Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid
A novel protocol for the synthesis of substituted alkenes from alcohols and styrenes using ionic liquid has been developed. The ionic liquid N -methyl-2-pyrrolidone hydrogen sulfate [NMP] + HSO 4 − acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider sub...
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Veröffentlicht in: | RSC advances 2014, Vol.4 (43), p.22763-22767 |
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creator | Wagh, Kishor V. Bhanage, Bhalchandra M. |
description | A novel protocol for the synthesis of substituted alkenes from alcohols and styrenes using ionic liquid has been developed. The ionic liquid
N
-methyl-2-pyrrolidone hydrogen sulfate [NMP]
+
HSO
4
−
acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider substrate applicability. The catalyst was effectively recycled for up to five consecutive cycles. |
doi_str_mv | 10.1039/C4RA01324G |
format | Article |
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N
-methyl-2-pyrrolidone hydrogen sulfate [NMP]
+
HSO
4
−
acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider substrate applicability. The catalyst was effectively recycled for up to five consecutive cycles.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA01324G</identifier><language>eng</language><ispartof>RSC advances, 2014, Vol.4 (43), p.22763-22767</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c76G-2c85a30d841254f8dda157adc0234f588549a25b479f1f683c90cd7d799776493</citedby><cites>FETCH-LOGICAL-c76G-2c85a30d841254f8dda157adc0234f588549a25b479f1f683c90cd7d799776493</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Wagh, Kishor V.</creatorcontrib><creatorcontrib>Bhanage, Bhalchandra M.</creatorcontrib><title>Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid</title><title>RSC advances</title><description>A novel protocol for the synthesis of substituted alkenes from alcohols and styrenes using ionic liquid has been developed. The ionic liquid
N
-methyl-2-pyrrolidone hydrogen sulfate [NMP]
+
HSO
4
−
acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider substrate applicability. The catalyst was effectively recycled for up to five consecutive cycles.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNkE1OwzAQhSMEElXphhPMGhSwHedvWSpIkQpF0B1CkeMfYjBxsROh3IA1h-BgnIS0IMFs3ujNN2_xguAQoxOMovx0Rm-nCEeEFjvBiCCahAQl-e6_fT-YeP-EhkliTBI8Cj4LJ2UjHbD12lnGa1DWQVtL8H0ziNcerALfVb7VbddKAcw8Dx8eqh6EdpK3wG23Nrp53JDMcFtb4-FNtzX4tndbuPOb-0D33LDKSDhztvHbOK6F5nB_fXXzAMcwv1sCha_3D9C2GXyjXzstDoI9xYyXk18dB6uL89VsHi6WxeVsugh5mhQh4VnMIiQyiklMVSYEw3HKBEckoirOspjmjMQVTXOFVZJFPEdcpCLN8zRNaB6Ng6OfWO6s906qcu30C3N9iVG56bj86zj6BuORcRk</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Wagh, Kishor V.</creator><creator>Bhanage, Bhalchandra M.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2014</creationdate><title>Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid</title><author>Wagh, Kishor V. ; Bhanage, Bhalchandra M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c76G-2c85a30d841254f8dda157adc0234f588549a25b479f1f683c90cd7d799776493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wagh, Kishor V.</creatorcontrib><creatorcontrib>Bhanage, Bhalchandra M.</creatorcontrib><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wagh, Kishor V.</au><au>Bhanage, Bhalchandra M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid</atitle><jtitle>RSC advances</jtitle><date>2014</date><risdate>2014</risdate><volume>4</volume><issue>43</issue><spage>22763</spage><epage>22767</epage><pages>22763-22767</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A novel protocol for the synthesis of substituted alkenes from alcohols and styrenes using ionic liquid has been developed. The ionic liquid
N
-methyl-2-pyrrolidone hydrogen sulfate [NMP]
+
HSO
4
−
acts as a catalyst as well as solvent. The developed protocol has higher atom efficiency and wider substrate applicability. The catalyst was effectively recycled for up to five consecutive cycles.</abstract><doi>10.1039/C4RA01324G</doi><tpages>5</tpages></addata></record> |
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title | Greener approach for the synthesis of substituted alkenes by direct coupling of alcohols with styrenes using recyclable Bronsted acidic [NMP] + HSO 4 − ionic liquid |
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