Lanthanide-based entangled coordination polymers connected by thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures, luminescence and magnetic properties
Nine novel coordination polymers (CPs) with the formulas [M 6 (TDA) 9 (DEF) 5 (H 2 O) 3 ] n [M = Ce ( 1 ), Pr ( 2 ), Nd ( 3 ), Sm ( 4 )], [Eu 4 (TDA) 6 (DEF) 3 (H 2 O) 2 ] n ( 5 ), [Gd 2 (TDA) 3 (DEF) 2 ] n ·H 2 O ( 6 ), [Tb 2 (TDA) 3 (DEF) 2 ] n ·0.5H 2 O ( 7 ), [Dy 2 (TDA) 3 (DEF) 2 ] n ·H 2 O ( 8...
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| description | Nine novel coordination polymers (CPs) with the formulas [M
6
(TDA)
9
(DEF)
5
(H
2
O)
3
]
n
[M = Ce (
1
), Pr (
2
), Nd (
3
), Sm (
4
)], [Eu
4
(TDA)
6
(DEF)
3
(H
2
O)
2
]
n
(
5
), [Gd
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
6
), [Tb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
7
), [Dy
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
8
) and [Yb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
9
) (TDA = 2,5-thiophenedicarboxylate anion and DEF = diethylformamide) have been synthesized at different temperatures in a DEF-H
2
O solvent system under solvothermal conditions. All the compounds were characterized by single crystal X-ray diffraction analysis (XRD), Fourier transformation vibrational spectroscopy (FT-IR) and thermal analysis (TGA). Structural analyses of CPs
1-4
reveal that the polymers crystallize in the orthorhombic space group
Pna
2
1
and form 3D frameworks with large volumes 10 378.1(5), 10 230.5(5), 10 171.9(5) and 10 077.1(11) Å
3
, respectively. The M(
iii
) ions of CPs
1-4
exhibit nine and eight coordination numbers with diverse geometries. Structural analyses of CPs
5
and
6-9
unveil that the polymers crystallize in the monoclinic system, with space groups
P
2
1
and
P
2/
c
, respectively, forming a 3D network. The TDA ligand exhibits two coordination modes [(κ
1
-κ
1
)-(κ
1
-κ
1
)-μ
4
and (κ
2
-κ
1
-μ
2
)-(κ
1
-κ
1
)-μ
5
] which interconnect the metal ions to generate 3D novel metal-organic frameworks. The luminescence properties of
4
,
5
,
7
and
8
, and the magnetic properties of
6-8
were investigated.
Nine novel coordination polymers
1-9
containing thiophene dicarboxylate anion and DEF have been synthesized solvothermally at different temperatures in DEF-H
2
O solvent system. |
| doi_str_mv | 10.1039/c6ce00321d |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C6CE00321D</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1816002272</sourcerecordid><originalsourceid>FETCH-LOGICAL-c323t-c3f0396d651ff2f28520f89ca8701e287964a71390afda00607ad61a55b84d1e3</originalsourceid><addsrcrecordid>eNpNkU1vFDEMhkcVlShtL9wr5YhQp83HTmaWG1oKVFqpl_Y88iaeblAmGeJMxfwm_iRZFgEX23r9yLb8VtVbwW8EV-tbow1yrqSwJ9WZWGldd1ypV__Vr6s3RN84Fysh-Fn1cwsh7yE4i_UOCC3DkCE8-1KZGJN1AbKLgU3RLyMmKmoIaHLp7xaW9y5OewxYy-umts5A2sUfi4eMHxhF_xLzHtMIntFS9iAhXTOTFsoHKafZ5DkdND-PLiAZDAYZBMtGeA6YnWFTihOm7JAuqtMBPOHln3xePX2-e9x8rbcPX-43H7e1UVLlEofyCm11I4ZBDrJrJB-6tYGu5QJl1671Clqh1hwGC5xr3oLVAppm162sQHVevTvOLau_z0i5H125zHsIGGfqRSc051K2sqDvj6hJkSjh0E_JjZCWXvD-4Ei_0Zu73458KvDVEU5k_nL_HFO_AEctjMs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1816002272</pqid></control><display><type>article</type><title>Lanthanide-based entangled coordination polymers connected by thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures, luminescence and magnetic properties</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yawer, Mohd ; Kariem, Mukaddus ; Sood, Puneet ; Sheikh, Haq Nawaz</creator><creatorcontrib>Yawer, Mohd ; Kariem, Mukaddus ; Sood, Puneet ; Sheikh, Haq Nawaz</creatorcontrib><description>Nine novel coordination polymers (CPs) with the formulas [M
6
(TDA)
9
(DEF)
5
(H
2
O)
3
]
n
[M = Ce (
1
), Pr (
2
), Nd (
3
), Sm (
4
)], [Eu
4
(TDA)
6
(DEF)
3
(H
2
O)
2
]
n
(
5
), [Gd
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
6
), [Tb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
7
), [Dy
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
