Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs)
The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. It was found that, in single-component systems, the adsorption...
Gespeichert in:
| Veröffentlicht in: | CrystEngComm 2016-01, Vol.18 (21), p.3842-3849 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3849 |
|---|---|
| container_issue | 21 |
| container_start_page | 3842 |
| container_title | CrystEngComm |
| container_volume | 18 |
| creator | Gao, Chunping Shi, Qi Dong, Jinxiang |
| description | The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. It was found that, in single-component systems, the adsorption capacities of ZIF-8 and MAF-6 were larger than that of TIF-1 Zn, mainly because of their larger pore volume; however, the time necessary to reach equilibrium was shorter when TIF-1 Zn with a larger pore aperture was used. In breakthrough experiments, it was shown that the adsorptive separation mechanism on ZIF-8 and MAF-6 was based on combined thermodynamics and kinetic effects; on TIF-1 Zn, thermodynamic adsorption took place.
The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. |
| doi_str_mv | 10.1039/c6ce00249h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C6CE00249H</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1825447627</sourcerecordid><originalsourceid>FETCH-LOGICAL-c389t-fd0f2b26697a478c1fc5eccf76b242f2c39b9816a61176baf96aa5221c95bf653</originalsourceid><addsrcrecordid>eNpNkMFLwzAchYMoOKcX70KOU6gmaZs2x1E2Nxh40YuX8muasGjb1CRTur_e6kQ9vcfj4x0-hC4puaUkFneSS0UIS8T2CE1ownmUkzg-_tdP0Zn3L4TQhFIyQd289tb1wbwr7FUPDoKxHe6V09a10EmFrcY0qnYBOttg2wWLw9AbCQ3eDrWz_dZWRuK9so0JYzGtqWFvGwgKawet-rDu1ePZ83rpr8_RiYbGq4ufnKKn5eKxWEWbh_t1Md9EMs5FiHRNNKsY5yKDJMsl1TJVUuqMVyxhmslYVCKnHDil4wZacICUMSpFWmmexlM0O_z2zr7tlA9la7xUTQOdsjtf0pylSZJxlo3ozQGVznrvlC57Z1pwQ0lJ-SW1LHix-Ja6GuGrA-y8_OX-pMefQD91vg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1825447627</pqid></control><display><type>article</type><title>Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs)</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Gao, Chunping ; Shi, Qi ; Dong, Jinxiang</creator><creatorcontrib>Gao, Chunping ; Shi, Qi ; Dong, Jinxiang</creatorcontrib><description>The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. It was found that, in single-component systems, the adsorption capacities of ZIF-8 and MAF-6 were larger than that of TIF-1 Zn, mainly because of their larger pore volume; however, the time necessary to reach equilibrium was shorter when TIF-1 Zn with a larger pore aperture was used. In breakthrough experiments, it was shown that the adsorptive separation mechanism on ZIF-8 and MAF-6 was based on combined thermodynamics and kinetic effects; on TIF-1 Zn, thermodynamic adsorption took place.
The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c6ce00249h</identifier><language>eng</language><subject>Adsorption ; Adsorptivity ; Apertures ; Broths ; Fermentation ; Porosity ; Separation ; Thermodynamics</subject><ispartof>CrystEngComm, 2016-01, Vol.18 (21), p.3842-3849</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-fd0f2b26697a478c1fc5eccf76b242f2c39b9816a61176baf96aa5221c95bf653</citedby><cites>FETCH-LOGICAL-c389t-fd0f2b26697a478c1fc5eccf76b242f2c39b9816a61176baf96aa5221c95bf653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Gao, Chunping</creatorcontrib><creatorcontrib>Shi, Qi</creatorcontrib><creatorcontrib>Dong, Jinxiang</creatorcontrib><title>Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs)</title><title>CrystEngComm</title><description>The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. It was found that, in single-component systems, the adsorption capacities of ZIF-8 and MAF-6 were larger than that of TIF-1 Zn, mainly because of their larger pore volume; however, the time necessary to reach equilibrium was shorter when TIF-1 Zn with a larger pore aperture was used. In breakthrough experiments, it was shown that the adsorptive separation mechanism on ZIF-8 and MAF-6 was based on combined thermodynamics and kinetic effects; on TIF-1 Zn, thermodynamic adsorption took place.
