Anion Affinity and Polarizing Power of Cations

IT is suggested that the ionization potential, I (first for univalent cations, second for divalent cations, third for trivalent cations, and so on), be used as a relative measure of the power of a cation to attract an anion (its ‘anion affinity’), and of its polarizing power. Its use thus may be dem...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Nature (London) 1952-03, Vol.169 (4298), p.463-463
1. Verfasser:	AHRENS, L. H
Format:	Artikel
Sprache:	eng
Schlagworte:	Humanities and Social Sciences letter multidisciplinary Science Science (multidisciplinary)
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	463
container_issue	4298
container_start_page	463
container_title	Nature (London)
container_volume	169
creator	AHRENS, L. H
description	IT is suggested that the ionization potential, I (first for univalent cations, second for divalent cations, third for trivalent cations, and so on), be used as a relative measure of the power of a cation to attract an anion (its ‘anion affinity’), and of its polarizing power. Its use thus may be demonstrated by some of the comparisons below. The general concept used here of the ability of cations to polarize and deform anions follows that discussed in the writings of Fajans 1,2 and of others, and the homopolar bonds referred to below are regarded as strongly polarized ionic bonds.
doi_str_mv	10.1038/169463a0
format	Article
fullrecord	<record><control><sourceid>nature_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1038_169463a0</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>169463a0</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-3f3a716875cf49530acf7e8f1fbaab953748a0b9825d6efa255a606ccde084453</originalsourceid><addsrcrecordid>eNptz01LxDAQBuAgCtZV8BdIj3roOmk-eyzFL1jQg57LNE2WLmsqSRdZf72RunjxNMPwMDMvIZcUlhSYvqWy4pIhHJGMciULLrU6JhlAqQvQTJ6Ssxg3ACCo4hlZ1n4YfV47N_hh2ufo-_xl3GIYvga_Tu2nDfno8gan5OI5OXG4jfbity7I2_3da_NYrJ4fnpp6VRhG9VQwx1DRdFkYxyvBAI1TVjvqOsQuDRTXCF2lS9FL67AUAiVIY3oLmnPBFuR63mvCGGOwrv0IwzuGfUuh_cnZHnImejPTmIhf29Buxl3w6bv_7NVsPU67YP-WHsA3crlbOA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Anion Affinity and Polarizing Power of Cations</title><source>Nature</source><source>SpringerLink Journals - AutoHoldings</source><creator>AHRENS, L. H</creator><creatorcontrib>AHRENS, L. H</creatorcontrib><description>IT is suggested that the ionization potential, I (first for univalent cations, second for divalent cations, third for trivalent cations, and so on), be used as a relative measure of the power of a cation to attract an anion (its ‘anion affinity’), and of its polarizing power. Its use thus may be demonstrated by some of the comparisons below. The general concept used here of the ability of cations to polarize and deform anions follows that discussed in the writings of Fajans 1,2 and of others, and the homopolar bonds referred to below are regarded as strongly polarized ionic bonds.</description><identifier>ISSN: 0028-0836</identifier><identifier>EISSN: 1476-4687</identifier><identifier>DOI: 10.1038/169463a0</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>Humanities and Social Sciences ; letter ; multidisciplinary ; Science ; Science (multidisciplinary)</subject><ispartof>Nature (London), 1952-03, Vol.169 (4298), p.463-463</ispartof><rights>Springer Nature Limited 1952</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-3f3a716875cf49530acf7e8f1fbaab953748a0b9825d6efa255a606ccde084453</citedby><cites>FETCH-LOGICAL-c318t-3f3a716875cf49530acf7e8f1fbaab953748a0b9825d6efa255a606ccde084453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1038/169463a0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1038/169463a0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,2725,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>AHRENS, L. H</creatorcontrib><title>Anion Affinity and Polarizing Power of Cations</title><title>Nature (London)</title><addtitle>Nature</addtitle><description>IT is suggested that the ionization potential, I (first for univalent cations, second for divalent cations, third for trivalent cations, and so on), be used as a relative measure of the power of a cation to attract an anion (its ‘anion affinity’), and of its polarizing power. Its use thus may be demonstrated by some of the comparisons below. The general concept used here of the ability of cations to polarize and deform anions follows that discussed in the writings of Fajans 1,2 and of others, and the homopolar bonds referred to below are regarded as strongly polarized ionic bonds.