Solid state π-π stacking and higher order dimensional crystal packing, reactivity, and electrochemical behaviour of salphenazine actinide and transition metal complexes
Condensation of a 2,3-diaminophenazine or 2,3-diamino-2-quinoxalinol with two equivalents of 3,5-ditertbutylsalicylaldehyde affords new Schiff base ligands. Here, we describe and compare the synthesis, UV-Vis, electrochemical, solution, and solid state behaviour of the free base, salphenazine ligand...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2016-09, Vol.45 (36), p.14243-14251 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Hardy, E. E Eddy, M. A Maynard, B. A Gorden, A. E. V |
| description | Condensation of a 2,3-diaminophenazine or 2,3-diamino-2-quinoxalinol with two equivalents of 3,5-ditertbutylsalicylaldehyde affords new Schiff base ligands. Here, we describe and compare the synthesis, UV-Vis, electrochemical, solution, and solid state behaviour of the free base, salphenazine ligand [L
I
], and M[L
I
] complexes, where M = UO
2
(
vi
), Cu(
ii
), VO(
iv
), Zn(
ii
), Co(
ii
), and Ni(
ii
). The change in π-overlap and π-stacking between molecules and long-range ordering of the solid-state structure is vastly different depending on the size and electronic character of the metal. A sterically constrained μ-oxo Fe(
iii
) dimer complex is also reported.
Here, we describe and compare the synthesis, solution characterization, and solid-state behaviour of the salphenazine ligand and metal complexes. |
| doi_str_mv | 10.1039/c6dt02389d |
| format | Article |
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I
], and M[L
I
] complexes, where M = UO
2
(
vi
), Cu(
ii
), VO(
iv
), Zn(
ii
), Co(
ii
), and Ni(
ii
). The change in π-overlap and π-stacking between molecules and long-range ordering of the solid-state structure is vastly different depending on the size and electronic character of the metal. A sterically constrained μ-oxo Fe(
iii
) dimer complex is also reported.
Here, we describe and compare the synthesis, solution characterization, and solid-state behaviour of the salphenazine ligand and metal complexes.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c6dt02389d</identifier><identifier>PMID: 27535454</identifier><language>eng</language><publisher>England</publisher><subject>Constraints ; Coordination compounds ; Ligands ; Molecular structure ; Order disorder ; Schiff bases ; Solid state ; Stacking</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2016-09, Vol.45 (36), p.14243-14251</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-dd21f9149b24a8235c9b9101aa388f8f8af3fbd73ded65c95601189822da410f3</citedby><cites>FETCH-LOGICAL-c342t-dd21f9149b24a8235c9b9101aa388f8f8af3fbd73ded65c95601189822da410f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27535454$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hardy, E. E</creatorcontrib><creatorcontrib>Eddy, M. A</creatorcontrib><creatorcontrib>Maynard, B. A</creatorcontrib><creatorcontrib>Gorden, A. E. V</creatorcontrib><title>Solid state π-π stacking and higher order dimensional crystal packing, reactivity, and electrochemical behaviour of salphenazine actinide and transition metal complexes</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Condensation of a 2,3-diaminophenazine or 2,3-diamino-2-quinoxalinol with two equivalents of 3,5-ditertbutylsalicylaldehyde affords new Schiff base ligands. Here, we describe and compare the synthesis, UV-Vis, electrochemical, solution, and solid state behaviour of the free base, salphenazine ligand [L
I
], and M[L
I
] complexes, where M = UO
2
(
vi
), Cu(
ii
), VO(
iv
), Zn(
ii
), Co(
ii
), and Ni(
ii
). The change in π-overlap and π-stacking between molecules and long-range ordering of the solid-state structure is vastly different depending on the size and electronic character of the metal. A sterically constrained μ-oxo Fe(
iii
) dimer complex is also reported.
