Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions

Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions

The phase-selective solubility properties of polymer supports that could be used in thermomorphic and latent biphasic systems useful in synthesis and catalysis were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol−water, heptane/ethyl a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic process research & development 2004-05, Vol.8 (3), p.461-468
Hauptverfasser: Bergbreiter, David E., Sung, Shayna D., Li, Jun, Ortiz, Denisse, Hamilton, Patrick N.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 468
container_issue 3
container_start_page 461
container_title Organic process research & development
container_volume 8
creator Bergbreiter, David E.
Sung, Shayna D.
Li, Jun
Ortiz, Denisse
Hamilton, Patrick N.
description The phase-selective solubility properties of polymer supports that could be used in thermomorphic and latent biphasic systems useful in synthesis and catalysis were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol−water, heptane/ethyl acetate, heptane/ethanol, and heptane/tert-butyl alcohol solvent mixtures were all studied as examples of thermomorphic or latent biphasic systems. A range of polymers including polyisobutylene (PIB), poly(tert-butylstyrene) (PTBS), poly(octadecyl acrylate) (PODA), and poly(octadecyl methacrylate) (PODMA) were tested for hydrophobic phase-selective solubility. The results of these studies are compared to prior work with polar and nonpolar poly(N-alkylacrylamide)s and polystyrene. Together with this prior work, these results show that a wide range of polymers and solvent mixtures can be used for the recycling of soluble polymer-bound catalysts, reagents, and sequestrants using either thermomorphic or latent biphasic separation strategies.
doi_str_mv 10.1021/op034183w
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_op034183w</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>h45168294</sourcerecordid><originalsourceid>FETCH-LOGICAL-a323t-7f7c25b2258be2424267663ad90a33b872056d712efab729c29e3b810fc6743d3</originalsourceid><addsrcrecordid>eNptkEFLxDAQhYMouK4e_Ae5ePBQd5K0SXvUdXWFgqIueCtpmtQs26YmLbL_3mrFk8zhDW8-hsdD6JzAFQFKFq4DFpOUfR6gGUkoREnK3w7HHVIWccLhGJ2EsAWAhBM6Q5tbHWzd2rbGT263b7QP2DiPb2z3LoNVOLcfg60Wk-AX3Ukve-vagKXptcdr17hat9oNAT9rqX5up-jIyF3QZ786R5u71etyHeWP9w_L6zySjLI-EkYompSUJmmpaTwOF5wzWWUgGStTQceUlSBUG1kKmima6dEmYBQXMavYHF1Of5V3IXhtis7bRvp9QaD47qP462NkLyZWqlBs3eDbMdk_3BeO6l93</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions</title><source>ACS Publications</source><creator>Bergbreiter, David E. ; Sung, Shayna D. ; Li, Jun ; Ortiz, Denisse ; Hamilton, Patrick N.</creator><creatorcontrib>Bergbreiter, David E. ; Sung, Shayna D. ; Li, Jun ; Ortiz, Denisse ; Hamilton, Patrick N.</creatorcontrib><description>The phase-selective solubility properties of polymer supports that could be used in thermomorphic and latent biphasic systems useful in synthesis and catalysis were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol−water, heptane/ethyl acetate, heptane/ethanol, and heptane/tert-butyl alcohol solvent mixtures were all studied as examples of thermomorphic or latent biphasic systems. A range of polymers including polyisobutylene (PIB), poly(tert-butylstyrene) (PTBS), poly(octadecyl acrylate) (PODA), and poly(octadecyl methacrylate) (PODMA) were tested for hydrophobic phase-selective solubility. The results of these studies are compared to prior work with polar and nonpolar poly(N-alkylacrylamide)s and polystyrene. Together with this prior work, these results show that a wide range of polymers and solvent mixtures can be used for the recycling of soluble polymer-bound catalysts, reagents, and sequestrants using either thermomorphic or latent biphasic separation strategies.</description><identifier>ISSN: 1083-6160</identifier><identifier>EISSN: 1520-586X</identifier><identifier>DOI: 10.1021/op034183w</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organic process research &amp; development, 2004-05, Vol.8 (3), p.461-468</ispartof><rights>Copyright © 2004 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a323t-7f7c25b2258be2424267663ad90a33b872056d712efab729c29e3b810fc6743d3</citedby><cites>FETCH-LOGICAL-a323t-7f7c25b2258be2424267663ad90a33b872056d712efab729c29e3b810fc6743d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/op034183w$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/op034183w$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Bergbreiter, David E.</creatorcontrib><creatorcontrib>Sung, Shayna D.</creatorcontrib><creatorcontrib>Li, Jun</creatorcontrib><creatorcontrib>Ortiz, Denisse</creatorcontrib><creatorcontrib>Hamilton, Patrick N.