Hydrogen release reactions of Al-based complex hydrides enhanced by vibrational dynamics and valences of metal cations

Hydrogen release from Al-based complex hydrides composed of metal cation(s) and [AlH 4 ] − was investigated using inelastic neutron scattering viewed from vibrational dynamics. The hydrogen release followed the softening of translational and [AlH 4 ] − librational modes, which was enhanced by vibrat...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (79), p.1187-1181
Hauptverfasser:	Sato, T, Ramirez-Cuesta, A. J, Daemen, L, Cheng, Y.-Q, Tomiyasu, K, Takagi, S, Orimo, S
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Cations Dynamic tests Dynamics Hydrides Hydrogen storage INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Neutron scattering Softening
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