Halide Effects in the Hydrolysis Reactions of (±)-7β,8α-Dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo- [a]pyrene

Rates of reaction of (±)-7β,8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (DE-2) have been determined in 1:9 dioxane−water solutions containing 1.0 M KCl, 0.5 M KBr, and 0.1 M NaI over the pH range 4−13. These pH−rate profiles are more complicated than those for reaction of DE-2 in 0.2...

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Veröffentlicht in:	Chemical research in toxicology 1998-06, Vol.11 (6), p.630-638
Hauptverfasser:	Lin, Bin, Doan, Lanxuan, Yagi, Haruhiko, Jerina, Donald M, Whalen, Dale L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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