A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals
Zirconium-based metal–organic frameworks (MOFs) are of great importance as sorbents due to their increased chemical and thermal stability when compared to other MOF families. Here we report a novel analogue of UiO-66 modified with oxalic acid via solvent-assisted ligand incorporation. This analogue...
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| Veröffentlicht in: | New journal of chemistry 2015-01, Vol.39 (4), p.2396-2399 |
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| container_title | New journal of chemistry |
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| creator | DeCoste, Jared B. Demasky, Tyler J. Katz, Michael J. Farha, Omar K. Hupp, Joseph T. |
| description | Zirconium-based metal–organic frameworks (MOFs) are of great importance as sorbents due to their increased chemical and thermal stability when compared to other MOF families. Here we report a novel analogue of UiO-66 modified with oxalic acid
via
solvent-assisted ligand incorporation. This analogue has the ability to remove ammonia, cyanogen chloride, sulphur dioxide, nitrogen dioxide and octane at levels greater than or equal to the base UiO-66. We report here the highest known capacities exhibited by a MOF for SO
2
and NO
2
, at pressures less than 0.10 bar and at room temperature, by UiO-66-ox. Furthermore, we show here the importance of the secondary building unit of the MOF in the removal of ammonia and cyanogen chloride. |
| doi_str_mv | 10.1039/C4NJ02093F |
| format | Article |
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via
solvent-assisted ligand incorporation. This analogue has the ability to remove ammonia, cyanogen chloride, sulphur dioxide, nitrogen dioxide and octane at levels greater than or equal to the base UiO-66. We report here the highest known capacities exhibited by a MOF for SO
2
and NO
2
, at pressures less than 0.10 bar and at room temperature, by UiO-66-ox. Furthermore, we show here the importance of the secondary building unit of the MOF in the removal of ammonia and cyanogen chloride.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/C4NJ02093F</identifier><language>eng</language><ispartof>New journal of chemistry, 2015-01, Vol.39 (4), p.2396-2399</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c231t-a30f2800588b8f16fc17a3d3449aadfedf5a6a3ca944065f33a49faae9b3615a3</citedby><cites>FETCH-LOGICAL-c231t-a30f2800588b8f16fc17a3d3449aadfedf5a6a3ca944065f33a49faae9b3615a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27915,27916</link.rule.ids></links><search><creatorcontrib>DeCoste, Jared B.</creatorcontrib><creatorcontrib>Demasky, Tyler J.</creatorcontrib><creatorcontrib>Katz, Michael J.</creatorcontrib><creatorcontrib>Farha, Omar K.</creatorcontrib><creatorcontrib>Hupp, Joseph T.</creatorcontrib><title>A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals</title><title>New journal of chemistry</title><description>Zirconium-based metal–organic frameworks (MOFs) are of great importance as sorbents due to their increased chemical and thermal stability when compared to other MOF families. Here we report a novel analogue of UiO-66 modified with oxalic acid
via
solvent-assisted ligand incorporation. This analogue has the ability to remove ammonia, cyanogen chloride, sulphur dioxide, nitrogen dioxide and octane at levels greater than or equal to the base UiO-66. We report here the highest known capacities exhibited by a MOF for SO
2
and NO
2
, at pressures less than 0.10 bar and at room temperature, by UiO-66-ox. Furthermore, we show here the importance of the secondary building unit of the MOF in the removal of ammonia and cyanogen chloride.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpFkL1OwzAYRS0EEqWw8ASekQx2PseNxyqi_KiiC52jL_5pjZK6slNo354gkJjOHa7OcAi5FfxecNAPtXx75QXXsDgjEwFKM10ocT5uISXjpVSX5CrnD86FmCkxIZs5XYcVU4riDru4OTj6FYYtPexMjMmGHQ7OUoOpjcdTFwxFE2ymPiY6bB1tU0TL8t6ZIR16mlwfP7Gj0dMhHse32bo-GOzyNbnwI9zNH6dkvXh8r5_ZcvX0Us-XzBQgBobAfVFxXlZVW3mhvBEzBAtSakTrnfUlKgSDWkquSg-AUntEp1tQokSYkrtfr0kx5-R8s0-hx3RqBG9-EjX_ieAbWhtaZg</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>DeCoste, Jared B.</creator><creator>Demasky, Tyler J.</creator><creator>Katz, Michael J.</creator><creator>Farha, Omar K.</creator><creator>Hupp, Joseph T.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20150101</creationdate><title>A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals</title><author>DeCoste, Jared B. ; Demasky, Tyler J. ; Katz, Michael J. ; Farha, Omar K. ; Hupp, Joseph T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c231t-a30f2800588b8f16fc17a3d3449aadfedf5a6a3ca944065f33a49faae9b3615a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>DeCoste, Jared B.</creatorcontrib><creatorcontrib>Demasky, Tyler J.</creatorcontrib><creatorcontrib>Katz, Michael J.</creatorcontrib><creatorcontrib>Farha, Omar K.</creatorcontrib><creatorcontrib>Hupp, Joseph T.</creatorcontrib><collection>CrossRef</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>DeCoste, Jared B.</au><au>Demasky, Tyler J.</au><au>Katz, Michael J.</au><au>Farha, Omar K.</au><au>Hupp, Joseph T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals</atitle><jtitle>New journal of chemistry</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>39</volume><issue>4</issue><spage>2396</spage><epage>2399</epage><pages>2396-2399</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>Zirconium-based metal–organic frameworks (MOFs) are of great importance as sorbents due to their increased chemical and thermal stability when compared to other MOF families. Here we report a novel analogue of UiO-66 modified with oxalic acid
via
solvent-assisted ligand incorporation. This analogue has the ability to remove ammonia, cyanogen chloride, sulphur dioxide, nitrogen dioxide and octane at levels greater than or equal to the base UiO-66. We report here the highest known capacities exhibited by a MOF for SO
2
and NO
2
, at pressures less than 0.10 bar and at room temperature, by UiO-66-ox. Furthermore, we show here the importance of the secondary building unit of the MOF in the removal of ammonia and cyanogen chloride.</abstract><doi>10.1039/C4NJ02093F</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2015-01, Vol.39 (4), p.2396-2399 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1039_C4NJ02093F |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals |
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