Sensitivity of Ozone Production to NO x and VOC Along the Lake Michigan Coastline
We report on the sensitivity of enhanced ozone (O 3 ) production, observed during lake breeze circulation along the coastline of Lake Michigan, to the concentrations of nitrogen oxides (NO x = NO + NO 2 ) and volatile organic compounds (VOCs). We assess the sensitivity of O 3 production to NO x and...
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| Veröffentlicht in: | Journal of geophysical research. Atmospheres 2019-10, Vol.124 (20), p.10989-11006 |
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| creator | Vermeuel, Michael P. Novak, Gordon A. Alwe, Hariprasad D. Hughes, Dagen D. Kaleel, Rob Dickens, Angela F. Kenski, Donna Czarnetzki, Alan C. Stone, Elizabeth A. Stanier, Charles O. Pierce, R. Bradley Millet, Dylan B. Bertram, Timothy H. |
| description | We report on the sensitivity of enhanced ozone (O
3
) production, observed during lake breeze circulation along the coastline of Lake Michigan, to the concentrations of nitrogen oxides (NO
x
= NO + NO
2
) and volatile organic compounds (VOCs). We assess the sensitivity of O
3
production to NO
x
and VOC on a high O
3
day during the Lake Michigan Ozone Study 2017 using an observationally constrained chemical box model that implements the Master Chemical Mechanism (MCM v3.3.1) and recent emission inventories for NO
x
and VOCs. The Master Chemical Mechanism model is coupled to a backward air mass trajectory analysis from a ground supersite in Zion, IL, where an extensive series of measurements of O
3
precursors and their oxidation products, including hydrogen peroxide (H
2
O
2
), nitric acid (HNO
3
), and particulate nitrates (NO
3
−
) serve as model constraints. We evaluate the chemical evolution of the Chicago‐Gary urban plume as it advects over Lake Michigan and demonstrate how modeled indicators of VOC‐ versus NO
x
‐sensitive regimes can be constrained by measurements at the trajectory endpoint. Using the modeled ratio of the instantaneous H
2
O
2
and HNO
3
production rates (
P
H2O2
/
P
HNO3
), we suggest that O
3
production over the urban source region is strongly VOC sensitive and progresses towards a more NO
x
‐sensitive regime as the plume advects north along the Lake Michigan coastline on this day. We also demonstrate that ground‐based measurements of the mean concentration ratio of H
2
O
2
to HNO
3
describe the sensitivity of O
3
production to VOC and NO
x
as the integral of chemical production along the plume path.
Direct observations of H
2
O
2
/HNO
3
at an urban plume endpoint can be used to assess the integrated O
3
sensitivity to NO
x
and VOC emissions
Indicators of O
3
sensitivity show that the urban plume traveling over Lake Michigan evolves from VOC towards NO
x
‐sensitive O
3
production
O
3
, H
2
O
2
, HNO
3
, and NO
3
−
provide unique constraints to predict the response of O
3
to changes in VOC and NO
x
emissions in coastal regions |
