Studies of the formation of all-carbon quaternary centres, en route to lyngbyatoxin A. A comparison of phenyl and 7-substituted indole systems

Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction conditions have been fo...

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Veröffentlicht in:	Organic & biomolecular chemistry 2004-05, Vol.2 (10), p.1447-1455
Hauptverfasser:	Tønder, Janne E, Hosseini, Masood, Ahrenst, Alex B, Tanner, David
Format:	Artikel
Sprache:	eng
Schlagworte:	Cinnamates - chemistry Copper - chemistry Cyclization Heterocyclic Compounds, 3-Ring - chemical synthesis Heterocyclic Compounds, 3-Ring - chemistry Indoles - chemistry Lactams - chemistry Lithium Chloride - chemistry Lyngbya Toxins - chemical synthesis Magnetic Resonance Spectroscopy Molecular Conformation Molecular Structure Molybdenum - chemistry Organometallic Compounds - chemistry Palladium - chemistry Solvents - chemistry Temperature Terpenes - chemistry
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