atitle><jtitle>RSC advances</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>6</volume><issue>45</issue><spage>38533</spage><epage>3854</epage><pages>38533-3854</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C. The as-prepared Co@C shows an agglomerated secondary structure with a highly embedded carbon shell comprising of cobalt nanoparticles of 20100 nm. These Co@C particles show excellent catalytic activity in the reduction of nitrophenol to aminophenol, studied as a model reaction, and evolves as a promising candidate for the gas phase reduction process.
Pyrolysis of a 1-D polymeric cobalt(
ii
) coordination complex ([Co(BDC)(Mim)
2
]
n
, H
2
BDC = benzenedicarboxylic acid; Mim =
N
-methylimidazole) results in the formation of carbon embedded
fcc
cobalt nanoparticle composites, Co@C.</abstract><doi>10.1039/c6ra04650a</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2016-01, Vol.6 (45), p.38533-3854 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C6RA04650A |
| source | Royal Society Of Chemistry Journals 2008- |
| title | A 1-D coordination polymer route to catalytically active Co@C nanoparticles |
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