| doi_str_mv | 10.1029/2019JD030842 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1029_2019JD030842</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1029_2019JD030842</sourcerecordid><originalsourceid>FETCH-LOGICAL-c802-bf7d432b431a1eb8e63365b2f673cd9799fcab7dc18de726cae522890371ff013</originalsourceid><addsrcrecordid>eNpNkMtKxDAYRoMoOIyz8wH-B7CaS9sky6HeGa3iIO5KmstMtCbSRHF8ehVFPJvvrL7FQWif4EOCqTyimMjLY8ywKOkWmlBSy0JIWW__OX_YRbOUHvEXArOyKifo9s6G5LN_83kD0UH7EYOFmzGaV519DJAjXLfwDioYuG8bmA8xrCCvLSzUk4Urr9d-pQI0UaU8-GD30I5TQ7Kz352i5enJsjkvFu3ZRTNfFFpgWvSOm5LRvmREEdsLWzNWVz11NWfaSC6l06rnRhNhLKe1VraiVEjMOHEOEzZFBz-3eowpjdZ1L6N_VuOmI7j7DtL9D8I-AZlOUb0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Sensitivity of Ozone Production to NO x and VOC Along the Lake Michigan Coastline</title><source>Wiley Free Content</source><source>Wiley Online Library All Journals</source><source>Alma/SFX Local Collection</source><creator>Vermeuel, Michael P. ; Novak, Gordon A. ; Alwe, Hariprasad D. ; Hughes, Dagen D. ; Kaleel, Rob ; Dickens, Angela F. ; Kenski, Donna ; Czarnetzki, Alan C. ; Stone, Elizabeth A. ; Stanier, Charles O. ; Pierce, R. Bradley ; Millet, Dylan B. ; Bertram, Timothy H.</creator><creatorcontrib>Vermeuel, Michael P. ; Novak, Gordon A. ; Alwe, Hariprasad D. ; Hughes, Dagen D. ; Kaleel, Rob ; Dickens, Angela F. ; Kenski, Donna ; Czarnetzki, Alan C. ; Stone, Elizabeth A. ; Stanier, Charles O. ; Pierce, R. Bradley ; Millet, Dylan B. ; Bertram, Timothy H.</creatorcontrib><description>We report on the sensitivity of enhanced ozone (O
3
) production, observed during lake breeze circulation along the coastline of Lake Michigan, to the concentrations of nitrogen oxides (NO
x
= NO + NO
2
) and volatile organic compounds (VOCs). We assess the sensitivity of O
3
production to NO
x
and VOC on a high O
3
day during the Lake Michigan Ozone Study 2017 using an observationally constrained chemical box model that implements the Master Chemical Mechanism (MCM v3.3.1) and recent emission inventories for NO
x
and VOCs. The Master Chemical Mechanism model is coupled to a backward air mass trajectory analysis from a ground supersite in Zion, IL, where an extensive series of measurements of O
3
precursors and their oxidation products, including hydrogen peroxide (H
2
O
2
), nitric acid (HNO
3
), and particulate nitrates (NO
3
−
) serve as model constraints. We evaluate the chemical evolution of the Chicago‐Gary urban plume as it advects over Lake Michigan and demonstrate how modeled indicators of VOC‐ versus NO
x
‐sensitive regimes can be constrained by measurements at the trajectory endpoint. Using the modeled ratio of the instantaneous H
2
O
2
and HNO
3
production rates (
P
H2O2
/
P
HNO3
), we suggest that O
3
production over the urban source region is strongly VOC sensitive and progresses towards a more NO
x
‐sensitive regime as the plume advects north along the Lake Michigan coastline on this day. We also demonstrate that ground‐based measurements of the mean concentration ratio of H
2
O
2
to HNO
3
describe the sensitivity of O
3
production to VOC and NO
x
as the integral of chemical production along the plume path.
