Where does the Raman optical activity of [Rh(en) 3 ] 3+ come from? Insight from a combined experimental and theoretical approach

Backscattered Raman optical activity (ROA) spectra are measured for Δ- and Λ-tris-(ethylenediamine)rhodium( iii ) chloride in aqueous solution. In addition, the spectra of the four possible conformers in the Λ configuration are investigated by ab initio calculations. The Λ( δδδ ) conformer is in bes...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2014-11, Vol.16 (42), p.23260-23273
Hauptverfasser:	Humbert-Droz, Marie, Oulevey, Patric, Lawson Daku, Latévi Max, Luber, Sandra, Hagemann, Hans, Bürgi, Thomas
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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