Ameliorated synthetic methodology for crystalline lanthanoid-metalloporphyrin open frameworks based on a multitopic octacarboxy-porphyrin scaffold: structural, gas sorption and photophysical properties

New crystalline lanthanoid-metalloporphyrin porous frameworks [(Zn(H 2 O)-OCPP)Ln 2 (H 2 O) 4 Na 2 ] n ·solvent (Ln = Sm, Eu, Gd, Tb, and Dy) (LnMPF-1) were synthesized from an octatopic tetrakis-(3,5-dicarboxyphenyl)porphyrin building block through a synthetic approach using NaOH as a modulator to...

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Veröffentlicht in:	CrystEngComm 2016-01, Vol.18 (4), p.515-52
Hauptverfasser:	Tripuramallu, Bharat Kumar, Titi, Hatem M, Roy, Sadipan, Verma, Roli, Goldberg, Israel
Format:	Artikel
Sprache:	eng
Schlagworte:	Channels Crystal structure Crystals Dysprosium Modulators Porosity Robustness Samarium
Online-Zugang:	Volltext
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