Direct observations of H
2
O
2
/HNO
3
at an urban plume endpoint can be used to assess the integrated O
3
sensitivity to NO
x
and VOC emissions
Indicators of O
3
sensitivity show that the urban plume traveling over Lake Michigan evolves from VOC towards NO
x
‐sensitive O
3
production
O
3
, H
2
O
2
, HNO
3
, and NO
3
−
provide unique constraints to predict the response of O
3
to changes in VOC and NO
x
emissions in coastal regions</description><identifier>ISSN: 2169-897X</identifier><identifier>EISSN: 2169-8996</identifier><identifier>DOI: 10.1029/2019JD030842</identifier><language>eng</language><ispartof>Journal of geophysical research. Atmospheres, 2019-10, Vol.124 (20), p.10989-11006</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c802-bf7d432b431a1eb8e63365b2f673cd9799fcab7dc18de726cae522890371ff013</citedby><cites>FETCH-LOGICAL-c802-bf7d432b431a1eb8e63365b2f673cd9799fcab7dc18de726cae522890371ff013</cites><orcidid>0000-0002-2767-1643 ; 0000-0002-3026-7588 ; 0000-0001-9924-0853 ; 0000-0003-3076-125X ; 0000-0003-2347-9168 ; 0000-0003-3851-4106 ; 0000-0001-8751-0027 ; 0000-0003-4009-039X ; 0000-0001-8433-5913 ; 0000-0003-0078-141X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Vermeuel, Michael P.</creatorcontrib><creatorcontrib>Novak, Gordon A.</creatorcontrib><creatorcontrib>Alwe, Hariprasad D.</creatorcontrib><creatorcontrib>Hughes, Dagen D.</creatorcontrib><creatorcontrib>Kaleel, Rob</creatorcontrib><creatorcontrib>Dickens, Angela F.</creatorcontrib><creatorcontrib>Kenski, Donna</creatorcontrib><creatorcontrib>Czarnetzki, Alan C.</creatorcontrib><creatorcontrib>Stone, Elizabeth A.</creatorcontrib><creatorcontrib>Stanier, Charles O.</creatorcontrib><creatorcontrib>Pierce, R. Bradley</creatorcontrib><creatorcontrib>Millet, Dylan B.</creatorcontrib><creatorcontrib>Bertram, Timothy H.</creatorcontrib><title>Sensitivity of Ozone Production to NO x and VOC Along the Lake Michigan Coastline</title><title>Journal of geophysical research. Atmospheres</title><description>We report on the sensitivity of enhanced ozone (O
3
) production, observed during lake breeze circulation along the coastline of Lake Michigan, to the concentrations of nitrogen oxides (NO
x
= NO + NO
2
) and volatile organic compounds (VOCs). We assess the sensitivity of O
3
production to NO
x
and VOC on a high O
3
day during the Lake Michigan Ozone Study 2017 using an observationally constrained chemical box model that implements the Master Chemical Mechanism (MCM v3.3.1) and recent emission inventories for NO
x
and VOCs. The Master Chemical Mechanism model is coupled to a backward air mass trajectory analysis from a ground supersite in Zion, IL, where an extensive series of measurements of O
3
precursors and their oxidation products, including hydrogen peroxide (H
2
O
2
), nitric acid (HNO
3
), and particulate nitrates (NO
3
−
) serve as model constraints. We evaluate the chemical evolution of the Chicago‐Gary urban plume as it advects over Lake Michigan and demonstrate how modeled indicators of VOC‐ versus NO
x
‐sensitive regimes can be constrained by measurements at the trajectory endpoint. Using the modeled ratio of the instantaneous H
2
O
2
and HNO
3
production rates (
P
H2O2
/
P
HNO3
), we suggest that O
3
production over the urban source region is strongly VOC sensitive and progresses towards a more NO
x
‐sensitive regime as the plume advects north along the Lake Michigan coastline on this day. We also demonstrate that ground‐based measurements of the mean concentration ratio of H
2
O
2
to HNO
3
describe the sensitivity of O
3
production to VOC and NO
x
as the integral of chemical production along the plume path.
