Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex

Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex

The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSbC(SiMe3)2-Pyr], results in the first s...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organometallics 1999-10, Vol.18 (21), p.4247-4249
Hauptverfasser: Andrews, Philip C, Nichols, Peter J, Raston, Colin L, Roberts, Brett A
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 4249
container_issue 21
container_start_page 4247
container_title Organometallics
container_volume 18
creator Andrews, Philip C
Nichols, Peter J
Raston, Colin L
Roberts, Brett A
description The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSbC(SiMe3)2-Pyr], results in the first structurally authenticated In(III)/Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the SbC double bond.
doi_str_mv 10.1021/om990542t
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_om990542t</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>f08184006</sourcerecordid><originalsourceid>FETCH-LOGICAL-a295t-9d0273defd8b0115fe55f63a03a27b31a9f47e19f93d68fc811eddf0bc4067cb3</originalsourceid><addsrcrecordid>eNptkDtPwzAYRS0EEqUw8A-8IMEQasd5NCOKoAQV-kSM1pfErtwmdmW7Uvn3hBZ1YrrL0dW9B6FbSh4pCenAtFlG4ij0Z6hH45AECYnoOeqRME2ClDF2ia6cWxNCkpSFPdTmYEvTCg8NeGU0NhIDXnhVQgDNRmiB58LtGq_0CiuNQeNC3xdF8TBYlIfEeZAL7YUVNR6JVmlo8MSuQJtaHXobVeHctNtG7K_RhYTGiZu_7KPPl-dl_hqMJ6MifxoHEGaxD7K6m8tqIethSSiNpYhjmTAgDMK0ZBQyGaWCZjJjdTKU1ZBSUdeSlFXU3apK1kcPx97KGueskHxrVQv2m1PCfz3xk6eODY6scl7sTyDYDe8UpTFfThd89vbOvubTDz7r-LsjD5Xja7Oz3WH3T-8PZpF2Qw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex</title><source>American Chemical Society Journals</source><creator>Andrews, Philip C ; Nichols, Peter J ; Raston, Colin L ; Roberts, Brett A</creator><creatorcontrib>Andrews, Philip C ; Nichols, Peter J ; Raston, Colin L ; Roberts, Brett A</creatorcontrib><description>The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSbC(SiMe3)2-Pyr], results in the first structurally authenticated In(III)/Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the SbC double bond.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om990542t</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 1999-10, Vol.18 (21), p.4247-4249</ispartof><rights>Copyright © 1999 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a295t-9d0273defd8b0115fe55f63a03a27b31a9f47e19f93d68fc811eddf0bc4067cb3</citedby><cites>FETCH-LOGICAL-a295t-9d0273defd8b0115fe55f63a03a27b31a9f47e19f93d68fc811eddf0bc4067cb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om990542t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om990542t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27081,27929,27930,56743,56793</link.rule.ids></links><search><creatorcontrib>Andrews, Philip C</creatorcontrib><creatorcontrib>Nichols, Peter J</creatorcontrib><creatorcontrib>Raston, Colin L</creatorcontrib><creatorcontrib>Roberts, Brett A</creatorcontrib><title>Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSbC(SiMe3)2-Pyr], results in the first structurally authenticated In(III)/Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the SbC double bond.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNptkDtPwzAYRS0EEqUw8A-8IMEQasd5NCOKoAQV-kSM1pfErtwmdmW7Uvn3hBZ1YrrL0dW9B6FbSh4pCenAtFlG4ij0Z6hH45AECYnoOeqRME2ClDF2ia6cWxNCkpSFPdTmYEvTCg8NeGU0NhIDXnhVQgDNRmiB58LtGq_0CiuNQeNC3xdF8TBYlIfEeZAL7YUVNR6JVmlo8MSuQJtaHXobVeHctNtG7K_RhYTGiZu_7KPPl-dl_hqMJ6MifxoHEGaxD7K6m8tqIethSSiNpYhjmTAgDMK0ZBQyGaWCZjJjdTKU1ZBSUdeSlFXU3apK1kcPx97KGueskHxrVQv2m1PCfz3xk6eODY6scl7sTyDYDe8UpTFfThd89vbOvubTDz7r-LsjD5Xja7Oz3WH3T-8PZpF2Qw</recordid><startdate>19991011</startdate><enddate>19991011</enddate><creator>Andrews, Philip C</creator><creator>Nichols, Peter J</creator><creator>Raston, Colin L</creator><creator>Roberts, Brett A</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19991011</creationdate><title>Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex</title><author>Andrews, Philip C ; Nichols, Peter J ; Raston, Colin L ; Roberts, Brett A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a295t-9d0273defd8b0115fe55f63a03a27b31a9f47e19f93d68fc811eddf0bc4067cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Andrews, Philip C</creatorcontrib><creatorcontrib>Nichols, Peter J</creatorcontrib><creatorcontrib>Raston, Colin L</creatorcontrib><creatorcontrib>Roberts, Brett A</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Andrews, Philip C</au><au>Nichols, Peter J</au><au>Raston, Colin L</au><au>Roberts, Brett A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1999-10-11</date><risdate>1999</risdate><volume>18</volume><issue>21</issue><spage>4247</spage><epage>4249</epage><pages>4247-4249</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSbC(SiMe3)2-Pyr], results in the first structurally authenticated In(III)/Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the SbC double bond.</abstract><pub>American Chemical Society</pub><doi>10.1021/om990542t</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0276-7333
ispartof Organometallics, 1999-10, Vol.18 (21), p.4247-4249
issn 0276-7333
1520-6041
language eng
recordid cdi_crossref_primary_10_1021_om990542t
source American Chemical Society Journals
title Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-13T10%3A51%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Carbometalation%20of%20a%20Stiba-alkene%20Resulting%20in%20an%20In(III)/Sb(III)%20C-Centered%20Geminal%20Organodimetallic%20Complex&rft.jtitle=Organometallics&rft.au=Andrews,%20Philip%20C&rft.date=1999-10-11&rft.volume=18&rft.issue=21&rft.spage=4247&rft.epage=4249&rft.pages=4247-4249&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om990542t&rft_dat=%3Cacs_cross%3Ef08184006%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true