Discovery of a non classic host guest complexation mode in a β-cyclodextrin/propionic acid model
A non-classic complexation mode was discovered upon spectroscopic, thermodynamic, crystallographic and computational studies of a β-cyclodextrin/propionic acid complex. A "fully immersed" complexation phenomenon, where both the guest's hydrophobic and polar moieties are located inside...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2016-02, Vol.52 (12), p.2565-2568 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Rutenberg, R Leitus, G Fallik, E Poverenov, E |
| description | A non-classic complexation mode was discovered upon spectroscopic, thermodynamic, crystallographic and computational studies of a β-cyclodextrin/propionic acid complex. A "fully immersed" complexation phenomenon, where both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it, was found and calculated as the most favorable configuration.
A non-classic complexation mode was discovered using a β-cyclodextrin/propionic acid model. A "fully immersed" complexation phenomenon was found in which both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it. This configuration was also found to be the most favorable and probable. |
| doi_str_mv | 10.1039/c5cc09676f |
| format | Article |
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A non-classic complexation mode was discovered using a β-cyclodextrin/propionic acid model. A "fully immersed" complexation phenomenon was found in which both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it. This configuration was also found to be the most favorable and probable.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc09676f</identifier><identifier>PMID: 26744749</identifier><language>eng</language><publisher>England</publisher><subject>Complexation ; Computation ; Crystallography ; Mathematical models ; Propionic acid ; Spectroscopic analysis ; Spectroscopy ; Thermodynamics</subject><ispartof>Chemical communications (Cambridge, England), 2016-02, Vol.52 (12), p.2565-2568</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c342t-34e881c4dffcb43661893df2714ba9e39b366f0c20600af0ba7f9d980f72a2433</citedby><cites>FETCH-LOGICAL-c342t-34e881c4dffcb43661893df2714ba9e39b366f0c20600af0ba7f9d980f72a2433</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26744749$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rutenberg, R</creatorcontrib><creatorcontrib>Leitus, G</creatorcontrib><creatorcontrib>Fallik, E</creatorcontrib><creatorcontrib>Poverenov, E</creatorcontrib><title>Discovery of a non classic host guest complexation mode in a β-cyclodextrin/propionic acid model</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A non-classic complexation mode was discovered upon spectroscopic, thermodynamic, crystallographic and computational studies of a β-cyclodextrin/propionic acid complex. A "fully immersed" complexation phenomenon, where both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it, was found and calculated as the most favorable configuration.
A non-classic complexation mode was discovered using a β-cyclodextrin/propionic acid model. A "fully immersed" complexation phenomenon was found in which both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it. This configuration was also found to be the most favorable and probable.</description><subject>Complexation</subject><subject>Computation</subject><subject>Crystallography</subject><subject>Mathematical models</subject><subject>Propionic acid</subject><subject>Spectroscopic analysis</subject><subject>Spectroscopy</subject><subject>Thermodynamics</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkctOwzAQRS0EoqWwYQ_KEiGF2vF7iQIFpEpsQGIXOY4NQUkc7Ba1v8WH8E24D8oSL8aPOTO6cw3AKYJXCGI51lRrKBlndg8MEWYkpUS87K_OVKYcEzoARyG8w7gQFYdgkDFOCCdyCNRNHbT7NH6ZOJuopHNdohsVQq2TNxdmyevcxKhd2zdmoWZ1zLeuMkndRfr7K9VL3cT7Yubrbtx710ci1ipdV2uwOQYHVjXBnGz3EXie3D7l9-n08e4hv56mGpNslmJihECaVNbqkmDGkJC4shlHpFTSYFnGNwt1BhmEysJScSsrKaDlmcoIxiNwsekbRXysRBdtHM00jeqMm4cCCQgJlRKK_1HOsigKUhnRyw2qvQvBG1v0vm6VXxYIFiv3i5zm-dr9SYTPt33nZWuqHfprdwTONoAPepf9-z78A-4riiw</recordid><startdate>20160211</startdate><enddate>20160211</enddate><creator>Rutenberg, R</creator><creator>Leitus, G</creator><creator>Fallik, E</creator><creator>Poverenov, E</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160211</creationdate><title>Discovery of a non classic host guest complexation mode in a β-cyclodextrin/propionic acid model</title><author>Rutenberg, R ; Leitus, G ; Fallik, E ; Poverenov, E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c342t-34e881c4dffcb43661893df2714ba9e39b366f0c20600af0ba7f9d980f72a2433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Complexation</topic><topic>Computation</topic><topic>Crystallography</topic><topic>Mathematical models</topic><topic>Propionic acid</topic><topic>Spectroscopic analysis</topic><topic>Spectroscopy</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rutenberg, R</creatorcontrib><creatorcontrib>Leitus, G</creatorcontrib><creatorcontrib>Fallik, E</creatorcontrib><creatorcontrib>Poverenov, E</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rutenberg, R</au><au>Leitus, G</au><au>Fallik, E</au><au>Poverenov, E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Discovery of a non classic host guest complexation mode in a β-cyclodextrin/propionic acid model</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-02-11</date><risdate>2016</risdate><volume>52</volume><issue>12</issue><spage>2565</spage><epage>2568</epage><pages>2565-2568</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A non-classic complexation mode was discovered upon spectroscopic, thermodynamic, crystallographic and computational studies of a β-cyclodextrin/propionic acid complex. A "fully immersed" complexation phenomenon, where both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it, was found and calculated as the most favorable configuration.
A non-classic complexation mode was discovered using a β-cyclodextrin/propionic acid model. A "fully immersed" complexation phenomenon was found in which both the guest's hydrophobic and polar moieties are located inside the host and are stabilized by it. This configuration was also found to be the most favorable and probable.</abstract><cop>England</cop><pmid>26744749</pmid><doi>10.1039/c5cc09676f</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Complexation Computation Crystallography Mathematical models Propionic acid Spectroscopic analysis Spectroscopy Thermodynamics |
| title | Discovery of a non classic host guest complexation mode in a β-cyclodextrin/propionic acid model |
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