Morphology and Thermal Properties of Renewable Resource-Based Polymer Blend Nanocomposites Influenced by a Reactive Compatibilizer
Partially miscible blends of poly(lactic acid) (PLA) and poly(hydroxybutyrate) (PHB) have been prepared by the melt mixing method. An interpenetrating network structure created by a maleic anhydride (MA) compatibilizer imparted additional interactions between the two matrices, which has resulted in...
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Veröffentlicht in: | ACS sustainable chemistry & engineering 2014-03, Vol.2 (3), p.377-386 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Partially miscible blends of poly(lactic acid) (PLA) and poly(hydroxybutyrate) (PHB) have been prepared by the melt mixing method. An interpenetrating network structure created by a maleic anhydride (MA) compatibilizer imparted additional interactions between the two matrices, which has resulted in increased miscibility within the blends. A modified interface has been characterized using morphological analysis through FT-IR and SEM analysis. Because MA compatibilization distributed flexible intermolecular hydrogen bonding within the blend matrix, elongation at break and Izod impact strength has been reported at a maximum of 540.17% and 99%, respectively, compared to those of the PLA matrix. Further, incorporation of layered silicates within the optimized composition of the PLA/PHB/MA blend modified the tensile strength by 49%, without compromising its superior flexible characteristics. Simultaneously, the renowned thermal insulating property of exfoliated/intercalated layered silicate works well to promote the thermal stability of the blend as well. Because two different nanoclays have been utilized in the present investigation, a comparative account of the extent of the intercalation/exfoliation has been reported through morphological analysis. |
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ISSN: | 2168-0485 2168-0485 |
DOI: | 10.1021/sc400395s |