Non-enzymatic Formation of Nitrogen Gas

SINCE comprehensive treatment of the biochemical reduction of nitrate of Gayon and Dupetit 1 it has been generally assumed in denitrification studies that nitric oxide, and particularly nitrogen gas, evolved either from cell preparations or soil systems under moderate conditions of acidity ( p H 5.0...

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Veröffentlicht in:Nature (London) 1966-06, Vol.210 (5041), p.1150-1151
Hauptverfasser: WULLSTEIN, L. H, GILMOUR, C. M
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description SINCE comprehensive treatment of the biochemical reduction of nitrate of Gayon and Dupetit 1 it has been generally assumed in denitrification studies that nitric oxide, and particularly nitrogen gas, evolved either from cell preparations or soil systems under moderate conditions of acidity ( p H 5.0–7.0) and temperature (28°-30° C), are dissimilatory products of ‘nitrate or nitrite respiration’ 2–4 . Recent evidence has shown, however, that nitric oxide can also be formed from nitrite in sterile, moderately acid systems when certain transition-like metals are present 5 . Subsequent experiments to be presented in this communication further indicate that nitrogen gas can be formed as a result of reacting potassium nitrite and ferrous sulphate.
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multidisciplinary
Science
Science (multidisciplinary)
title Non-enzymatic Formation of Nitrogen Gas
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