Exploring the role of the 3-center–4-electron bond in hypervalent λ 3 -iodanes using the methodology of domain averaged Fermi holes

Hypervalent iodine compounds, in particular λ 3 -iodanes, have become important reagents in organic synthesis for the electrophilic transfer of substituents to arenes and other nucleophiles. The structure and reactivity of these compounds are usually described based on a 3-center–4-electron bond mod...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016, Vol.18 (2), p.846-856
Hauptverfasser:	Pinto de Magalhães, Halua, Lüthi, Hans Peter, Bultinck, Patrick
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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