ROMP of acetoxy-substituted dicyclopentadiene to a linear polymer with a high T g

ROMP of acetoxy-substituted dicyclopentadiene to a linear polymer with a high T g

A polydicyclopentadiene derivative was obtained via ring-opening metathesis polymerization (ROMP) of acetoxy-substituted dicyclopentadiene (AcO-DCPD) using the Grubbs 1 st generation catalyst. Analyses of the polymer microstructures indicate that polymers are linear. The glass transition temperature...

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Veröffentlicht in:RSC advances 2015, Vol.5 (33), p.26185-26188
Hauptverfasser: Gong, Laijiang, Liu, Kun, Ou, Encai, Xu, Feng, Lu, Yanbing, Wang, Zhao, Gao, Tao, Yang, Zhongkui, Xu, Weijian
Format: Artikel
Sprache:eng
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Zusammenfassung:A polydicyclopentadiene derivative was obtained via ring-opening metathesis polymerization (ROMP) of acetoxy-substituted dicyclopentadiene (AcO-DCPD) using the Grubbs 1 st generation catalyst. Analyses of the polymer microstructures indicate that polymers are linear. The glass transition temperatures ( T g ) of the linear polymers range from 136 °C to 159 °C, which are much higher than that of linear polydicyclopentadiene.
ISSN:2046-2069
2046-2069
DOI:10.1039/C5RA01855B