One-pot synthesis and characterization of chalcopyrite CuInS 2 nanoparticles
We synthesized tetragonal chalcopyrite CuInS 2 (CIS) nanoparticles from molecular single source precursors, (Ph 3 P) 2 Cu-(μ-SEt) 2 In(SEt) 2 , by a one-pot reaction in the presence of 3-mercaptopropionic acid at reaction times of 3 hours or less with high yields. In our approach, NaCl as a by-produ...
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Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2014, Vol.2 (27), p.10629-10633 |
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container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
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creator | Sun, Chivin Cevher, Zehra Zhang, Jin Gao, Bo Shum, Kai Ren, Yuhang |
description | We synthesized tetragonal chalcopyrite CuInS
2
(CIS) nanoparticles from molecular single source precursors, (Ph
3
P)
2
Cu-(μ-SEt)
2
In(SEt)
2
, by a one-pot reaction in the presence of 3-mercaptopropionic acid at reaction times of 3 hours or less with high yields. In our approach, NaCl as a by-product was used as a heat transfer agent
via
a conventional convective heating method. We tuned the sizes of nanoparticles through manipulation of the reaction temperature, reaction time, precursor, and thiol concentration. The sizes of nanoparticles from 1.8 nm to 5.2 nm were obtained as reaction temperatures were increased from 150 °C to 190 °C. The method developed in this study is scalable to achieve production of ultra-large quantities of tetragonal chalcopyrite CIS nanoparticles. The resulting nanoparticles were analyzed by UV-vis spectroscopy, X-ray diffraction, EDAX, and HRTEM. |
doi_str_mv | 10.1039/C4TA01062K |
format | Article |
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2
(CIS) nanoparticles from molecular single source precursors, (Ph
3
P)
2
Cu-(μ-SEt)
2
In(SEt)
2
, by a one-pot reaction in the presence of 3-mercaptopropionic acid at reaction times of 3 hours or less with high yields. In our approach, NaCl as a by-product was used as a heat transfer agent
via
a conventional convective heating method. We tuned the sizes of nanoparticles through manipulation of the reaction temperature, reaction time, precursor, and thiol concentration. The sizes of nanoparticles from 1.8 nm to 5.2 nm were obtained as reaction temperatures were increased from 150 °C to 190 °C. The method developed in this study is scalable to achieve production of ultra-large quantities of tetragonal chalcopyrite CIS nanoparticles. The resulting nanoparticles were analyzed by UV-vis spectroscopy, X-ray diffraction, EDAX, and HRTEM.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/C4TA01062K</identifier><language>eng</language><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2014, Vol.2 (27), p.10629-10633</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76K-96b2ce1ca57e7f8e728b8f1b8a93d37d15e20092f85b2b04bbb537f5338939e13</citedby><cites>FETCH-LOGICAL-c76K-96b2ce1ca57e7f8e728b8f1b8a93d37d15e20092f85b2b04bbb537f5338939e13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Sun, Chivin</creatorcontrib><creatorcontrib>Cevher, Zehra</creatorcontrib><creatorcontrib>Zhang, Jin</creatorcontrib><creatorcontrib>Gao, Bo</creatorcontrib><creatorcontrib>Shum, Kai</creatorcontrib><creatorcontrib>Ren, Yuhang</creatorcontrib><title>One-pot synthesis and characterization of chalcopyrite CuInS 2 nanoparticles</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>We synthesized tetragonal chalcopyrite CuInS
2
(CIS) nanoparticles from molecular single source precursors, (Ph
3
P)
2
Cu-(μ-SEt)
2
In(SEt)
2
, by a one-pot reaction in the presence of 3-mercaptopropionic acid at reaction times of 3 hours or less with high yields. In our approach, NaCl as a by-product was used as a heat transfer agent
via
a conventional convective heating method. We tuned the sizes of nanoparticles through manipulation of the reaction temperature, reaction time, precursor, and thiol concentration. The sizes of nanoparticles from 1.8 nm to 5.2 nm were obtained as reaction temperatures were increased from 150 °C to 190 °C. The method developed in this study is scalable to achieve production of ultra-large quantities of tetragonal chalcopyrite CIS nanoparticles. The resulting nanoparticles were analyzed by UV-vis spectroscopy, X-ray diffraction, EDAX, and HRTEM.</description><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpFkL1OwzAYRS0EElXpwhN4Rgp8tuPYHquIn6qROpA9sh1bNSp2ZIchPD1UILjLvTrDHQ5CtwTuCTD10Nb9Fgg0dH-BVhQ4VKJWzeXflvIabUp5g-9IgEapFeoO0VVTmnFZ4nx0JRSs44jtUWdtZ5fDp55Dijj5MzvZNC05zA63H7v4iimOOqZJ5znYkys36MrrU3Gb316j_umxb1-q7vC8a7ddZUWzr1RjqHXEai6c8NIJKo30xEit2MjESLijAIp6yQ01UBtjOBOeMyYVU46wNbr7ubU5lZKdH6Yc3nVeBgLD2cTwb4J9AcJUUKQ</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Sun, Chivin</creator><creator>Cevher, Zehra</creator><creator>Zhang, Jin</creator><creator>Gao, Bo</creator><creator>Shum, Kai</creator><creator>Ren, Yuhang</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2014</creationdate><title>One-pot synthesis and characterization of chalcopyrite CuInS 2 nanoparticles</title><author>Sun, Chivin ; Cevher, Zehra ; Zhang, Jin ; Gao, Bo ; Shum, Kai ; Ren, Yuhang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76K-96b2ce1ca57e7f8e728b8f1b8a93d37d15e20092f85b2b04bbb537f5338939e13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Chivin</creatorcontrib><creatorcontrib>Cevher, Zehra</creatorcontrib><creatorcontrib>Zhang, Jin</creatorcontrib><creatorcontrib>Gao, Bo</creatorcontrib><creatorcontrib>Shum, Kai</creatorcontrib><creatorcontrib>Ren, Yuhang</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Chivin</au><au>Cevher, Zehra</au><au>Zhang, Jin</au><au>Gao, Bo</au><au>Shum, Kai</au><au>Ren, Yuhang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-pot synthesis and characterization of chalcopyrite CuInS 2 nanoparticles</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2014</date><risdate>2014</risdate><volume>2</volume><issue>27</issue><spage>10629</spage><epage>10633</epage><pages>10629-10633</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>We synthesized tetragonal chalcopyrite CuInS
2
(CIS) nanoparticles from molecular single source precursors, (Ph
3
P)
2
Cu-(μ-SEt)
2
In(SEt)
2
, by a one-pot reaction in the presence of 3-mercaptopropionic acid at reaction times of 3 hours or less with high yields. In our approach, NaCl as a by-product was used as a heat transfer agent
via
a conventional convective heating method. We tuned the sizes of nanoparticles through manipulation of the reaction temperature, reaction time, precursor, and thiol concentration. The sizes of nanoparticles from 1.8 nm to 5.2 nm were obtained as reaction temperatures were increased from 150 °C to 190 °C. The method developed in this study is scalable to achieve production of ultra-large quantities of tetragonal chalcopyrite CIS nanoparticles. The resulting nanoparticles were analyzed by UV-vis spectroscopy, X-ray diffraction, EDAX, and HRTEM.</abstract><doi>10.1039/C4TA01062K</doi><tpages>5</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
title | One-pot synthesis and characterization of chalcopyrite CuInS 2 nanoparticles |
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