8
) and [Yb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
9
) (TDA = 2,5-thiophenedicarboxylate anion and DEF = diethylformamide) have been synthesized at different temperatures in a DEF-H
2
O solvent system under solvothermal conditions. All the compounds were characterized by single crystal X-ray diffraction analysis (XRD), Fourier transformation vibrational spectroscopy (FT-IR) and thermal analysis (TGA). Structural analyses of CPs
1-4
reveal that the polymers crystallize in the orthorhombic space group
Pna
2
1
and form 3D frameworks with large volumes 10 378.1(5), 10 230.5(5), 10 171.9(5) and 10 077.1(11) Å
3
, respectively. The M(
iii
) ions of CPs
1-4
exhibit nine and eight coordination numbers with diverse geometries. Structural analyses of CPs
5
and
6-9
unveil that the polymers crystallize in the monoclinic system, with space groups
P
2
1
and
P
2/
c
, respectively, forming a 3D network. The TDA ligand exhibits two coordination modes [(κ
1
-κ
1
)-(κ
1
-κ
1
)-μ
4
and (κ
2
-κ
1
-μ
2
)-(κ
1
-κ
1
)-μ
5
] which interconnect the metal ions to generate 3D novel metal-organic frameworks. The luminescence properties of
4
,
5
,
7
and
8
, and the magnetic properties of
6-8
were investigated.
Nine novel coordination polymers
1-9
containing thiophene dicarboxylate anion and DEF have been synthesized solvothermally at different temperatures in DEF-H
2
O solvent system.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c6ce00321d</identifier><language>eng</language><subject>Anions ; Coordination polymers ; Luminescence ; Magnetic properties ; Networks ; Polymers ; Structural analysis ; Three dimensional</subject><ispartof>CrystEngComm, 2016-01, Vol.18 (2), p.3617-3634</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c323t-c3f0396d651ff2f28520f89ca8701e287964a71390afda00607ad61a55b84d1e3</citedby><cites>FETCH-LOGICAL-c323t-c3f0396d651ff2f28520f89ca8701e287964a71390afda00607ad61a55b84d1e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Yawer, Mohd</creatorcontrib><creatorcontrib>Kariem, Mukaddus</creatorcontrib><creatorcontrib>Sood, Puneet</creatorcontrib><creatorcontrib>Sheikh, Haq Nawaz</creatorcontrib><title>Lanthanide-based entangled coordination polymers connected by thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures, luminescence and magnetic properties</title><title>CrystEngComm</title><description>Nine novel coordination polymers (CPs) with the formulas [M
6
(TDA)
9
(DEF)
5
(H
2
O)
3
]
n
[M = Ce (
1
), Pr (
2
), Nd (
3
), Sm (
4
)], [Eu
4
(TDA)
6
(DEF)
3
(H
2
O)
2
]
n
(
5
), [Gd
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
6
), [Tb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
7
), [Dy
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
8
) and [Yb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
9
) (TDA = 2,5-thiophenedicarboxylate anion and DEF = diethylformamide) have been synthesized at different temperatures in a DEF-H
2
O solvent system under solvothermal conditions. All the compounds were characterized by single crystal X-ray diffraction analysis (XRD), Fourier transformation vibrational spectroscopy (FT-IR) and thermal analysis (TGA). Structural analyses of CPs
1-4
reveal that the polymers crystallize in the orthorhombic space group
Pna
2
1
and form 3D frameworks with large volumes 10 378.1(5), 10 230.5(5), 10 171.9(5) and 10 077.1(11) Å
3
, respectively. The M(
iii
) ions of CPs
1-4
exhibit nine and eight coordination numbers with diverse geometries. Structural analyses of CPs
5
and
6-9
unveil that the polymers crystallize in the monoclinic system, with space groups
P
2
1
and
P
2/
c
, respectively, forming a 3D network. The TDA ligand exhibits two coordination modes [(κ
1
-κ
1
)-(κ
1
-κ
1
)-μ
4
and (κ
2
-κ
1
-μ
2
)-(κ
1
-κ
1
)-μ
5
] which interconnect the metal ions to generate 3D novel metal-organic frameworks. The luminescence properties of
4
,
5
,
7
and
8
, and the magnetic properties of
6-8
were investigated.