Here, we describe and compare the synthesis, solution characterization, and solid-state behaviour of the salphenazine ligand and metal complexes.</description><subject>Constraints</subject><subject>Coordination compounds</subject><subject>Ligands</subject><subject>Molecular structure</subject><subject>Order disorder</subject><subject>Schiff bases</subject><subject>Solid state</subject><subject>Stacking</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFks1O3DAUha2qqPy0m-6LvESItP5LJl6igQISUhel68ixb4iLE6e2BzGseJ6-DK-EZwamy8qSfaX7nXMWxwh9puQrJVx-05VJhPFamndoj4rZrJCMi_fbmVW7aD_G34QwRkr2Ae2yWclLUYo99Pend9bgmFQC_PxUPD-tZn1nx1usRoN7e9tDwD6YfBs7wBitH5XDOiwz6PC0gU9wAKWTvbdpebJWggOdgtc9DFZnsIVe3Vu_yGYdjspNPYzq0Y6AV7rRGljLUlA5IuUQPMAqQPthcvAA8SPa6ZSL8On1PUC_vp_fzC-L6x8XV_PT60JzwVJhDKOdpEK2TKia8VLLVlJCleJ13eWjOt61ZsYNmCovy4pQWsuaMaMEJR0_QEcb3yn4PwuIqRls1OCcGsEvYkMlLTljpeT_R2sqBeeC0oweb1AdfIwBumYKdlBh2VDSrGps5tXZzbrGswwfvvou2gHMFn3rLQNfNkCIerv99w_4C8Yupok</recordid><startdate>20160928</startdate><enddate>20160928</enddate><creator>Hardy, E. E</creator><creator>Eddy, M. A</creator><creator>Maynard, B. A</creator><creator>Gorden, A. E. V</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160928</creationdate><title>Solid state π-π stacking and higher order dimensional crystal packing, reactivity, and electrochemical behaviour of salphenazine actinide and transition metal complexes</title><author>Hardy, E. E ; Eddy, M. A ; Maynard, B. A ; Gorden, A. E. V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-dd21f9149b24a8235c9b9101aa388f8f8af3fbd73ded65c95601189822da410f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Constraints</topic><topic>Coordination compounds</topic><topic>Ligands</topic><topic>Molecular structure</topic><topic>Order disorder</topic><topic>Schiff bases</topic><topic>Solid state</topic><topic>Stacking</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hardy, E. E</creatorcontrib><creatorcontrib>Eddy, M. A</creatorcontrib><creatorcontrib>Maynard, B. A</creatorcontrib><creatorcontrib>Gorden, A. E. V</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hardy, E. E</au><au>Eddy, M. A</au><au>Maynard, B. A</au><au>Gorden, A. E. V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid state π-π stacking and higher order dimensional crystal packing, reactivity, and electrochemical behaviour of salphenazine actinide and transition metal complexes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2016-09-28</date><risdate>2016</risdate><volume>45</volume><issue>36</issue><spage>14243</spage><epage>14251</epage><pages>14243-14251</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Condensation of a 2,3-diaminophenazine or 2,3-diamino-2-quinoxalinol with two equivalents of 3,5-ditertbutylsalicylaldehyde affords new Schiff base ligands. Here, we describe and compare the synthesis, UV-Vis, electrochemical, solution, and solid state behaviour of the free base, salphenazine ligand [L
I
], and M[L
I
] complexes, where M = UO
2
(
vi
), Cu(
ii
), VO(
iv
), Zn(
ii
), Co(
ii
), and Ni(
ii
). The change in π-overlap and π-stacking between molecules and long-range ordering of the solid-state structure is vastly different depending on the size and electronic character of the metal. A sterically constrained μ-oxo Fe(
iii
) dimer complex is also reported.
Here, we describe and compare the synthesis, solution characterization, and solid-state behaviour of the salphenazine ligand and metal complexes.</abstract><cop>England</cop><pmid>27535454</pmid><doi>10.1039/c6dt02389d</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2016-09, Vol.45 (36), p.14243-14251 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C6DT02389D |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Constraints Coordination compounds Ligands Molecular structure Order disorder Schiff bases Solid state Stacking |
| title | Solid state π-π stacking and higher order dimensional crystal packing, reactivity, and electrochemical behaviour of salphenazine actinide and transition metal complexes |
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