Complex Formation between Lead(II) Ions and Acetate Ions
THE complex formation between lead (II) and acetato ions has been examined at 25° C with 3 M (Na)ClO 4 as the ionic medium. The equilibrium constants were determined by potentiometric titrations at which the free lead concentration, [Pb 2+ ], was measured with a lead amalgam electrode and a ‘Wilhelm...
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| Veröffentlicht in: | Nature (London) 1963-01, Vol.197 (4864), p.283-284 |
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| container_issue | 4864 |
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| container_title | Nature (London) |
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| creator | GOBOM, SYLVIA |
| description | THE complex formation between lead (II) and acetato ions has been examined at 25° C with 3 M (Na)ClO
4
as the ionic medium. The equilibrium constants were determined by potentiometric titrations at which the free lead concentration, [Pb
2+
], was measured with a lead amalgam electrode and a ‘Wilhelm’ reference bridge of the type:
In each series the analytical lead concentration,
C
Pb
2+
was kept constant while the ligand concentration was varied. In order to avoid hydrolysis of the lead ions a suitable amount of perchloric acid was added to the lead perchlorate solutions. |
| doi_str_mv | 10.1038/197283b0 |
| format | Article |
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4
as the ionic medium. The equilibrium constants were determined by potentiometric titrations at which the free lead concentration, [Pb
2+
], was measured with a lead amalgam electrode and a ‘Wilhelm’ reference bridge of the type:
In each series the analytical lead concentration,
C
Pb
2+
was kept constant while the ligand concentration was varied. In order to avoid hydrolysis of the lead ions a suitable amount of perchloric acid was added to the lead perchlorate solutions.</description><identifier>ISSN: 0028-0836</identifier><identifier>EISSN: 1476-4687</identifier><identifier>DOI: 10.1038/197283b0</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>Humanities and Social Sciences ; letter ; multidisciplinary ; Science ; Science (multidisciplinary)</subject><ispartof>Nature (London), 1963-01, Vol.197 (4864), p.283-284</ispartof><rights>Springer Nature Limited 1963</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1990-97942868c2bc7d0cfe54c71107478753980fe10fe649bd017d3175459313ab6c3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1038/197283b0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1038/197283b0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,2727,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>GOBOM, SYLVIA</creatorcontrib><title>Complex Formation between Lead(II) Ions and Acetate Ions</title><title>Nature (London)</title><addtitle>Nature</addtitle><description>THE complex formation between lead (II) and acetato ions has been examined at 25° C with 3 M (Na)ClO
4
as the ionic medium. The equilibrium constants were determined by potentiometric titrations at which the free lead concentration, [Pb
2+
], was measured with a lead amalgam electrode and a ‘Wilhelm’ reference bridge of the type:
In each series the analytical lead concentration,
C
Pb
2+
was kept constant while the ligand concentration was varied. In order to avoid hydrolysis of the lead ions a suitable amount of perchloric acid was added to the lead perchlorate solutions.</description><subject>Humanities and Social Sciences</subject><subject>letter</subject><subject>multidisciplinary</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><issn>0028-0836</issn><issn>1476-4687</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1963</creationdate><recordtype>article</recordtype><recordid>eNptz8FKw0AQBuBFFKxV8Akkx_YQnclusrvHEqwGAl70HDabibQ0m7Kbor69sbF48TAMDB8_8zN2i3CPwNUDapkoXsMZm6GQWSwyJc_ZDCBRMSieXbKrELYAkKIUM6byvtvv6DNa974zw6Z3UU3DB5GLSjLNoiiWUdG7EBnXRCtLgxnoeLhmF63ZBbr53XP2tn58zZ_j8uWpyFdlbFFriLXUIlGZskltZQO2pVRYiQhSSCVTrhW0hONkQtcNoGw4ylSkmiM3dWb5nC2mXOv7EDy11d5vOuO_KoTqp3F1ajzS5UTDSNw7-WrbH7wbv_vP3k3WmeHg6S_0BL4BIINclw</recordid><startdate>19630119</startdate><enddate>19630119</enddate><creator>GOBOM, SYLVIA</creator><general>Nature Publishing Group UK</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19630119</creationdate><title>Complex Formation between Lead(II) Ions and Acetate Ions</title><author>GOBOM, SYLVIA</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1990-97942868c2bc7d0cfe54c71107478753980fe10fe649bd017d3175459313ab6c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1963</creationdate><topic>Humanities and Social Sciences</topic><topic>letter</topic><topic>multidisciplinary</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>GOBOM, SYLVIA</creatorcontrib><collection>CrossRef</collection><jtitle>Nature (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>GOBOM, SYLVIA</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Complex Formation between Lead(II) Ions and Acetate Ions</atitle><jtitle>Nature (London)</jtitle><stitle>Nature</stitle><date>1963-01-19</date><risdate>1963</risdate><volume>197</volume><issue>4864</issue><spage>283</spage><epage>284</epage><pages>283-284</pages><issn>0028-0836</issn><eissn>1476-4687</eissn><abstract>THE complex formation between lead (II) and acetato ions has been examined at 25° C with 3 M (Na)ClO
4
as the ionic medium. The equilibrium constants were determined by potentiometric titrations at which the free lead concentration, [Pb
2+
], was measured with a lead amalgam electrode and a ‘Wilhelm’ reference bridge of the type:
In each series the analytical lead concentration,
C
Pb
2+
was kept constant while the ligand concentration was varied. In order to avoid hydrolysis of the lead ions a suitable amount of perchloric acid was added to the lead perchlorate solutions.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/197283b0</doi><tpages>2</tpages></addata></record> |
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| ispartof | Nature (London), 1963-01, Vol.197 (4864), p.283-284 |
| issn | 0028-0836 1476-4687 |
| language | eng |
| recordid | cdi_crossref_primary_10_1038_197283b0 |
| source | Nature; SpringerLink Journals - AutoHoldings |
| subjects | Humanities and Social Sciences letter multidisciplinary Science Science (multidisciplinary) |
| title | Complex Formation between Lead(II) Ions and Acetate Ions |
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