Does functionalisation enhance CO 2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series
The effect of pore functionalisation (–I, –OH, –OCH 3 ) on a series of topologically equivalent, interpenetrated metal–organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO 2 was observed in the functionalised materials, compared t...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014, Vol.50 (24), p.3238-3241 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Babarao, Ravichandar Coghlan, Campbell J. Rankine, Damien Bloch, Witold M. Gransbury, Gemma K. Sato, Hiroshi Kitagawa, Susumu Sumby, Christopher J. Hill, Matthew R. Doonan, Christian J. |
| description | The effect of pore functionalisation (–I, –OH, –OCH
3
) on a series of topologically equivalent, interpenetrated metal–organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO
2
was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO
2
adsorption. |
| doi_str_mv | 10.1039/C4CC00700J |
| format | Article |
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) on a series of topologically equivalent, interpenetrated metal–organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO
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2
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2014, Vol.50 (24), p.3238-3241 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C4CC00700J |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Does functionalisation enhance CO 2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series |
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