Solvent-controlled synthesis of tetranuclear cage-like copper() silsesquioxanes. Remarkable features of the cage structures and their high catalytic activity in oxidation with peroxides

Two principally different in their molecular architecture isomeric tetranuclear copper( ii ) silsesquioxanes, "Globule"-like compound [(PhSiO 1.5 ) 12 (CuO) 4 (NaO 0.5 ) 4 ] ( 1 ) and "Sandwich"-like derivative [(PhSiO 1.5 ) 6 (CuO) 4 (NaO 0.5 ) 4 (PhSiO 1.5 ) 6 ] ( 2 ), were syn...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-01, Vol.43 (2), p.872-882
Hauptverfasser:	Dronova, Marina S, Bilyachenko, Alexey N, Yalymov, Alexey I, Kozlov, Yuriy N, Shul'pina, Lidia S, Korlyukov, Alexander A, Arkhipov, Dmitry E, Levitsky, Mikhail M, Shubina, Elena S, Shul'pin, Georgiy B
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzene - chemistry Catalysis Chemistry Techniques, Synthetic Copper - chemistry Hydrogen Peroxide - chemistry Isomerism Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Phenylethyl Alcohol - chemistry Solvents - chemistry tert-Butylhydroperoxide - chemistry
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