WS 2 nanoparticles – potential replacement for ZDDP and friction modifier additives
In high-pressure, high-temperature sliding contacts, WS 2 nanoadditives react with the metal substrate to generate 100+ nm chemical tribofilms with a layered structure and excellent tribological properties. The friction, wear and micromechanical properties of WS 2 tribofilms are compared with those...
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Veröffentlicht in: | RSC advances 2014, Vol.4 (41), p.21238-21245 |
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creator | Ratoi, M. Niste, V. B. Zekonyte, J. |
description | In high-pressure, high-temperature sliding contacts, WS
2
nanoadditives react with the metal substrate to generate 100+ nm chemical tribofilms with a layered structure and excellent tribological properties. The friction, wear and micromechanical properties of WS
2
tribofilms are compared with those of tribofilms formed by the zinc dialkyldithiophosphate (ZDDP) antiwear additive and ZDDP-organic friction modifier (OFM) mixture. Nanoindentation measurements showed that WS
2
generates tribofilms with higher values of hardness and Young's modulus than ZDDP and ZDDP + OFM, which explains its excellent antiwear properties. The friction performance of WS
2
surpassed that of ZDDP + OFM. The striking reduction of boundary friction is credited to the layered structure of the WS
2
tribofilm, with exfoliated/squashed WS
2
nanoparticles that fill the gaps and cover the reacted tribofilm. In view of these results, WS
2
proves to be a suitable candidate for the replacement of problematic lubricant additives currently in use. |
doi_str_mv | 10.1039/C4RA01795A |
format | Article |
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2
nanoadditives react with the metal substrate to generate 100+ nm chemical tribofilms with a layered structure and excellent tribological properties. The friction, wear and micromechanical properties of WS
2
tribofilms are compared with those of tribofilms formed by the zinc dialkyldithiophosphate (ZDDP) antiwear additive and ZDDP-organic friction modifier (OFM) mixture. Nanoindentation measurements showed that WS
2
generates tribofilms with higher values of hardness and Young's modulus than ZDDP and ZDDP + OFM, which explains its excellent antiwear properties. The friction performance of WS
2
surpassed that of ZDDP + OFM. The striking reduction of boundary friction is credited to the layered structure of the WS
2
tribofilm, with exfoliated/squashed WS
2
nanoparticles that fill the gaps and cover the reacted tribofilm. In view of these results, WS
2
proves to be a suitable candidate for the replacement of problematic lubricant additives currently in use.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA01795A</identifier><language>eng</language><ispartof>RSC advances, 2014, Vol.4 (41), p.21238-21245</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76A-e9d8183aa9974811e324524c3393620984110ab1029d15fe6435b41bdcc5c6633</citedby><cites>FETCH-LOGICAL-c76A-e9d8183aa9974811e324524c3393620984110ab1029d15fe6435b41bdcc5c6633</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Ratoi, M.</creatorcontrib><creatorcontrib>Niste, V. B.</creatorcontrib><creatorcontrib>Zekonyte, J.</creatorcontrib><title>WS 2 nanoparticles – potential replacement for ZDDP and friction modifier additives</title><title>RSC advances</title><description>In high-pressure, high-temperature sliding contacts, WS
2
nanoadditives react with the metal substrate to generate 100+ nm chemical tribofilms with a layered structure and excellent tribological properties. The friction, wear and micromechanical properties of WS
2
tribofilms are compared with those of tribofilms formed by the zinc dialkyldithiophosphate (ZDDP) antiwear additive and ZDDP-organic friction modifier (OFM) mixture. Nanoindentation measurements showed that WS
2
generates tribofilms with higher values of hardness and Young's modulus than ZDDP and ZDDP + OFM, which explains its excellent antiwear properties. The friction performance of WS
2
surpassed that of ZDDP + OFM. The striking reduction of boundary friction is credited to the layered structure of the WS
2
tribofilm, with exfoliated/squashed WS
2
nanoparticles that fill the gaps and cover the reacted tribofilm. In view of these results, WS
2
proves to be a suitable candidate for the replacement of problematic lubricant additives currently in use.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNkMtKxDAYhYMoOIyz8QmyFqr5c2uzLB11hAFFRwQ3Jc0FIm1TkiK48x18Q5_EEQU9m3O-zVl8CJ0COQfC1EXD72sCpRL1AVpQwmVBiVSH__YxWuX8QvaRAqiEBXp8esAUj3qMk05zML3L-PP9A09xduMcdI-Tm3pt3LBH7GPCz-v1HdajxT4FM4c44iHa4INLWFsb5vDq8gk68rrPbvXbS7S7utw1m2J7e33T1NvClLIunLIVVExrpUpeAThGuaDcMKaYpERVHIDoDghVFoR3kjPRceisMcJIydgSnf3cmhRzTs63UwqDTm8tkPZbSfunhH0BpzZSxg</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Ratoi, M.</creator><creator>Niste, V. B.</creator><creator>Zekonyte, J.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2014</creationdate><title>WS 2 nanoparticles – potential replacement for ZDDP and friction modifier additives</title><author>Ratoi, M. ; Niste, V. B. ; Zekonyte, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76A-e9d8183aa9974811e324524c3393620984110ab1029d15fe6435b41bdcc5c6633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ratoi, M.</creatorcontrib><creatorcontrib>Niste, V. B.</creatorcontrib><creatorcontrib>Zekonyte, J.</creatorcontrib><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ratoi, M.</au><au>Niste, V. B.</au><au>Zekonyte, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>WS 2 nanoparticles – potential replacement for ZDDP and friction modifier additives</atitle><jtitle>RSC advances</jtitle><date>2014</date><risdate>2014</risdate><volume>4</volume><issue>41</issue><spage>21238</spage><epage>21245</epage><pages>21238-21245</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>In high-pressure, high-temperature sliding contacts, WS
2
nanoadditives react with the metal substrate to generate 100+ nm chemical tribofilms with a layered structure and excellent tribological properties. The friction, wear and micromechanical properties of WS
2
tribofilms are compared with those of tribofilms formed by the zinc dialkyldithiophosphate (ZDDP) antiwear additive and ZDDP-organic friction modifier (OFM) mixture. Nanoindentation measurements showed that WS
2
generates tribofilms with higher values of hardness and Young's modulus than ZDDP and ZDDP + OFM, which explains its excellent antiwear properties. The friction performance of WS
2
surpassed that of ZDDP + OFM. The striking reduction of boundary friction is credited to the layered structure of the WS
2
tribofilm, with exfoliated/squashed WS
2
nanoparticles that fill the gaps and cover the reacted tribofilm. In view of these results, WS
2
proves to be a suitable candidate for the replacement of problematic lubricant additives currently in use.</abstract><doi>10.1039/C4RA01795A</doi><tpages>8</tpages></addata></record> |
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title | WS 2 nanoparticles – potential replacement for ZDDP and friction modifier additives |
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