Reaction of L 2 Zn 2 with Ph 2 E 2 – synthesis of LZnEPh and reactions with oxygen and H-acidic substrates
L 2 Zn 2 (L = HC[C(Me)N(2,4,6-Me 3 C 6 H 2 )] 2 ) and Ph 2 E 2 (E = Se, Te) react to form LZnSePh ( 1 ) and LZnTePh ( 2 ). 1 and 2 further react with H 2 O and EtOH to form LZnOH ( 3 ) and LZnOEt ( 4 ), respectively, whereas the reaction of 2 with oxygen yielded [LZnOTe(O)Ph] 2 ( 5 ). 1 , 4 and 5 we...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014, Vol.50 (10), p.1189-1191 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | L
2
Zn
2
(L = HC[C(Me)N(2,4,6-Me
3
C
6
H
2
)]
2
) and Ph
2
E
2
(E = Se, Te) react to form LZnSePh (
1
) and LZnTePh (
2
).
1
and
2
further react with H
2
O and EtOH to form LZnOH (
3
) and LZnOEt (
4
), respectively, whereas the reaction of
2
with oxygen yielded [LZnOTe(O)Ph]
2
(
5
).
1
,
4
and
5
were characterized by single crystal X-ray diffraction. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/C3CC48677J |