</description><subject>Humanities and Social Sciences</subject><subject>letter</subject><subject>multidisciplinary</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><issn>0028-0836</issn><issn>1476-4687</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1952</creationdate><recordtype>article</recordtype><recordid>eNptz01LxDAQBuAgCtZV8BdIj3roOmk-eyzFL1jQg57LNE2WLmsqSRdZf72RunjxNMPwMDMvIZcUlhSYvqWy4pIhHJGMciULLrU6JhlAqQvQTJ6Ssxg3ACCo4hlZ1n4YfV47N_hh2ufo-_xl3GIYvga_Tu2nDfno8gan5OI5OXG4jfbity7I2_3da_NYrJ4fnpp6VRhG9VQwx1DRdFkYxyvBAI1TVjvqOsQuDRTXCF2lS9FL67AUAiVIY3oLmnPBFuR63mvCGGOwrv0IwzuGfUuh_cnZHnImejPTmIhf29Buxl3w6bv_7NVsPU67YP-WHsA3crlbOA</recordid><startdate>19520315</startdate><enddate>19520315</enddate><creator>AHRENS, L. H</creator><general>Nature Publishing Group UK</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19520315</creationdate><title>Anion Affinity and Polarizing Power of Cations</title><author>AHRENS, L. H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-3f3a716875cf49530acf7e8f1fbaab953748a0b9825d6efa255a606ccde084453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1952</creationdate><topic>Humanities and Social Sciences</topic><topic>letter</topic><topic>multidisciplinary</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>AHRENS, L. H</creatorcontrib><collection>CrossRef</collection><jtitle>Nature (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>AHRENS, L. H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anion Affinity and Polarizing Power of Cations</atitle><jtitle>Nature (London)</jtitle><stitle>Nature</stitle><date>1952-03-15</date><risdate>1952</risdate><volume>169</volume><issue>4298</issue><spage>463</spage><epage>463</epage><pages>463-463</pages><issn>0028-0836</issn><eissn>1476-4687</eissn><abstract>IT is suggested that the ionization potential, I (first for univalent cations, second for divalent cations, third for trivalent cations, and so on), be used as a relative measure of the power of a cation to attract an anion (its ‘anion affinity’), and of its polarizing power. Its use thus may be demonstrated by some of the comparisons below. The general concept used here of the ability of cations to polarize and deform anions follows that discussed in the writings of Fajans 1,2 and of others, and the homopolar bonds referred to below are regarded as strongly polarized ionic bonds.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/169463a0</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record>
fulltext	fulltext
identifier	ISSN: 0028-0836
ispartof	Nature (London), 1952-03, Vol.169 (4298), p.463-463
issn	0028-0836 1476-4687
language	eng
recordid	cdi_crossref_primary_10_1038_169463a0
source	Nature; SpringerLink Journals - AutoHoldings
subjects	Humanities and Social Sciences letter multidisciplinary Science Science (multidisciplinary)
title	Anion Affinity and Polarizing Power of Cations
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-09T23%3A24%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-nature_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Anion%20Affinity%20and%20Polarizing%20Power%20of%20Cations&rft.jtitle=Nature%20(London)&rft.au=AHRENS,%20L.%20H&rft.date=1952-03-15&rft.volume=169&rft.issue=4298&rft.spage=463&rft.epage=463&rft.pages=463-463&rft.issn=0028-0836&rft.eissn=1476-4687&rft_id=info:doi/10.1038/169463a0&rft_dat=%3Cnature_cross%3E169463a0%3C/nature_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true