Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid

A novel protocol for the synthesis of substituted alkenes from alcohols and styrenes using ionic liquid has been developed. The ionic liquid N -methyl-2-pyrrolidone hydrogen sulfate [NMP] + HSO 4 − acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider sub...

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Veröffentlicht in:RSC advances 2014, Vol.4 (43), p.22763-22767
Hauptverfasser: Wagh, Kishor V., Bhanage, Bhalchandra M.
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Bhanage, Bhalchandra M.
description A novel protocol for the synthesis of substituted alkenes from alcohols and styrenes using ionic liquid has been developed. The ionic liquid N -methyl-2-pyrrolidone hydrogen sulfate [NMP] + HSO 4 − acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider substrate applicability. The catalyst was effectively recycled for up to five consecutive cycles.
doi_str_mv 10.1039/C4RA01324G
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title Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid
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