A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries

Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. Elemental phosphorus (P) is a very promising anode ma...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (37), p.1911-1917
Hauptverfasser: Ruan, Boyang, Wang, Jun, Shi, Dongqi, Xu, Yanfei, Chou, Shulei, Liu, Huakun, Wang, Jiazhao
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container_end_page 1917
container_issue 37
container_start_page 1911
container_title Journal of materials chemistry. A, Materials for energy and sustainability
container_volume 3
creator Ruan, Boyang
Wang, Jun
Shi, Dongqi
Xu, Yanfei
Chou, Shulei
Liu, Huakun
Wang, Jiazhao
description Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. Elemental phosphorus (P) is a very promising anode material for SIBs, with the highest theoretical capacity of 2596 mA h g −1 . Recently, there have been many efforts devoted to phosphorus anode materials for SIBs. As pure red phosphorus cannot react with Na reversibly, many attempts to prepare composite materials containing phosphorus have been reported. Here, we report the facile preparation of a red phosphorus/N-doped carbon nanofiber composite (P/NCF) that can deliver a reversible capacity of 731 mA h g −1 in sodium-ion batteries (SIBs), with a capacity retention of 57.3% over 55 cycles. Our results suggest that it would be a promising anode candidate for SIBs with a high capacity and low cost. Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium.
doi_str_mv 10.1039/c5ta04366b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Anodes
Carbon fibers
Composite materials
Electric batteries
Lithium batteries
Nanofibers
Phosphorus
Sodium
Storage batteries
title A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries
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