Facile synthesis of single crystalline sub-micron Cu 2 ZnSnS 4 (CZTS) powders using solvothermal treatment
Single crystalline sub-micron Cu 2 ZnSnS 4 (CZTS) powders were successfully synthesized by a facile solvothermal method, using l -cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 °C after 5 h, with the irregular polygonal particle siz...
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| Veröffentlicht in: | RSC advances 2015, Vol.5 (9), p.6682-6686 |
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| container_title | RSC advances |
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| creator | Chen, Shanlong Tao, Haijun Shen, Yizhou Zhu, Lumin Zeng, Xiaofei Tao, Jie Wang, Tao |
| description | Single crystalline sub-micron Cu
2
ZnSnS
4
(CZTS) powders were successfully synthesized by a facile solvothermal method, using
l
-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 °C after 5 h, with the irregular polygonal particle size being 500 nm to 1 μm. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H
2
S released from
l
-cysteine had an impact on the growth of CZTS particles at high temperature. Further, the as-synthesized CZTS powders were used as counter electrode for dye-sensitized solar cells (DSSCs) and it is indicated that the CZTS counter electrode based DSSCs show a conversion efficiency of 4.243%. |
| doi_str_mv | 10.1039/C4RA12815J |
| format | Article |
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2
ZnSnS
4
(CZTS) powders were successfully synthesized by a facile solvothermal method, using
l
-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 °C after 5 h, with the irregular polygonal particle size being 500 nm to 1 μm. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H
2
S released from
l
-cysteine had an impact on the growth of CZTS particles at high temperature. Further, the as-synthesized CZTS powders were used as counter electrode for dye-sensitized solar cells (DSSCs) and it is indicated that the CZTS counter electrode based DSSCs show a conversion efficiency of 4.243%.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA12815J</identifier><language>eng</language><ispartof>RSC advances, 2015, Vol.5 (9), p.6682-6686</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76J-feb763673735a920393050deca4dcb615e52bd9b54df09da2d5e2574cf5f5f83</citedby><cites>FETCH-LOGICAL-c76J-feb763673735a920393050deca4dcb615e52bd9b54df09da2d5e2574cf5f5f83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Chen, Shanlong</creatorcontrib><creatorcontrib>Tao, Haijun</creatorcontrib><creatorcontrib>Shen, Yizhou</creatorcontrib><creatorcontrib>Zhu, Lumin</creatorcontrib><creatorcontrib>Zeng, Xiaofei</creatorcontrib><creatorcontrib>Tao, Jie</creatorcontrib><creatorcontrib>Wang, Tao</creatorcontrib><title>Facile synthesis of single crystalline sub-micron Cu 2 ZnSnS 4 (CZTS) powders using solvothermal treatment</title><title>RSC advances</title><description>Single crystalline sub-micron Cu
2
ZnSnS
4
(CZTS) powders were successfully synthesized by a facile solvothermal method, using
l
-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 °C after 5 h, with the irregular polygonal particle size being 500 nm to 1 μm. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H
2
S released from
l
-cysteine had an impact on the growth of CZTS particles at high temperature. Further, the as-synthesized CZTS powders were used as counter electrode for dye-sensitized solar cells (DSSCs) and it is indicated that the CZTS counter electrode based DSSCs show a conversion efficiency of 4.243%.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpNUE1Lw0AQXUTBUnvxF-xRheh-pzmWYNVSEExPvYTNfmjKZlN2EyX_3i0KOu8wjzfMY-YBcI3RPUa0eCjZ2wqTJeabMzAjiImMIFGc_-OXYBHjAaUSHBOBZ-Cwlqp1BsbJDx8mthH2FsbWvydNhSkO0rnWp_nYZF2rQu9hOUIC977yFWTwptzvqlt47L-0CRGOp1UYe_fZJ7vQSQeHYOTQGT9cgQsrXTSL3z4H1fpxVz5n29enl3K1zVQuNpk1TS6oyGlOuSxI-osijrRRkmnVCMwNJ40uGs60RYWWRHNDeM6U5QlLOgd3P67p1hiDsfUxtJ0MU41RfYqp_ouJfgNAalrJ</recordid><startdate>2015</startdate><enddate>2015</enddate><creator>Chen, Shanlong</creator><creator>Tao, Haijun</creator><creator>Shen, Yizhou</creator><creator>Zhu, Lumin</creator><creator>Zeng, Xiaofei</creator><creator>Tao, Jie</creator><creator>Wang, Tao</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2015</creationdate><title>Facile synthesis of single crystalline sub-micron Cu 2 ZnSnS 4 (CZTS) powders using solvothermal treatment</title><author>Chen, Shanlong ; Tao, Haijun ; Shen, Yizhou ; Zhu, Lumin ; Zeng, Xiaofei ; Tao, Jie ; Wang, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76J-feb763673735a920393050deca4dcb615e52bd9b54df09da2d5e2574cf5f5f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Shanlong</creatorcontrib><creatorcontrib>Tao, Haijun</creatorcontrib><creatorcontrib>Shen, Yizhou</creatorcontrib><creatorcontrib>Zhu, Lumin</creatorcontrib><creatorcontrib>Zeng, Xiaofei</creatorcontrib><creatorcontrib>Tao, Jie</creatorcontrib><creatorcontrib>Wang, Tao</creatorcontrib><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Shanlong</au><au>Tao, Haijun</au><au>Shen, Yizhou</au><au>Zhu, Lumin</au><au>Zeng, Xiaofei</au><au>Tao, Jie</au><au>Wang, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis of single crystalline sub-micron Cu 2 ZnSnS 4 (CZTS) powders using solvothermal treatment</atitle><jtitle>RSC advances</jtitle><date>2015</date><risdate>2015</risdate><volume>5</volume><issue>9</issue><spage>6682</spage><epage>6686</epage><pages>6682-6686</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Single crystalline sub-micron Cu
2
ZnSnS
4
(CZTS) powders were successfully synthesized by a facile solvothermal method, using
l
-cysteine as sulfur precursor. It was confirmed that pure kesterite structured CZTS powders were synthesized at 400 °C after 5 h, with the irregular polygonal particle size being 500 nm to 1 μm. Interestingly, single crystalline CZTS particles were also obtained by simple solvothermal treatment without post annealing. The H
2
S released from
l
-cysteine had an impact on the growth of CZTS particles at high temperature. Further, the as-synthesized CZTS powders were used as counter electrode for dye-sensitized solar cells (DSSCs) and it is indicated that the CZTS counter electrode based DSSCs show a conversion efficiency of 4.243%.</abstract><doi>10.1039/C4RA12815J</doi><tpages>5</tpages></addata></record> |
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| ispartof | RSC advances, 2015, Vol.5 (9), p.6682-6686 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_C4RA12815J |
| source | Royal Society Of Chemistry Journals 2008- |
| title | Facile synthesis of single crystalline sub-micron Cu 2 ZnSnS 4 (CZTS) powders using solvothermal treatment |
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