Topologically diverse shape-persistent bis-(Zn-salphen) catalysts: efficient cyclic carbonate formation under mild conditions

By adopting a shape-persistent bimetallic design approach, high initial molecular turnover frequencies (up to 14 800 h −1 ) for coupling of CO 2 with epoxides in conjunction with n Bu 4 NI, plus excellent yields under mild conditions (1 bar of CO 2 , 45 °C) have been achieved for catalysts containin...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (5), p.117-12
Hauptverfasser:	He, Shixiong, Wang, Fuli, Tong, Wah-Leung, Yiu, Shek-Man, Chan, Michael C. W
Format:	Artikel
Sprache:	eng
Schlagworte:	Bimetals Carbon dioxide Carbonates Catalysis Catalysts Coupling (molecular) Formations Zinc
Online-Zugang:	Volltext
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