Direct observations of H
2
O
2
/HNO
3
at an urban plume endpoint can be used to assess the integrated O
3
sensitivity to NO
x
and VOC emissions
Indicators of O
3
sensitivity show that the urban plume traveling over Lake Michigan evolves from VOC towards NO
x
‐sensitive O
3
production
O
3
, H
2
O
2
, HNO
3
, and NO
3
−
provide unique constraints to predict the response of O
3
to changes in VOC and NO
x
emissions in coastal regions</description><issn>2169-897X</issn><issn>2169-8996</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpNkMtKxDAYRoMoOIyz8wH-B7CaS9sky6HeGa3iIO5KmstMtCbSRHF8ehVFPJvvrL7FQWif4EOCqTyimMjLY8ywKOkWmlBSy0JIWW__OX_YRbOUHvEXArOyKifo9s6G5LN_83kD0UH7EYOFmzGaV519DJAjXLfwDioYuG8bmA8xrCCvLSzUk4Urr9d-pQI0UaU8-GD30I5TQ7Kz352i5enJsjkvFu3ZRTNfFFpgWvSOm5LRvmREEdsLWzNWVz11NWfaSC6l06rnRhNhLKe1VraiVEjMOHEOEzZFBz-3eowpjdZ1L6N_VuOmI7j7DtL9D8I-AZlOUb0</recordid><startdate>20191027</startdate><enddate>20191027</enddate><creator>Vermeuel, Michael P.</creator><creator>Novak, Gordon A.</creator><creator>Alwe, Hariprasad D.</creator><creator>Hughes, Dagen D.</creator><creator>Kaleel, Rob</creator><creator>Dickens, Angela F.</creator><creator>Kenski, Donna</creator><creator>Czarnetzki, Alan C.</creator><creator>Stone, Elizabeth A.</creator><creator>Stanier, Charles O.</creator><creator>Pierce, R. Bradley</creator><creator>Millet, Dylan B.</creator><creator>Bertram, Timothy H.</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-2767-1643</orcidid><orcidid>https://orcid.org/0000-0002-3026-7588</orcidid><orcidid>https://orcid.org/0000-0001-9924-0853</orcidid><orcidid>https://orcid.org/0000-0003-3076-125X</orcidid><orcidid>https://orcid.org/0000-0003-2347-9168</orcidid><orcidid>https://orcid.org/0000-0003-3851-4106</orcidid><orcidid>https://orcid.org/0000-0001-8751-0027</orcidid><orcidid>https://orcid.org/0000-0003-4009-039X</orcidid><orcidid>https://orcid.org/0000-0001-8433-5913</orcidid><orcidid>https://orcid.org/0000-0003-0078-141X</orcidid></search><sort><creationdate>20191027</creationdate><title>Sensitivity of Ozone Production to NO x and VOC Along the Lake Michigan Coastline</title><author>Vermeuel, Michael P. ; Novak, Gordon A. ; Alwe, Hariprasad D. ; Hughes, Dagen D. ; Kaleel, Rob ; Dickens, Angela F. ; Kenski, Donna ; Czarnetzki, Alan C. ; Stone, Elizabeth A. ; Stanier, Charles O. ; Pierce, R. Bradley ; Millet, Dylan B. ; Bertram, Timothy H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c802-bf7d432b431a1eb8e63365b2f673cd9799fcab7dc18de726cae522890371ff013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vermeuel, Michael P.</creatorcontrib><creatorcontrib>Novak, Gordon A.</creatorcontrib><creatorcontrib>Alwe, Hariprasad D.</creatorcontrib><creatorcontrib>Hughes, Dagen D.</creatorcontrib><creatorcontrib>Kaleel, Rob</creatorcontrib><creatorcontrib>Dickens, Angela F.</creatorcontrib><creatorcontrib>Kenski, Donna</creatorcontrib><creatorcontrib>Czarnetzki, Alan C.</creatorcontrib><creatorcontrib>Stone, Elizabeth A.</creatorcontrib><creatorcontrib>Stanier, Charles O.</creatorcontrib><creatorcontrib>Pierce, R. Bradley</creatorcontrib><creatorcontrib>Millet, Dylan B.</creatorcontrib><creatorcontrib>Bertram, Timothy H.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of geophysical research. Atmospheres</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vermeuel, Michael P.</au><au>Novak, Gordon A.</au><au>Alwe, Hariprasad D.</au><au>Hughes, Dagen D.</au><au>Kaleel, Rob</au><au>Dickens, Angela F.</au><au>Kenski, Donna</au><au>Czarnetzki, Alan C.</au><au>Stone, Elizabeth A.</au><au>Stanier, Charles O.</au><au>Pierce, R. Bradley</au><au>Millet, Dylan B.</au><au>Bertram, Timothy H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sensitivity of Ozone Production to NO x and VOC Along the Lake Michigan Coastline</atitle><jtitle>Journal of geophysical research. Atmospheres</jtitle><date>2019-10-27</date><risdate>2019</risdate><volume>124</volume><issue>20</issue><spage>10989</spage><epage>11006</epage><pages>10989-11006</pages><issn>2169-897X</issn><eissn>2169-8996</eissn><abstract>We report on the sensitivity of enhanced ozone (O
