Stable Cationic Dimethyl(hydrido)platinum(IV) Complex
The complex [PtMe2(9N3)], 1, 9N3 = 1,4,7-triazacyclononane, undergoes protonation by triflic acid and, reversibly, even by methanol to form the cationic complex [PtHMe2(9N3)]+, 2, which is thermally stable up to 190 °C in the solid state as the triflate salt. Oxidation of 1 or 2 by H2O2 or by H2O/O2...
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| Veröffentlicht in: | Organometallics 1999-07, Vol.18 (15), p.2861-2866 |
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| container_title | Organometallics |
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| creator | Prokopchuk, Ernest M Jenkins, Hilary A Puddephatt, Richard J |
| description | The complex [PtMe2(9N3)], 1, 9N3 = 1,4,7-triazacyclononane, undergoes protonation by triflic acid and, reversibly, even by methanol to form the cationic complex [PtHMe2(9N3)]+, 2, which is thermally stable up to 190 °C in the solid state as the triflate salt. Oxidation of 1 or 2 by H2O2 or by H2O/O2 gives the hydroxy complex [Pt(OH)Me2(9N3)]+, which can be reversibly protonated to the aqua complex [Pt(OH2)Me2(9N3)]2+. |
| doi_str_mv | 10.1021/om990205k |
| format | Article |
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Oxidation of 1 or 2 by H2O2 or by H2O/O2 gives the hydroxy complex [Pt(OH)Me2(9N3)]+, which can be reversibly protonated to the aqua complex [Pt(OH2)Me2(9N3)]2+.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om990205k</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 1999-07, Vol.18 (15), p.2861-2866</ispartof><rights>Copyright © 1999 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a295t-bba42b6532bf42cb8570ebee84d1df060e127166573ff36f272ccb782c138b153</citedby><cites>FETCH-LOGICAL-a295t-bba42b6532bf42cb8570ebee84d1df060e127166573ff36f272ccb782c138b153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om990205k$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om990205k$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Prokopchuk, Ernest M</creatorcontrib><creatorcontrib>Jenkins, Hilary A</creatorcontrib><creatorcontrib>Puddephatt, Richard J</creatorcontrib><title>Stable Cationic Dimethyl(hydrido)platinum(IV) Complex</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>The complex [PtMe2(9N3)], 1, 9N3 = 1,4,7-triazacyclononane, undergoes protonation by triflic acid and, reversibly, even by methanol to form the cationic complex [PtHMe2(9N3)]+, 2, which is thermally stable up to 190 °C in the solid state as the triflate salt. Oxidation of 1 or 2 by H2O2 or by H2O/O2 gives the hydroxy complex [Pt(OH)Me2(9N3)]+, which can be reversibly protonated to the aqua complex [Pt(OH2)Me2(9N3)]2+.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNptz8FLwzAUx_EgCs7pwf9gF2E7VF9emqQ7StUpDhQ2h7eQpAnr1q4j6WD7761MdvL0Du_DD76E3FK4p4D0oanHY0Dg6zPSoxwhEZDSc9IDlCKRjLFLchXjCgCEZNgjfNZqU7lBrtuy2ZR28FTWrl0equHyUISyaEbbqnttdvXwbTEa5E29rdz-mlx4XUV383f75OvleZ6_JtOPyVv-OE00jnmbGKNTNIIzND5FazIuwRnnsrSghQcBjqKkQnDJvGfCo0RrjczQUpYZylmfjI67NjQxBufVNpS1DgdFQf32qlNvZ5OjLWPr9ieow1p1qZKr-edMZen7RHwvhJp0_u7otY1q1ezCpiv5Z_cHAMJiUA</recordid><startdate>19990719</startdate><enddate>19990719</enddate><creator>Prokopchuk, Ernest M</creator><creator>Jenkins, Hilary A</creator><creator>Puddephatt, Richard J</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19990719</creationdate><title>Stable Cationic Dimethyl(hydrido)platinum(IV) Complex</title><author>Prokopchuk, Ernest M ; Jenkins, Hilary A ; Puddephatt, Richard J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a295t-bba42b6532bf42cb8570ebee84d1df060e127166573ff36f272ccb782c138b153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Prokopchuk, Ernest M</creatorcontrib><creatorcontrib>Jenkins, Hilary A</creatorcontrib><creatorcontrib>Puddephatt, Richard J</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Prokopchuk, Ernest M</au><au>Jenkins, Hilary A</au><au>Puddephatt, Richard J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stable Cationic Dimethyl(hydrido)platinum(IV) Complex</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1999-07-19</date><risdate>1999</risdate><volume>18</volume><issue>15</issue><spage>2861</spage><epage>2866</epage><pages>2861-2866</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>The complex [PtMe2(9N3)], 1, 9N3 = 1,4,7-triazacyclononane, undergoes protonation by triflic acid and, reversibly, even by methanol to form the cationic complex [PtHMe2(9N3)]+, 2, which is thermally stable up to 190 °C in the solid state as the triflate salt. Oxidation of 1 or 2 by H2O2 or by H2O/O2 gives the hydroxy complex [Pt(OH)Me2(9N3)]+, which can be reversibly protonated to the aqua complex [Pt(OH2)Me2(9N3)]2+.</abstract><pub>American Chemical Society</pub><doi>10.1021/om990205k</doi><tpages>6</tpages></addata></record> |
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| source | ACS Publications |
| title | Stable Cationic Dimethyl(hydrido)platinum(IV) Complex |
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