</creatorcontrib><title>Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions</title><title>Organic process research &amp; development</title><addtitle>Org. Process Res. Dev</addtitle><description>The phase-selective solubility properties of polymer supports that could be used in thermomorphic and latent biphasic systems useful in synthesis and catalysis were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol−water, heptane/ethyl acetate, heptane/ethanol, and heptane/tert-butyl alcohol solvent mixtures were all studied as examples of thermomorphic or latent biphasic systems. A range of polymers including polyisobutylene (PIB), poly(tert-butylstyrene) (PTBS), poly(octadecyl acrylate) (PODA), and poly(octadecyl methacrylate) (PODMA) were tested for hydrophobic phase-selective solubility. The results of these studies are compared to prior work with polar and nonpolar poly(N-alkylacrylamide)s and polystyrene. Together with this prior work, these results show that a wide range of polymers and solvent mixtures can be used for the recycling of soluble polymer-bound catalysts, reagents, and sequestrants using either thermomorphic or latent biphasic separation strategies.</description><issn>1083-6160</issn><issn>1520-586X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNptkEFLxDAQhYMouK4e_Ae5ePBQd5K0SXvUdXWFgqIueCtpmtQs26YmLbL_3mrFk8zhDW8-hsdD6JzAFQFKFq4DFpOUfR6gGUkoREnK3w7HHVIWccLhGJ2EsAWAhBM6Q5tbHWzd2rbGT263b7QP2DiPb2z3LoNVOLcfg60Wk-AX3Ukve-vagKXptcdr17hat9oNAT9rqX5up-jIyF3QZ786R5u71etyHeWP9w_L6zySjLI-EkYompSUJmmpaTwOF5wzWWUgGStTQceUlSBUG1kKmima6dEmYBQXMavYHF1Of5V3IXhtis7bRvp9QaD47qP462NkLyZWqlBs3eDbMdk_3BeO6l93</recordid><startdate>20040501</startdate><enddate>20040501</enddate><creator>Bergbreiter, David E.</creator><creator>Sung, Shayna D.</creator><creator>Li, Jun</creator><creator>Ortiz, Denisse</creator><creator>Hamilton, Patrick N.</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20040501</creationdate><title>Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions</title><author>Bergbreiter, David E. ; Sung, Shayna D. ; Li, Jun ; Ortiz, Denisse ; Hamilton, Patrick N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a323t-7f7c25b2258be2424267663ad90a33b872056d712efab729c29e3b810fc6743d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bergbreiter, David E.</creatorcontrib><creatorcontrib>Sung, Shayna D.</creatorcontrib><creatorcontrib>Li, Jun</creatorcontrib><creatorcontrib>Ortiz, Denisse</creatorcontrib><creatorcontrib>Hamilton, Patrick N.</creatorcontrib><collection>CrossRef</collection><jtitle>Organic process research &amp; development</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bergbreiter, David E.</au><au>Sung, Shayna D.</au><au>Li, Jun</au><au>Ortiz, Denisse</au><au>Hamilton, Patrick N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions</atitle><jtitle>Organic process research &amp; development</jtitle><addtitle>Org. Process Res. Dev</addtitle><date>2004-05-01</date><risdate>2004</risdate><volume>8</volume><issue>3</issue><spage>461</spage><epage>468</epage><pages>461-468</pages><issn>1083-6160</issn><eissn>1520-586X</eissn><abstract>The phase-selective solubility properties of polymer supports that could be used in thermomorphic and latent biphasic systems useful in synthesis and catalysis were evaluated using polymers tagged with either visible dyes or fluorescent probes. Heptane/DMF, heptane/90% ethanol−water, heptane/ethyl acetate, heptane/ethanol, and heptane/tert-butyl alcohol solvent mixtures were all studied as examples of thermomorphic or latent biphasic systems. A range of polymers including polyisobutylene (PIB), poly(tert-butylstyrene) (PTBS), poly(octadecyl acrylate) (PODA), and poly(octadecyl methacrylate) (PODMA) were tested for hydrophobic phase-selective solubility. The results of these studies are compared to prior work with polar and nonpolar poly(N-alkylacrylamide)s and polystyrene. Together with this prior work, these results show that a wide range of polymers and solvent mixtures can be used for the recycling of soluble polymer-bound catalysts, reagents, and sequestrants using either thermomorphic or latent biphasic separation strategies.</abstract><pub>American Chemical Society</pub><doi>10.1021/op034183w</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1083-6160
ispartof Organic process research & development, 2004-05, Vol.8 (3), p.461-468
issn 1083-6160
1520-586X
language eng
recordid cdi_crossref_primary_10_1021_op034183w
source ACS Publications
title Designing Polymers for Biphasic Liquid/Liquid Separations after Homogeneous Reactions
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T21%3A45%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Designing%20Polymers%20for%20Biphasic%20Liquid/Liquid%20Separations%20after%20Homogeneous%20Reactions&rft.jtitle=Organic%20process%20research%20&%20development&rft.au=Bergbreiter,%20David%20E.&rft.date=2004-05-01&rft.volume=8&rft.issue=3&rft.spage=461&rft.epage=468&rft.pages=461-468&rft.issn=1083-6160&rft.eissn=1520-586X&rft_id=info:doi/10.1021/op034183w&rft_dat=%3Cacs_cross%3Eh45168294%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true