3
) production, observed during lake breeze circulation along the coastline of Lake Michigan, to the concentrations of nitrogen oxides (NO
x
= NO + NO
2
) and volatile organic compounds (VOCs). We assess the sensitivity of O
3
production to NO
x
and VOC on a high O
3
day during the Lake Michigan Ozone Study 2017 using an observationally constrained chemical box model that implements the Master Chemical Mechanism (MCM v3.3.1) and recent emission inventories for NO
x
and VOCs. The Master Chemical Mechanism model is coupled to a backward air mass trajectory analysis from a ground supersite in Zion, IL, where an extensive series of measurements of O
3
precursors and their oxidation products, including hydrogen peroxide (H
2
O
2
), nitric acid (HNO
3
), and particulate nitrates (NO
3
−
) serve as model constraints. We evaluate the chemical evolution of the Chicago‐Gary urban plume as it advects over Lake Michigan and demonstrate how modeled indicators of VOC‐ versus NO
x
‐sensitive regimes can be constrained by measurements at the trajectory endpoint. Using the modeled ratio of the instantaneous H
2
O
2
and HNO
3
production rates (
P
H2O2
/
P
HNO3
), we suggest that O
3
production over the urban source region is strongly VOC sensitive and progresses towards a more NO
x
‐sensitive regime as the plume advects north along the Lake Michigan coastline on this day. We also demonstrate that ground‐based measurements of the mean concentration ratio of H
2
O
2
to HNO
3
describe the sensitivity of O
3
production to VOC and NO
x
as the integral of chemical production along the plume path.
Direct observations of H
2
O
2
/HNO
3
at an urban plume endpoint can be used to assess the integrated O
3
sensitivity to NO
x
and VOC emissions
Indicators of O
3
sensitivity show that the urban plume traveling over Lake Michigan evolves from VOC towards NO
x
‐sensitive O
3
production
O
3
, H
2
O
2
, HNO
3
, and NO
3
−
provide unique constraints to predict the response of O
3
to changes in VOC and NO
x
emissions in coastal regions</abstract><doi>10.1029/2019JD030842</doi><tpages>18</tpages><orcidid>https://orcid.org/0000-0002-2767-1643</orcidid><orcidid>https://orcid.org/0000-0002-3026-7588</orcidid><orcidid>https://orcid.org/0000-0001-9924-0853</orcidid><orcidid>https://orcid.org/0000-0003-3076-125X</orcidid><orcidid>https://orcid.org/0000-0003-2347-9168</orcidid><orcidid>https://orcid.org/0000-0003-3851-4106</orcidid><orcidid>https://orcid.org/0000-0001-8751-0027</orcidid><orcidid>https://orcid.org/0000-0003-4009-039X</orcidid><orcidid>https://orcid.org/0000-0001-8433-5913</orcidid><orcidid>https://orcid.org/0000-0003-0078-141X</orcidid></addata></record> |
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| identifier | ISSN: 2169-897X |
| ispartof | Journal of geophysical research. Atmospheres, 2019-10, Vol.124 (20), p.10989-11006 |
| issn | 2169-897X 2169-8996 |
| language | eng |
| recordid | cdi_crossref_primary_10_1029_2019JD030842 |
| source | Wiley Free Content; Wiley Online Library All Journals; Alma/SFX Local Collection |
| title | Sensitivity of Ozone Production to NO x and VOC Along the Lake Michigan Coastline |
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