Nine novel coordination polymers
1-9
containing thiophene dicarboxylate anion and DEF have been synthesized solvothermally at different temperatures in DEF-H
2
O solvent system.</description><subject>Anions</subject><subject>Coordination polymers</subject><subject>Luminescence</subject><subject>Magnetic properties</subject><subject>Networks</subject><subject>Polymers</subject><subject>Structural analysis</subject><subject>Three dimensional</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkU1vFDEMhkcVlShtL9wr5YhQp83HTmaWG1oKVFqpl_Y88iaeblAmGeJMxfwm_iRZFgEX23r9yLb8VtVbwW8EV-tbow1yrqSwJ9WZWGldd1ypV__Vr6s3RN84Fysh-Fn1cwsh7yE4i_UOCC3DkCE8-1KZGJN1AbKLgU3RLyMmKmoIaHLp7xaW9y5OewxYy-umts5A2sUfi4eMHxhF_xLzHtMIntFS9iAhXTOTFsoHKafZ5DkdND-PLiAZDAYZBMtGeA6YnWFTihOm7JAuqtMBPOHln3xePX2-e9x8rbcPX-43H7e1UVLlEofyCm11I4ZBDrJrJB-6tYGu5QJl1671Clqh1hwGC5xr3oLVAppm162sQHVevTvOLau_z0i5H125zHsIGGfqRSc051K2sqDvj6hJkSjh0E_JjZCWXvD-4Ei_0Zu73458KvDVEU5k_nL_HFO_AEctjMs</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Yawer, Mohd</creator><creator>Kariem, Mukaddus</creator><creator>Sood, Puneet</creator><creator>Sheikh, Haq Nawaz</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Lanthanide-based entangled coordination polymers connected by thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures, luminescence and magnetic properties</title><author>Yawer, Mohd ; Kariem, Mukaddus ; Sood, Puneet ; Sheikh, Haq Nawaz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c323t-c3f0396d651ff2f28520f89ca8701e287964a71390afda00607ad61a55b84d1e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Anions</topic><topic>Coordination polymers</topic><topic>Luminescence</topic><topic>Magnetic properties</topic><topic>Networks</topic><topic>Polymers</topic><topic>Structural analysis</topic><topic>Three dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yawer, Mohd</creatorcontrib><creatorcontrib>Kariem, Mukaddus</creatorcontrib><creatorcontrib>Sood, Puneet</creatorcontrib><creatorcontrib>Sheikh, Haq Nawaz</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yawer, Mohd</au><au>Kariem, Mukaddus</au><au>Sood, Puneet</au><au>Sheikh, Haq Nawaz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lanthanide-based entangled coordination polymers connected by thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures, luminescence and magnetic properties</atitle><jtitle>CrystEngComm</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>18</volume><issue>2</issue><spage>3617</spage><epage>3634</epage><pages>3617-3634</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Nine novel coordination polymers (CPs) with the formulas [M
6
(TDA)
9
(DEF)
5
(H
2
O)
3
]
n
[M = Ce (
1
), Pr (
2
), Nd (
3
), Sm (
4
)], [Eu
4
(TDA)
6
(DEF)
3
(H
2
O)
2
]
n
(
5
), [Gd
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
6
), [Tb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
7
), [Dy
2
(TDA)
3
(DEF)
2
]
n
·H
2
O (
8
) and [Yb
2
(TDA)
3
(DEF)
2
]
n
·0.5H
2
O (
9
) (TDA = 2,5-thiophenedicarboxylate anion and DEF = diethylformamide) have been synthesized at different temperatures in a DEF-H
2
O solvent system under solvothermal conditions. All the compounds were characterized by single crystal X-ray diffraction analysis (XRD), Fourier transformation vibrational spectroscopy (FT-IR) and thermal analysis (TGA). Structural analyses of CPs
1-4
reveal that the polymers crystallize in the orthorhombic space group
Pna
2
1
and form 3D frameworks with large volumes 10 378.1(5), 10 230.5(5), 10 171.9(5) and 10 077.1(11) Å
3
, respectively. The M(
iii
) ions of CPs
1-4
exhibit nine and eight coordination numbers with diverse geometries. Structural analyses of CPs
5
and
6-9
unveil that the polymers crystallize in the monoclinic system, with space groups
P
2
1
and
P
2/
c
, respectively, forming a 3D network. The TDA ligand exhibits two coordination modes [(κ
1
-κ
1
)-(κ
1
-κ
1
)-μ
4
and (κ
2
-κ
1
-μ
2
)-(κ
1
-κ
1
)-μ
5
] which interconnect the metal ions to generate 3D novel metal-organic frameworks. The luminescence properties of
4
,
5
,
7
and
8
, and the magnetic properties of
6-8
were investigated.
Nine novel coordination polymers
1-9
containing thiophene dicarboxylate anion and DEF have been synthesized solvothermally at different temperatures in DEF-H
2
O solvent system.</abstract><doi>10.1039/c6ce00321d</doi><tpages>18</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2016-01, Vol.18 (2), p.3617-3634 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C6CE00321D |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Coordination polymers Luminescence Magnetic properties Networks Polymers Structural analysis Three dimensional |
| title | Lanthanide-based entangled coordination polymers connected by thiophene-2,5-dicarboxylate: solvothermal syntheses, crystal structures, luminescence and magnetic properties |
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