Activation of carbon dioxide by new mixed sandwich uranium( iii ) complexes incorporating cyclooctatetraenyl and pyrrolide, phospholide, or arsolide ligands

A series of uranium( iii ) mixed-sandwich complexes of the type [U(COT TIPS2 )(Cp EMe4 )] (Cp EMe4 = EC 4 Me 4 , E is N, P or As, and COT TIPS2 = C 8 H 6 {1,4-Si i Pr 3 }), featuring a heterocyclic five membered ring, have been synthesised and their X-ray crystal structures determined. The redox pro...

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Veröffentlicht in:	New journal of chemistry 2015-01, Vol.39 (10), p.7602-7607
Hauptverfasser:	Kahan, Rachel J., Cloke, F. Geoffrey N., Roe, S. Mark, Nief, François
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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