Chemical recycling of unsaturated polyester resin and its composites via selective cleavage of the ester bond

An efficient strategy has been developed for chemical recycling of unsaturated polyester resin (UPR) and its glass fibre reinforced polymer composites (GFRP) by selectively cleaving C–O bonds using the AlCl 3 /CH 3 COOH system. AlCl 3 promotes acyl exchange reaction between CH 3 COOH and UPR. This p...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2015-01, Vol.17 (9), p.4527-4532
Hauptverfasser: Wang, Yuqi, Cui, Xiaojing, Yang, Qiqi, Deng, Tiansheng, Wang, Yingxiong, Yang, Yongxing, Jia, Shiyu, Qin, Zhangfeng, Hou, Xianglin
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Sprache:eng
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Zusammenfassung:An efficient strategy has been developed for chemical recycling of unsaturated polyester resin (UPR) and its glass fibre reinforced polymer composites (GFRP) by selectively cleaving C–O bonds using the AlCl 3 /CH 3 COOH system. AlCl 3 promotes acyl exchange reaction between CH 3 COOH and UPR. This process facilitates recovery of valuable oligomers and monomers from UPR, and glass fibres from GFRP.
ISSN:1463-9262
1463-9270
DOI:10.1039/C5GC01048A