A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries
Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. Elemental phosphorus (P) is a very promising anode ma...
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Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2015-01, Vol.3 (37), p.1911-1917 |
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container_end_page | 1917 |
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container_issue | 37 |
container_start_page | 1911 |
container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
container_volume | 3 |
creator | Ruan, Boyang Wang, Jun Shi, Dongqi Xu, Yanfei Chou, Shulei Liu, Huakun Wang, Jiazhao |
description | Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. Elemental phosphorus (P) is a very promising anode material for SIBs, with the highest theoretical capacity of 2596 mA h g
−1
. Recently, there have been many efforts devoted to phosphorus anode materials for SIBs. As pure red phosphorus cannot react with Na reversibly, many attempts to prepare composite materials containing phosphorus have been reported. Here, we report the facile preparation of a red phosphorus/N-doped carbon nanofiber composite (P/NCF) that can deliver a reversible capacity of 731 mA h g
−1
in sodium-ion batteries (SIBs), with a capacity retention of 57.3% over 55 cycles. Our results suggest that it would be a promising anode candidate for SIBs with a high capacity and low cost.
Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. |
doi_str_mv | 10.1039/c5ta04366b |
format | Article |
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−1
. Recently, there have been many efforts devoted to phosphorus anode materials for SIBs. As pure red phosphorus cannot react with Na reversibly, many attempts to prepare composite materials containing phosphorus have been reported. Here, we report the facile preparation of a red phosphorus/N-doped carbon nanofiber composite (P/NCF) that can deliver a reversible capacity of 731 mA h g
−1
in sodium-ion batteries (SIBs), with a capacity retention of 57.3% over 55 cycles. Our results suggest that it would be a promising anode candidate for SIBs with a high capacity and low cost.
Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c5ta04366b</identifier><language>eng</language><subject>Anodes ; Carbon fibers ; Composite materials ; Electric batteries ; Lithium batteries ; Nanofibers ; Phosphorus ; Sodium ; Storage batteries</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2015-01, Vol.3 (37), p.1911-1917</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c452t-408bfa91e45e8289322794c4be3da6cb4307dbc80c113791c37ef37b2d1e6ef3</citedby><cites>FETCH-LOGICAL-c452t-408bfa91e45e8289322794c4be3da6cb4307dbc80c113791c37ef37b2d1e6ef3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Ruan, Boyang</creatorcontrib><creatorcontrib>Wang, Jun</creatorcontrib><creatorcontrib>Shi, Dongqi</creatorcontrib><creatorcontrib>Xu, Yanfei</creatorcontrib><creatorcontrib>Chou, Shulei</creatorcontrib><creatorcontrib>Liu, Huakun</creatorcontrib><creatorcontrib>Wang, Jiazhao</creatorcontrib><title>A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. Elemental phosphorus (P) is a very promising anode material for SIBs, with the highest theoretical capacity of 2596 mA h g
−1
. Recently, there have been many efforts devoted to phosphorus anode materials for SIBs. As pure red phosphorus cannot react with Na reversibly, many attempts to prepare composite materials containing phosphorus have been reported. Here, we report the facile preparation of a red phosphorus/N-doped carbon nanofiber composite (P/NCF) that can deliver a reversible capacity of 731 mA h g
−1
in sodium-ion batteries (SIBs), with a capacity retention of 57.3% over 55 cycles. Our results suggest that it would be a promising anode candidate for SIBs with a high capacity and low cost.
Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium.</description><subject>Anodes</subject><subject>Carbon fibers</subject><subject>Composite materials</subject><subject>Electric batteries</subject><subject>Lithium batteries</subject><subject>Nanofibers</subject><subject>Phosphorus</subject><subject>Sodium</subject><subject>Storage batteries</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkUtLxEAMxwdRcFn34l0YbyLUnVc7M8d18QWLXvYqZR4pVtpOnWkPfnu7rqw3MSTkD_klhAShc0puKOF66fLBEMGLwh6hGSM5yaTQxfFBK3WKFim9k8kUIYXWM_S6wv1bSFPEMS2fMx968NiZaEOHO9OFqrYQsQttH1I9ADYJm27y4AG3ZoBYmwZXIeIUfD22WT31WTPsCpDO0EllmgSLnzxH2_u77fox27w8PK1Xm8yJnA2ZIMpWRlMQOSimNGdMauGEBe5N4azgRHrrFHGUcqmp4xIqLi3zFIpJzdHVfmwfw8cIaSjbOjloGtNBGFNJZc6FkiyX_0A5U5wSyif0eo-6GFKKUJV9rFsTP0tKyt3By3W-XX0f_HaCL_dwTO7A_T6k7P1uzYu_GP4FaBeIMQ</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Ruan, Boyang</creator><creator>Wang, Jun</creator><creator>Shi, Dongqi</creator><creator>Xu, Yanfei</creator><creator>Chou, Shulei</creator><creator>Liu, Huakun</creator><creator>Wang, Jiazhao</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7U6</scope><scope>C1K</scope><scope>7SP</scope><scope>7SR</scope><scope>7SU</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150101</creationdate><title>A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries</title><author>Ruan, Boyang ; Wang, Jun ; Shi, Dongqi ; Xu, Yanfei ; Chou, Shulei ; Liu, Huakun ; Wang, Jiazhao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c452t-408bfa91e45e8289322794c4be3da6cb4307dbc80c113791c37ef37b2d1e6ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Anodes</topic><topic>Carbon fibers</topic><topic>Composite materials</topic><topic>Electric batteries</topic><topic>Lithium batteries</topic><topic>Nanofibers</topic><topic>Phosphorus</topic><topic>Sodium</topic><topic>Storage batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ruan, Boyang</creatorcontrib><creatorcontrib>Wang, Jun</creatorcontrib><creatorcontrib>Shi, Dongqi</creatorcontrib><creatorcontrib>Xu, Yanfei</creatorcontrib><creatorcontrib>Chou, Shulei</creatorcontrib><creatorcontrib>Liu, Huakun</creatorcontrib><creatorcontrib>Wang, Jiazhao</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ruan, Boyang</au><au>Wang, Jun</au><au>Shi, Dongqi</au><au>Xu, Yanfei</au><au>Chou, Shulei</au><au>Liu, Huakun</au><au>Wang, Jiazhao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>3</volume><issue>37</issue><spage>1911</spage><epage>1917</epage><pages>1911-1917</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium. Elemental phosphorus (P) is a very promising anode material for SIBs, with the highest theoretical capacity of 2596 mA h g
−1
. Recently, there have been many efforts devoted to phosphorus anode materials for SIBs. As pure red phosphorus cannot react with Na reversibly, many attempts to prepare composite materials containing phosphorus have been reported. Here, we report the facile preparation of a red phosphorus/N-doped carbon nanofiber composite (P/NCF) that can deliver a reversible capacity of 731 mA h g
−1
in sodium-ion batteries (SIBs), with a capacity retention of 57.3% over 55 cycles. Our results suggest that it would be a promising anode candidate for SIBs with a high capacity and low cost.
Sodium-ion batteries (SIBs) have been attracting intensive attention at present as the most promising alternative to lithium-ion batteries in large-scale electrical energy storage applications, due to the low-cost and natural abundance of sodium.</abstract><doi>10.1039/c5ta04366b</doi><tpages>7</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Anodes Carbon fibers Composite materials Electric batteries Lithium batteries Nanofibers Phosphorus Sodium Storage batteries |
title | A phosphorus/N-doped carbon nanofiber composite as an anode material for sodium-ion batteries |
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