The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8.</description><subject>Adsorption</subject><subject>Adsorptivity</subject><subject>Apertures</subject><subject>Broths</subject><subject>Fermentation</subject><subject>Porosity</subject><subject>Separation</subject><subject>Thermodynamics</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkMFLwzAchYMoOKcX70KOU6gmaZs2x1E2Nxh40YuX8muasGjb1CRTur_e6kQ9vcfj4x0-hC4puaUkFneSS0UIS8T2CE1ownmUkzg-_tdP0Zn3L4TQhFIyQd289tb1wbwr7FUPDoKxHe6V09a10EmFrcY0qnYBOttg2wWLw9AbCQ3eDrWz_dZWRuK9so0JYzGtqWFvGwgKawet-rDu1ePZ83rpr8_RiYbGq4ufnKKn5eKxWEWbh_t1Md9EMs5FiHRNNKsY5yKDJMsl1TJVUuqMVyxhmslYVCKnHDil4wZacICUMSpFWmmexlM0O_z2zr7tlA9la7xUTQOdsjtf0pylSZJxlo3ozQGVznrvlC57Z1pwQ0lJ-SW1LHix-Ja6GuGrA-y8_OX-pMefQD91vg</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Gao, Chunping</creator><creator>Shi, Qi</creator><creator>Dong, Jinxiang</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs)</title><author>Gao, Chunping ; Shi, Qi ; Dong, Jinxiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-fd0f2b26697a478c1fc5eccf76b242f2c39b9816a61176baf96aa5221c95bf653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Adsorption</topic><topic>Adsorptivity</topic><topic>Apertures</topic><topic>Broths</topic><topic>Fermentation</topic><topic>Porosity</topic><topic>Separation</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Chunping</creatorcontrib><creatorcontrib>Shi, Qi</creatorcontrib><creatorcontrib>Dong, Jinxiang</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Chunping</au><au>Shi, Qi</au><au>Dong, Jinxiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs)</atitle><jtitle>CrystEngComm</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>18</volume><issue>21</issue><spage>3842</spage><epage>3849</epage><pages>3842-3849</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. It was found that, in single-component systems, the adsorption capacities of ZIF-8 and MAF-6 were larger than that of TIF-1 Zn, mainly because of their larger pore volume; however, the time necessary to reach equilibrium was shorter when TIF-1 Zn with a larger pore aperture was used. In breakthrough experiments, it was shown that the adsorptive separation mechanism on ZIF-8 and MAF-6 was based on combined thermodynamics and kinetic effects; on TIF-1 Zn, thermodynamic adsorption took place.
The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone-butanol-ethanol model fermentation broth was studied and compared to the data reported for ZIF-8.</abstract><doi>10.1039/c6ce00249h</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2016-01, Vol.18 (21), p.3842-3849 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C6CE00249H |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Adsorption Adsorptivity Apertures Broths Fermentation Porosity Separation Thermodynamics |
| title | Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-16T08%3A56%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Adsorptive%20separation%20performance%20of%201-butanol%20onto%20typical%20hydrophobic%20zeolitic%20imidazolate%20frameworks%20(ZIFs)&rft.jtitle=CrystEngComm&rft.au=Gao,%20Chunping&rft.date=2016-01-01&rft.volume=18&rft.issue=21&rft.spage=3842&rft.epage=3849&rft.pages=3842-3849&rft.issn=1466-8033&rft.eissn=1466-8033&rft_id=info:doi/10.1039/c6ce00249h&rft_dat=%3Cproquest_cross%3E1825447627%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1825447627&rft_id=info:pmid/&rfr_iscdi=true |